Terpolymerization of acrylamide, acrylic acid, and acrylonitrile: Synthesis and properties
Free‐radical solution terpolymerization of acrylamide, acrylic acid, and acrylonitrile was carried out in a mixture of dimethylformamide and water (60 : 40,v/v) at 85°C using benzoyl peroxide as the initiator. The polymers were characterized by elemental analysis, IR, 1H‐NMR, TGA, and viscosity meas...
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| Veröffentlicht in: | Journal of applied polymer science 1998-07, Vol.69 (2), p.217-228 |
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| creator | Mathakiya, Ismail Vangani, Veena Rakshit, Animesh Kumar |
| description | Free‐radical solution terpolymerization of acrylamide, acrylic acid, and acrylonitrile was carried out in a mixture of dimethylformamide and water (60 : 40,v/v) at 85°C using benzoyl peroxide as the initiator. The polymers were characterized by elemental analysis, IR, 1H‐NMR, TGA, and viscosity measurements. Elemental analysis data were used to evaluate the terpolymer composition. The reactivity ratios were determined by Fineman–Ross and Kelen–Tudos methods. The reactivity ratios (r) for the copolymerization of (1) acrylic acid + acrylonitrile with (2) acrylamide was found to be r1 = 0.86 ± 0.09 and r2 = 1.93 ± 0.03, respectively, by the Kelen–Tudos method. The Fineman–Ross method yielded a value of r1 = 0.86 ± 0.05 and r2 = 1.94 ± 0.09, respectively. The activation energy values for various stages of decomposition were calculated from TGA analysis. Voluminosity (VE) and the shape factor (ν) were also computed from the viscosity measurements in different ratios of the solvent mixture. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 217–228, 1998 |
| doi_str_mv | 10.1002/(SICI)1097-4628(19980711)69:2<217::AID-APP2>3.0.CO;2-Q |
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The polymers were characterized by elemental analysis, IR, 1H‐NMR, TGA, and viscosity measurements. Elemental analysis data were used to evaluate the terpolymer composition. The reactivity ratios were determined by Fineman–Ross and Kelen–Tudos methods. The reactivity ratios (r) for the copolymerization of (1) acrylic acid + acrylonitrile with (2) acrylamide was found to be r1 = 0.86 ± 0.09 and r2 = 1.93 ± 0.03, respectively, by the Kelen–Tudos method. The Fineman–Ross method yielded a value of r1 = 0.86 ± 0.05 and r2 = 1.94 ± 0.09, respectively. The activation energy values for various stages of decomposition were calculated from TGA analysis. Voluminosity (VE) and the shape factor (ν) were also computed from the viscosity measurements in different ratios of the solvent mixture. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 217–228, 1998</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/(SICI)1097-4628(19980711)69:2<217::AID-APP2>3.0.CO;2-Q</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>Applied sciences ; Copolymerization ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; properties ; reactivity ratio ; synthesis ; terpolymers</subject><ispartof>Journal of applied polymer science, 1998-07, Vol.69 (2), p.217-228</ispartof><rights>Copyright © 1998 John Wiley & Sons, Inc.</rights><rights>1998 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2F%28SICI%291097-4628%2819980711%2969%3A2%3C217%3A%3AAID-APP2%3E3.0.CO%3B2-Q$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2F%28SICI%291097-4628%2819980711%2969%3A2%3C217%3A%3AAID-APP2%3E3.0.CO%3B2-Q$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2248485$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Mathakiya, Ismail</creatorcontrib><creatorcontrib>Vangani, Veena</creatorcontrib><creatorcontrib>Rakshit, Animesh Kumar</creatorcontrib><title>Terpolymerization of acrylamide, acrylic acid, and acrylonitrile: Synthesis and properties</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Free‐radical solution terpolymerization of acrylamide, acrylic acid, and acrylonitrile was carried out in a mixture of dimethylformamide and water (60 : 40,v/v) at 85°C using benzoyl peroxide as the initiator. The polymers were characterized by elemental analysis, IR, 1H‐NMR, TGA, and viscosity measurements. Elemental analysis data were used to evaluate the terpolymer composition. The reactivity ratios were determined by Fineman–Ross and Kelen–Tudos methods. The reactivity ratios (r) for the copolymerization of (1) acrylic acid + acrylonitrile with (2) acrylamide was found to be r1 = 0.86 ± 0.09 and r2 = 1.93 ± 0.03, respectively, by the Kelen–Tudos method. The Fineman–Ross method yielded a value of r1 = 0.86 ± 0.05 and r2 = 1.94 ± 0.09, respectively. The activation energy values for various stages of decomposition were calculated from TGA analysis. Voluminosity (VE) and the shape factor (ν) were also computed from the viscosity measurements in different ratios of the solvent mixture. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 217–228, 1998</description><subject>Applied sciences</subject><subject>Copolymerization</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>properties</subject><subject>reactivity ratio</subject><subject>synthesis</subject><subject>terpolymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkF1v0zAUhiMEEmXsP_QCoU0ixR-JYxc0qcq-Km10UwNI3Bw5tiPM0qTYmVj49TjL6C6YxI2Pz7H9vNYTRUcYzTBC5P3BepkvDzESWZwwwg-wEBxlGB8yMScfCc7m88XyOF5cXZEjOkOzfPWBxNfPosnuyfNoEkA45kKkL6NX3v9ACOMUsUn0rTBu29b9xjj7W3a2baZtNZXK9bXcWG3ejXurQrU6dI0eJ21jO2drM5-u-6b7brz194db126N66zxr6MXlay92X-oe9Hn05MiP48vVmfLfHERqwQJEmc0Q1KXOgmr5qoqszLFkqASU0EzygxDRnPJODalSgjSVaq5wFRlmlXUELoXvR25IfrnrfEdbKxXpq5lY9pbD4RxkuGEhotfxovKtd47U8HW2Y10PWAEg2qAQTUM3mDwBn9VAxNAIKgGCKphUA0UEOSrML4O4DcPP5BeybpyslHW7-iEJDzh6WP-r-Ct_yf8v9lPRN_3ARyPYOs7c7cDS3cDLOhN4eunMzg_Pl0nl0UBBf0DH-Ou7g</recordid><startdate>19980711</startdate><enddate>19980711</enddate><creator>Mathakiya, Ismail</creator><creator>Vangani, Veena</creator><creator>Rakshit, Animesh Kumar</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19980711</creationdate><title>Terpolymerization of acrylamide, acrylic acid, and acrylonitrile: Synthesis and properties</title><author>Mathakiya, Ismail ; Vangani, Veena ; Rakshit, Animesh Kumar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4092-7370adbd40add8cfb7b51a20b1393736e60ed8a681ebc420df5d8913c7d6f3e23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Copolymerization</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>properties</topic><topic>reactivity ratio</topic><topic>synthesis</topic><topic>terpolymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mathakiya, Ismail</creatorcontrib><creatorcontrib>Vangani, Veena</creatorcontrib><creatorcontrib>Rakshit, Animesh Kumar</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mathakiya, Ismail</au><au>Vangani, Veena</au><au>Rakshit, Animesh Kumar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Terpolymerization of acrylamide, acrylic acid, and acrylonitrile: Synthesis and properties</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. 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The Fineman–Ross method yielded a value of r1 = 0.86 ± 0.05 and r2 = 1.94 ± 0.09, respectively. The activation energy values for various stages of decomposition were calculated from TGA analysis. Voluminosity (VE) and the shape factor (ν) were also computed from the viscosity measurements in different ratios of the solvent mixture. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 217–228, 1998</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/(SICI)1097-4628(19980711)69:2<217::AID-APP2>3.0.CO;2-Q</doi><tpages>12</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts properties reactivity ratio synthesis terpolymers |
| title | Terpolymerization of acrylamide, acrylic acid, and acrylonitrile: Synthesis and properties |
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