Palladium-catalyzed stereoselective ring-opening reaction of aryl cyclopropyl ketones

Herein, we report that ,-unsaturated ketones could be obtained by palladium-catalyzed ring-opening of mono-substituted cyclopropyl ketones efficiently and systematically. ( E )-1-Arylbut-2-en-1-ones were generated from aryl cyclopropyl ketones stereoselectively in yields of 2389% by the Pd(OAc) 2 /P...

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Veröffentlicht in:	Organic & biomolecular chemistry 2022-07, Vol.2 (27), p.5412-5415
Hauptverfasser:	Chen, Yan-Zuo, Wang, Neng, Hou, Zong-Rui, Zhou, Xian-Li, Li, Xiaohuan, Gao, Feng, Jiang, Ting
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Ketones Organic compounds Palladium Ring opening Stereoselectivity
Online-Zugang:	Volltext
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