Coordination chemistry of hepta- tert -butylnonaphosphane
Hepta- tert -butylnonaphosphane { cyclo -(P 4 t Bu 3 )} 2 P t Bu was employed as a ligand in transition metal complexes of iron(0) (1), cobalt(− i ) (2), copper( i ) (3) and rhodium( i ) (4), which are readily formed in moderate to good yields, and an unstable palladium( ii ) complex (5). The ligand...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2022-07, Vol.51 (29), p.10887-10897 |
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| container_issue | 29 |
| container_start_page | 10887 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 51 |
| creator | Eilrich, Volker Jens Grell, Toni Lönnecke, Peter Hey-Hawkins, Evamarie |
| description | Hepta-
tert
-butylnonaphosphane {
cyclo
-(P
4
t
Bu
3
)}
2
P
t
Bu was employed as a ligand in transition metal complexes of iron(0) (1), cobalt(−
i
) (2), copper(
i
) (3) and rhodium(
i
) (4), which are readily formed in moderate to good yields, and an unstable palladium(
ii
) complex (5). The ligand features three different bonding modes (one monodentate (compounds 1 and 2) and two bidentate (compounds 3–5) with formation of four- or six-membered chelate rings), as determined by X-ray diffraction studies. The
31
P{
1
H} NMR spectral data of 1–3 have been determined by automated line-shape analysis. |
| doi_str_mv | 10.1039/d2dt01691e |
| format | Article |
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tert
-butylnonaphosphane {
cyclo
-(P
4
t
Bu
3
)}
2
P
t
Bu was employed as a ligand in transition metal complexes of iron(0) (1), cobalt(−
i
) (2), copper(
i
) (3) and rhodium(
i
) (4), which are readily formed in moderate to good yields, and an unstable palladium(
ii
) complex (5). The ligand features three different bonding modes (one monodentate (compounds 1 and 2) and two bidentate (compounds 3–5) with formation of four- or six-membered chelate rings), as determined by X-ray diffraction studies. The
31
P{
1
H} NMR spectral data of 1–3 have been determined by automated line-shape analysis.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d2dt01691e</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemical bonds ; Coordination compounds ; Ligands ; NMR ; Nuclear magnetic resonance ; Palladium ; Rhodium ; Transition metal compounds</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2022-07, Vol.51 (29), p.10887-10897</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-be4d8eac2311af8336623d57a7885af6b7a8d3b954a9ef4fc6aaac12492b27083</citedby><cites>FETCH-LOGICAL-c328t-be4d8eac2311af8336623d57a7885af6b7a8d3b954a9ef4fc6aaac12492b27083</cites><orcidid>0000-0001-9162-6487 ; 0000-0001-7433-4044 ; 0000-0003-4267-0603 ; 0000-0003-1335-0897</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Eilrich, Volker Jens</creatorcontrib><creatorcontrib>Grell, Toni</creatorcontrib><creatorcontrib>Lönnecke, Peter</creatorcontrib><creatorcontrib>Hey-Hawkins, Evamarie</creatorcontrib><title>Coordination chemistry of hepta- tert -butylnonaphosphane</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Hepta-
tert
-butylnonaphosphane {
cyclo
-(P
4
t
Bu
3
)}
2
P
t
Bu was employed as a ligand in transition metal complexes of iron(0) (1), cobalt(−
i
) (2), copper(
i
) (3) and rhodium(
i
) (4), which are readily formed in moderate to good yields, and an unstable palladium(
ii
) complex (5). The ligand features three different bonding modes (one monodentate (compounds 1 and 2) and two bidentate (compounds 3–5) with formation of four- or six-membered chelate rings), as determined by X-ray diffraction studies. The
31
P{
1
H} NMR spectral data of 1–3 have been determined by automated line-shape analysis.</description><subject>Chemical bonds</subject><subject>Coordination compounds</subject><subject>Ligands</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Palladium</subject><subject>Rhodium</subject><subject>Transition metal compounds</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkE1LxDAURYMoOI5u_AUFNyJUk5e0TZYyM37AgJtxXV7ThHboNDVJF_331hlx4erexeFyuITcMvrIKFdPNdSRslwxc0YWTBRFqoCL878O-SW5CmFPKQDNYEHUyjlftz3G1vWJbsyhDdFPibNJY4aIaRKNj0lajXHqetfj0LgwNNiba3JhsQvm5jeX5PNls1u9pduP1_fV8zbVHGRMKyNqaVADZwyt5DzPgddZgYWUGdq8KlDWvFKZQGWssDpHRM1AKKigoJIvyf1pd_DuazQhlrOiNl03O7gxlJDLjHJQvJjRu3_o3o2-n-1mSgkuQR6phxOlvQvBG1sOvj2gn0pGy58XyzWsd8cXN_wbee5kJg</recordid><startdate>20220726</startdate><enddate>20220726</enddate><creator>Eilrich, Volker Jens</creator><creator>Grell, Toni</creator><creator>Lönnecke, Peter</creator><creator>Hey-Hawkins, Evamarie</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-9162-6487</orcidid><orcidid>https://orcid.org/0000-0001-7433-4044</orcidid><orcidid>https://orcid.org/0000-0003-4267-0603</orcidid><orcidid>https://orcid.org/0000-0003-1335-0897</orcidid></search><sort><creationdate>20220726</creationdate><title>Coordination chemistry of hepta- tert -butylnonaphosphane</title><author>Eilrich, Volker Jens ; Grell, Toni ; Lönnecke, Peter ; Hey-Hawkins, Evamarie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-be4d8eac2311af8336623d57a7885af6b7a8d3b954a9ef4fc6aaac12492b27083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical bonds</topic><topic>Coordination compounds</topic><topic>Ligands</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Palladium</topic><topic>Rhodium</topic><topic>Transition metal compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Eilrich, Volker Jens</creatorcontrib><creatorcontrib>Grell, Toni</creatorcontrib><creatorcontrib>Lönnecke, Peter</creatorcontrib><creatorcontrib>Hey-Hawkins, Evamarie</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Eilrich, Volker Jens</au><au>Grell, Toni</au><au>Lönnecke, Peter</au><au>Hey-Hawkins, Evamarie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coordination chemistry of hepta- tert -butylnonaphosphane</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2022-07-26</date><risdate>2022</risdate><volume>51</volume><issue>29</issue><spage>10887</spage><epage>10897</epage><pages>10887-10897</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Hepta-
tert
-butylnonaphosphane {
cyclo
-(P
4
t
Bu
3
)}
2
P
t
Bu was employed as a ligand in transition metal complexes of iron(0) (1), cobalt(−
i
) (2), copper(
i
) (3) and rhodium(
i
) (4), which are readily formed in moderate to good yields, and an unstable palladium(
ii
) complex (5). The ligand features three different bonding modes (one monodentate (compounds 1 and 2) and two bidentate (compounds 3–5) with formation of four- or six-membered chelate rings), as determined by X-ray diffraction studies. The
31
P{
1
H} NMR spectral data of 1–3 have been determined by automated line-shape analysis.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2dt01691e</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-9162-6487</orcidid><orcidid>https://orcid.org/0000-0001-7433-4044</orcidid><orcidid>https://orcid.org/0000-0003-4267-0603</orcidid><orcidid>https://orcid.org/0000-0003-1335-0897</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2022-07, Vol.51 (29), p.10887-10897 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2685032937 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical bonds Coordination compounds Ligands NMR Nuclear magnetic resonance Palladium Rhodium Transition metal compounds |
| title | Coordination chemistry of hepta- tert -butylnonaphosphane |
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