Spin and valence states of manganese ions in manganese-doped yttrium orthoaluminate

Two paramagnetic charge states of manganese with total electron spin of S=5/2 (Mn 2+) and S=3/2 (Mn 4+) were identified by electron paramagnetic resonance (EPR) method in Mn doped YAlO 3. In addition to the allowed ΔM S =1 spin transitions, low field forbidden ΔM S =2 transitions were observed for b...

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Veröffentlicht in:	Solid state communications 1998-10, Vol.108 (8), p.549-554
Hauptverfasser:	Rakhimov, R.R., Wilkerson, A.L., Loutts, G.B., Noginov, M.A., Noginova, N., Lindsay, W., Ries, H.R.
Format:	Artikel
Sprache:	eng
Schlagworte:	B. crystal growth Condensed matter: electronic structure, electrical, magnetic, and optical properties D. spin dynamics E. electron paramagnetic resonance Electron paramagnetic resonance and relaxation Exact sciences and technology Iron group (3d) ions and impurities (ti-cu) Magnetic resonances and relaxations in condensed matter, mössbauer effect Physics valence fluctuations
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