Structural phase transitions of betaine phosphite studied by X-ray scattering
DSC and X-ray scattering studies of betaine phosphite, (CH 3 ) 3 NCH 2 COO·H 3 PO 3 , single crystals have been made. The space group of Phase I (T > 355 K) and that of Phase III (T < 216K) are determined as P12 1 /ml and P12 1 1, respectively, where the cell length of the c axis in Phases II...
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| Veröffentlicht in: | Ferroelectrics 1998-09, Vol.217 (1), p.75-81 |
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| container_title | Ferroelectrics |
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| creator | Hasebe, Katsuhiko Masuno, Kazuo Nanitani, Seiji Asahi, Takanao |
| description | DSC and X-ray scattering studies of betaine phosphite, (CH
3
)
3
NCH
2
COO·H
3
PO
3
, single crystals have been made. The space group of Phase I (T > 355 K) and that of Phase III (T < 216K) are determined as P12
1
/ml and P12
1
1, respectively, where the cell length of the c axis in Phases II and III are two times larger than that in Phase I. The crystal structure is determined at 373 K. in Phase I and at 173 K in Phase III. The phosphite molecules are disordered in Phase I. |
| doi_str_mv | 10.1080/00150199808015023 |
| format | Article |
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3
)
3
NCH
2
COO·H
3
PO
3
, single crystals have been made. The space group of Phase I (T > 355 K) and that of Phase III (T < 216K) are determined as P12
1
/ml and P12
1
1, respectively, where the cell length of the c axis in Phases II and III are two times larger than that in Phase I. The crystal structure is determined at 373 K. in Phase I and at 173 K in Phase III. The phosphite molecules are disordered in Phase I.</description><identifier>ISSN: 0015-0193</identifier><identifier>EISSN: 1563-5112</identifier><identifier>DOI: 10.1080/00150199808015023</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><subject>Betaine phosphite ; crystal structure ; ferroelectric ; Keywords ; phase transition</subject><ispartof>Ferroelectrics, 1998-09, Vol.217 (1), p.75-81</ispartof><rights>Copyright Taylor & Francis Group, LLC 1998</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c441t-6e27373a8926ff29b43000481fe361182d34766b7c2b149fa32e92eb781d1c543</citedby><cites>FETCH-LOGICAL-c441t-6e27373a8926ff29b43000481fe361182d34766b7c2b149fa32e92eb781d1c543</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/00150199808015023$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/00150199808015023$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,59620,60409</link.rule.ids></links><search><creatorcontrib>Hasebe, Katsuhiko</creatorcontrib><creatorcontrib>Masuno, Kazuo</creatorcontrib><creatorcontrib>Nanitani, Seiji</creatorcontrib><creatorcontrib>Asahi, Takanao</creatorcontrib><title>Structural phase transitions of betaine phosphite studied by X-ray scattering</title><title>Ferroelectrics</title><description>DSC and X-ray scattering studies of betaine phosphite, (CH
3
)
3
NCH
2
COO·H
3
PO
3
, single crystals have been made. The space group of Phase I (T > 355 K) and that of Phase III (T < 216K) are determined as P12
1
/ml and P12
1
1, respectively, where the cell length of the c axis in Phases II and III are two times larger than that in Phase I. The crystal structure is determined at 373 K. in Phase I and at 173 K in Phase III. The phosphite molecules are disordered in Phase I.</description><subject>Betaine phosphite</subject><subject>crystal structure</subject><subject>ferroelectric</subject><subject>Keywords</subject><subject>phase transition</subject><issn>0015-0193</issn><issn>1563-5112</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkD1LBDEYhIMoeJ7-ALtUdqv52mwCNnL4BYqFCnYhm028yN7mTLLo_ntznN2BVu8MM89bDACnGJ1jJNAFQrhGWEpRTFGE7oEZrjmtaozJPpht8qoU6CE4SumjWMqYnIHH5xxHk8eoe7he6mRhjnpIPvswJBgcbG3WfrAlDGm99NnClMfO2w62E3yrop5gMjpnG_3wfgwOnO6TPfm9c_B6c_2yuKsenm7vF1cPlWEM54pb0tCGaiEJd47IllGEEBPYWcoxFqSjrOG8bQxpMZNOU2IlsW0jcIdNzegcnG3_rmP4HG3KauWTsX2vBxvGpAhvpOBMlCLeFk0MKUXr1Dr6lY6TwkhthlM7wxXmcsv4wYW40l8h9p3KeupDdGUc45Oif-HNv_gOpfJ3pj8LtYUM</recordid><startdate>199809</startdate><enddate>199809</enddate><creator>Hasebe, Katsuhiko</creator><creator>Masuno, Kazuo</creator><creator>Nanitani, Seiji</creator><creator>Asahi, Takanao</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>199809</creationdate><title>Structural phase transitions of betaine phosphite studied by X-ray scattering</title><author>Hasebe, Katsuhiko ; Masuno, Kazuo ; Nanitani, Seiji ; Asahi, Takanao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c441t-6e27373a8926ff29b43000481fe361182d34766b7c2b149fa32e92eb781d1c543</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Betaine phosphite</topic><topic>crystal structure</topic><topic>ferroelectric</topic><topic>Keywords</topic><topic>phase transition</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hasebe, Katsuhiko</creatorcontrib><creatorcontrib>Masuno, Kazuo</creatorcontrib><creatorcontrib>Nanitani, Seiji</creatorcontrib><creatorcontrib>Asahi, Takanao</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Ferroelectrics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hasebe, Katsuhiko</au><au>Masuno, Kazuo</au><au>Nanitani, Seiji</au><au>Asahi, Takanao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural phase transitions of betaine phosphite studied by X-ray scattering</atitle><jtitle>Ferroelectrics</jtitle><date>1998-09</date><risdate>1998</risdate><volume>217</volume><issue>1</issue><spage>75</spage><epage>81</epage><pages>75-81</pages><issn>0015-0193</issn><eissn>1563-5112</eissn><abstract>DSC and X-ray scattering studies of betaine phosphite, (CH
3
)
3
NCH
2
COO·H
3
PO
3
, single crystals have been made. The space group of Phase I (T > 355 K) and that of Phase III (T < 216K) are determined as P12
1
/ml and P12
1
1, respectively, where the cell length of the c axis in Phases II and III are two times larger than that in Phase I. The crystal structure is determined at 373 K. in Phase I and at 173 K in Phase III. The phosphite molecules are disordered in Phase I.</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/00150199808015023</doi><tpages>7</tpages></addata></record> |
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| issn | 0015-0193 1563-5112 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_26798648 |
| source | Taylor & Francis |
| subjects | Betaine phosphite crystal structure ferroelectric Keywords phase transition |
| title | Structural phase transitions of betaine phosphite studied by X-ray scattering |
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