The crystallization and growth of AlB2 single crystal flakes in aluminum

An in situ high temperature heat treatment was used to investigate the crystallization and growth behavior of AlB2 flakes in aluminum. Aluminum samples containing 1.8% boron were heated above the liquidus and then rapidly cooled through the Al(L) + AlB12 region to avoid the formation of AlB12 crysta...

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Veröffentlicht in:Journal of materials research 1998-12, Vol.13 (12), p.3485-3498
Hauptverfasser: Deppisch, C., Liu, G., Hall, A., Xu, Y., Zangvil, A., Shang, J. K., Economy, J.
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container_end_page 3498
container_issue 12
container_start_page 3485
container_title Journal of materials research
container_volume 13
creator Deppisch, C.
Liu, G.
Hall, A.
Xu, Y.
Zangvil, A.
Shang, J. K.
Economy, J.
description An in situ high temperature heat treatment was used to investigate the crystallization and growth behavior of AlB2 flakes in aluminum. Aluminum samples containing 1.8% boron were heated above the liquidus and then rapidly cooled through the Al(L) + AlB12 region to avoid the formation of AlB12 crystals. Subsequently, a homogeneous distribution of high aspect ratio AlB2 flakes crystallized upon holding below the peritectic transition temperature. Growth rate in the (a) and (c) dimensions increased during elevated hold temperatures below the peritectic transition temperature. Surprisingly, faster cooling rates from above the liquidus to room temperature resulted in thinner, wider flakes. Similar to graphite this phenomenon is believed to result from a need to accommodate a changing misfit strain energy between the solidifying aluminum and the growing AlB2 flakes.
doi_str_mv 10.1557/JMR.1998.0476
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