Study on polypyrrole as an electrode material in neutral solutions
A study of the polypyrrole (PPy) as an electrode material for cathodic reduction of dioxygen in water solutions depending on the substrate material was carried out. It has been found that the electroactivity of a PPy film strongly depends on the nature of a substrate, especially if the thickness of...
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Veröffentlicht in: | Corrosion science 1998-11, Vol.40 (11), p.1873-1881 |
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container_end_page | 1881 |
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container_issue | 11 |
container_start_page | 1873 |
container_title | Corrosion science |
container_volume | 40 |
creator | Biallozor, S Zalewska, T |
description | A study of the polypyrrole (PPy) as an electrode material for cathodic reduction of dioxygen in water solutions depending on the substrate material was carried out. It has been found that the electroactivity of a PPy film strongly depends on the nature of a substrate, especially if the thickness of the PPy film is low. The efficiency coefficient of the dioxygen reduction on the Ni⧹PPy electrode is higher than the one on the Pt⧹PPy electrode and achieves 84%. The electroactivity of PPy film falls as a result of cathodic polarization, but it can be regenerated by short anodic polarization pulse. The stability of the PPy film in 0.1 M NaCl is higher than in 0.1 M Na
2 SO
4. |
doi_str_mv | 10.1016/S0010-938X(98)00085-7 |
format | Article |
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2 SO
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2 SO
4.</description><subject>Applied sciences</subject><subject>Corrosion</subject><subject>Corrosion tests</subject><subject>Exact sciences and technology</subject><subject>Metals. Metallurgy</subject><subject>oxygen reduction</subject><subject>polypyrrole nickel</subject><subject>water deoxidation</subject><issn>0010-938X</issn><issn>1879-0496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LxDAQhoMouK7-BCEHET1Uk7TNx0l08QsWPKyCt5CmU4hkm5q0Qv-9XXfRo6cZhuedYR6ETim5ooTy6xUhlGQql-8XSl4SQmSZiT00o1KojBSK76PZL3KIjlL6mCA2TWbobtUP9YhDi7vgx26MMXjAJmHTYvBg-xhqwGvTQ3TGY9fiFoY-Tm0KfuhdaNMxOmiMT3Cyq3P09nD_unjKli-Pz4vbZWZzLvqMllIWNWcSqMpLEDKvhK1qUllKuc2JEEAbwQpCClPWlrNCKFVXBVVSMkPLfI7Ot3u7GD4HSL1eu2TBe9NCGJJmXCguBJ3AcgvaGFKK0OguurWJo6ZEb4zpH2N6o0MrqX-MaTHlznYHTLLGN9G01qW_MC8ZydmE3WwxmJ79chB1sg5aC7WLkzBdB_fPoW-MLX8k</recordid><startdate>19981101</startdate><enddate>19981101</enddate><creator>Biallozor, S</creator><creator>Zalewska, T</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>19981101</creationdate><title>Study on polypyrrole as an electrode material in neutral solutions</title><author>Biallozor, S ; Zalewska, T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-15884d628e1935e783b7cbd0bc116c3077e1f724004a5dc624799db419882a153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Corrosion</topic><topic>Corrosion tests</topic><topic>Exact sciences and technology</topic><topic>Metals. Metallurgy</topic><topic>oxygen reduction</topic><topic>polypyrrole nickel</topic><topic>water deoxidation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Biallozor, S</creatorcontrib><creatorcontrib>Zalewska, T</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Corrosion science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Biallozor, S</au><au>Zalewska, T</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study on polypyrrole as an electrode material in neutral solutions</atitle><jtitle>Corrosion science</jtitle><date>1998-11-01</date><risdate>1998</risdate><volume>40</volume><issue>11</issue><spage>1873</spage><epage>1881</epage><pages>1873-1881</pages><issn>0010-938X</issn><eissn>1879-0496</eissn><coden>CRRSAA</coden><abstract>A study of the polypyrrole (PPy) as an electrode material for cathodic reduction of dioxygen in water solutions depending on the substrate material was carried out. It has been found that the electroactivity of a PPy film strongly depends on the nature of a substrate, especially if the thickness of the PPy film is low. The efficiency coefficient of the dioxygen reduction on the Ni⧹PPy electrode is higher than the one on the Pt⧹PPy electrode and achieves 84%. The electroactivity of PPy film falls as a result of cathodic polarization, but it can be regenerated by short anodic polarization pulse. The stability of the PPy film in 0.1 M NaCl is higher than in 0.1 M Na
2 SO
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subjects | Applied sciences Corrosion Corrosion tests Exact sciences and technology Metals. Metallurgy oxygen reduction polypyrrole nickel water deoxidation |
title | Study on polypyrrole as an electrode material in neutral solutions |
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