On the reactions of Cu(II/I)ATP complexes with methyl radicals

The CuI/IIATP react with methyl radicals to form methane and methanol, where CuIATP reacts with •CH3 in a process that is surprisingly slow. The low-rate constant of this process is attributed to the significant rearrangement of the chelating ligand required for the transient's formation. These...

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Veröffentlicht in:	Journal of inorganic biochemistry 2022-09, Vol.234, p.111883-111883, Article 111883
Hauptverfasser:	Lerner, Ana, Meyerstein, Dan, Blahman, Alex, Saphier, Magal, Yardeni, Guy, Maimon, Eric, Kornweitz, Haya, Zilbermann, Israel
Format:	Artikel
Sprache:	eng
Schlagworte:	Adenosine triphosphate Copper complexes DFT Radicals Radiolysis Reaction mechanisms
Online-Zugang:	Volltext
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