Hydrophosphorylation of electron-deficient alkenes and alkynes mediated by convergent paired electrolysis
A straightforward and practical strategy for hydrophosphorylation of electron-deficient alkenes and alkynes to access γ-ketophosphine oxides, enabled by a convergent paired electrolysis (CPE) in the absence of a metal, base, and redox reagent, has been described. Mechanistic studies have revealed th...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-07, Vol.58 (59), p.8238-8241 |
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| container_issue | 59 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Sun, Xue Yang, Jianjing Yan, Kelu Zhuang, Xinyu Yu, Jie Song, Xiaodan Zhang, Fanjun Li, Bingwen Wen, Jiangwei |
| description | A straightforward and practical strategy for hydrophosphorylation of electron-deficient alkenes and alkynes to access γ-ketophosphine oxides, enabled by a convergent paired electrolysis (CPE) in the absence of a metal, base, and redox reagent, has been described. Mechanistic studies have revealed that the diarylphosphane oxides play the dual role of a phosphorus radical precursor and hydrogen donor in this transformation.
A straightforward and practical strategy for hydrophosphorylation of electron-deficient alkenes and alkynes to access γ-ketophosphine oxides, enabled by CPE strategy in the absence of a metal, base, and redox reagent, has been described. |
| doi_str_mv | 10.1039/d2cc02745c |
| format | Article |
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A straightforward and practical strategy for hydrophosphorylation of electron-deficient alkenes and alkynes to access γ-ketophosphine oxides, enabled by CPE strategy in the absence of a metal, base, and redox reagent, has been described.</description><subject>Alkenes</subject><subject>Alkynes</subject><subject>Convergence</subject><subject>Electrolysis</subject><subject>Reagents</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpd0c9LwzAUB_AgCs7pxbtQ8CJCNb_THqX-mDDwouCtZMmrZnbNTDqh_72pGwoGknwJHx6PF4ROCb4imJXXlhqDqeLC7KEJYZLnghev-2MWZa4YF4foKMYlTouIYoLcbLDBr999TDsMre6d7zLfZNCC6YPvcguNMw66PtPtB3QQM93ZMQ9jXoF1ugebLYbM-O4LwttI19qF9Lgr0g7RxWN00Og2wsnunqKX-7vnapbPnx4eq5t5bijnfU4sp2VZMtkowoimXCpKFoxLYIIWupFUYw7KGiFZQbBShSkaayTG3GDLMJuii23ddfCfG4h9vXLRQNvqDvwm1lQWAjNWcpXo-T-69JvQpe6SKimW45nU5VaZ4GMM0NTr4FY6DDXB9Tj1-pZW1c_Uq4TPtjhE8-v-foV9A89vfwU</recordid><startdate>20220721</startdate><enddate>20220721</enddate><creator>Sun, Xue</creator><creator>Yang, Jianjing</creator><creator>Yan, Kelu</creator><creator>Zhuang, Xinyu</creator><creator>Yu, Jie</creator><creator>Song, Xiaodan</creator><creator>Zhang, Fanjun</creator><creator>Li, Bingwen</creator><creator>Wen, Jiangwei</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4431-9158</orcidid><orcidid>https://orcid.org/0000-0002-1551-267X</orcidid></search><sort><creationdate>20220721</creationdate><title>Hydrophosphorylation of electron-deficient alkenes and alkynes mediated by convergent paired electrolysis</title><author>Sun, Xue ; Yang, Jianjing ; Yan, Kelu ; Zhuang, Xinyu ; Yu, Jie ; Song, Xiaodan ; Zhang, Fanjun ; Li, Bingwen ; Wen, Jiangwei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c244t-1d4299936f7131a246721b346e3528af62a04e7dc563810778c8fdc6004c0d303</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alkenes</topic><topic>Alkynes</topic><topic>Convergence</topic><topic>Electrolysis</topic><topic>Reagents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Xue</creatorcontrib><creatorcontrib>Yang, Jianjing</creatorcontrib><creatorcontrib>Yan, Kelu</creatorcontrib><creatorcontrib>Zhuang, Xinyu</creatorcontrib><creatorcontrib>Yu, Jie</creatorcontrib><creatorcontrib>Song, Xiaodan</creatorcontrib><creatorcontrib>Zhang, Fanjun</creatorcontrib><creatorcontrib>Li, Bingwen</creatorcontrib><creatorcontrib>Wen, Jiangwei</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Xue</au><au>Yang, Jianjing</au><au>Yan, Kelu</au><au>Zhuang, Xinyu</au><au>Yu, Jie</au><au>Song, Xiaodan</au><au>Zhang, Fanjun</au><au>Li, Bingwen</au><au>Wen, Jiangwei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrophosphorylation of electron-deficient alkenes and alkynes mediated by convergent paired electrolysis</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2022-07-21</date><risdate>2022</risdate><volume>58</volume><issue>59</issue><spage>8238</spage><epage>8241</epage><pages>8238-8241</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A straightforward and practical strategy for hydrophosphorylation of electron-deficient alkenes and alkynes to access γ-ketophosphine oxides, enabled by a convergent paired electrolysis (CPE) in the absence of a metal, base, and redox reagent, has been described. Mechanistic studies have revealed that the diarylphosphane oxides play the dual role of a phosphorus radical precursor and hydrogen donor in this transformation.
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2022-07, Vol.58 (59), p.8238-8241 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alkenes Alkynes Convergence Electrolysis Reagents |
| title | Hydrophosphorylation of electron-deficient alkenes and alkynes mediated by convergent paired electrolysis |
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