Impedance of solid oxide fuel cell LSM/YSZ composite cathodes
The composites were investigated using impedance spectroscopy. General trends related to the oxygen reduction process are extracted from the impedance data. Literature concerning kinetic studies of LSM/YSZ electrodes and related systems was reviewed and compared to new experimental data. From this i...
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| Veröffentlicht in: | Journal of the Electrochemical Society 2001-01, Vol.148 (5), p.A433-A442 |
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| container_end_page | A442 |
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| container_title | Journal of the Electrochemical Society |
| container_volume | 148 |
| creator | JØRGENSEN, M. J MOGENSEN, M |
| description | The composites were investigated using impedance spectroscopy. General trends related to the oxygen reduction process are extracted from the impedance data. Literature concerning kinetic studies of LSM/YSZ electrodes and related systems was reviewed and compared to new experimental data. From this it is found that at least five processes affect the impedance. Going from high to low frequency, these processes are (i) and (ii) two geometry-related contributions interpreted as transport across LSM/YSZ interfaces and through the YSZ of the composite, (iii) a process reflecting competitive reaction steps such as bond breaking and surface diffusion, (iv) gas diffusion in a stagnant glass layer above the electrode structure, and (v) an activation process (inductive) presumably located at the triple phase boundary of electrode, electrolyte, and gas phase. 56 refs. |
| doi_str_mv | 10.1149/1.1360203 |
| format | Article |
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Going from high to low frequency, these processes are (i) and (ii) two geometry-related contributions interpreted as transport across LSM/YSZ interfaces and through the YSZ of the composite, (iii) a process reflecting competitive reaction steps such as bond breaking and surface diffusion, (iv) gas diffusion in a stagnant glass layer above the electrode structure, and (v) an activation process (inductive) presumably located at the triple phase boundary of electrode, electrolyte, and gas phase. 56 refs.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.1360203</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>Pennington, NJ: Electrochemical Society</publisher><subject>Applied sciences ; Energy ; Energy. 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Going from high to low frequency, these processes are (i) and (ii) two geometry-related contributions interpreted as transport across LSM/YSZ interfaces and through the YSZ of the composite, (iii) a process reflecting competitive reaction steps such as bond breaking and surface diffusion, (iv) gas diffusion in a stagnant glass layer above the electrode structure, and (v) an activation process (inductive) presumably located at the triple phase boundary of electrode, electrolyte, and gas phase. 56 refs.</description><subject>Applied sciences</subject><subject>Energy</subject><subject>Energy. 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Thermal use of fuels</topic><topic>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</topic><topic>Exact sciences and technology</topic><topic>Fuel cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>JØRGENSEN, M. J</creatorcontrib><creatorcontrib>MOGENSEN, M</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>JØRGENSEN, M. 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Going from high to low frequency, these processes are (i) and (ii) two geometry-related contributions interpreted as transport across LSM/YSZ interfaces and through the YSZ of the composite, (iii) a process reflecting competitive reaction steps such as bond breaking and surface diffusion, (iv) gas diffusion in a stagnant glass layer above the electrode structure, and (v) an activation process (inductive) presumably located at the triple phase boundary of electrode, electrolyte, and gas phase. 56 refs.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.1360203</doi></addata></record> |
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| language | eng |
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| source | IOP Publishing Journals |
| subjects | Applied sciences Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells |
| title | Impedance of solid oxide fuel cell LSM/YSZ composite cathodes |
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