Electrochemistry of powder material studied by means of the cavity microelectrode (CME)
The kinetic aspects of powder material electrochemistry can be studied using the cavity microelectrode (CME) as it allows carrying out voltammetry at scan rates between a few millivolts per second to several hundreds of volts per second. Thus, significant voltammogram characteristics-scan rate profi...
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| Veröffentlicht in: | Electrochimica acta 2001-09, Vol.47 (1), p.181-189 |
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| container_title | Electrochimica acta |
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| creator | Cachet-Vivier, C. Vivier, V. Cha, C.S. Nedelec, J.-Y. Yu, L.T. |
| description | The kinetic aspects of powder material electrochemistry can be studied using the cavity microelectrode (CME) as it allows carrying out voltammetry at scan rates between a few millivolts per second to several hundreds of volts per second. Thus, significant voltammogram characteristics-scan rate profiles can be drawn. Theoretical models suited to each material needs to be developed for their exploitation. First, we report significant results obtained with CME on powder materials. The materials studied were chosen for their wide variety of possible applications such as battery materials (polyaniline or Bi
2O
3, which modifies the electrochemical behavior of materials in which it is included), supercapacitor (carbon black), and for the electrocatalytic hydrogenation of organic compounds (PtO
2). Secondly, we briefly describe the general action for establishing models to obtain a better understanding of the electrochemical processes. |
| doi_str_mv | 10.1016/S0013-4686(01)00549-7 |
| format | Article |
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2O
3, which modifies the electrochemical behavior of materials in which it is included), supercapacitor (carbon black), and for the electrocatalytic hydrogenation of organic compounds (PtO
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2O
3, which modifies the electrochemical behavior of materials in which it is included), supercapacitor (carbon black), and for the electrocatalytic hydrogenation of organic compounds (PtO
2). Secondly, we briefly describe the general action for establishing models to obtain a better understanding of the electrochemical processes.</description><subject>Bi 2O 3</subject><subject>Carbon black</subject><subject>Cavity microelectrode</subject><subject>Chemistry</subject><subject>Electrochemistry</subject><subject>Electrochemistry of powder materials</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Kinetics and mechanism of reactions</subject><subject>Multilayer slab system</subject><subject>Polyaniline</subject><subject>PtO 2</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKs_QdiLYg-rkybZj5NIqR9Q8aDiMWSzszSyHzVJK_33ZrtFj57ChGfmnXkIOadwTYEmN68AlMU8yZIroBMAwfM4PSAjmqUsZpnID8noFzkmJ859AkCapDAiH_MatbedXmJjnLfbqKuiVfddoo0a5dEaVUfOr0uDZVRsowZV63rGLzHSamN8-DPadjjMKTG6mj3PJ6fkqFK1w7P9Oybv9_O32WO8eHl4mt0tYs0Z9zEK5JALyKuq4LykqBiUqqBTDqwQFAUPexdCK0UzAToXLGUiDYVOdKExZWNyOcxd2e5rjc7LcIbGulYtdmsnp0ma5BmIAIoBDLs6Z7GSK2saZbeSguw1yp1G2TuSQOVOo-wDLvYBymlVV1a12ri_Zk556Ou524HDcO3GoJVOG2w1lsYGM7LszD9JP0bAhq4</recordid><startdate>20010901</startdate><enddate>20010901</enddate><creator>Cachet-Vivier, C.</creator><creator>Vivier, V.</creator><creator>Cha, C.S.</creator><creator>Nedelec, J.-Y.</creator><creator>Yu, L.T.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20010901</creationdate><title>Electrochemistry of powder material studied by means of the cavity microelectrode (CME)</title><author>Cachet-Vivier, C. ; Vivier, V. ; Cha, C.S. ; Nedelec, J.-Y. ; Yu, L.T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c434t-e5e409509ffb44d1ea30dab12403b51e54013b5caa1850c9537357a18c6cbce73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Bi 2O 3</topic><topic>Carbon black</topic><topic>Cavity microelectrode</topic><topic>Chemistry</topic><topic>Electrochemistry</topic><topic>Electrochemistry of powder materials</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Kinetics and mechanism of reactions</topic><topic>Multilayer slab system</topic><topic>Polyaniline</topic><topic>PtO 2</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cachet-Vivier, C.</creatorcontrib><creatorcontrib>Vivier, V.</creatorcontrib><creatorcontrib>Cha, C.S.</creatorcontrib><creatorcontrib>Nedelec, J.-Y.</creatorcontrib><creatorcontrib>Yu, L.T.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cachet-Vivier, C.</au><au>Vivier, V.</au><au>Cha, C.S.</au><au>Nedelec, J.-Y.</au><au>Yu, L.T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemistry of powder material studied by means of the cavity microelectrode (CME)</atitle><jtitle>Electrochimica acta</jtitle><date>2001-09-01</date><risdate>2001</risdate><volume>47</volume><issue>1</issue><spage>181</spage><epage>189</epage><pages>181-189</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>The kinetic aspects of powder material electrochemistry can be studied using the cavity microelectrode (CME) as it allows carrying out voltammetry at scan rates between a few millivolts per second to several hundreds of volts per second. Thus, significant voltammogram characteristics-scan rate profiles can be drawn. Theoretical models suited to each material needs to be developed for their exploitation. First, we report significant results obtained with CME on powder materials. The materials studied were chosen for their wide variety of possible applications such as battery materials (polyaniline or Bi
2O
3, which modifies the electrochemical behavior of materials in which it is included), supercapacitor (carbon black), and for the electrocatalytic hydrogenation of organic compounds (PtO
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Bi 2O 3 Carbon black Cavity microelectrode Chemistry Electrochemistry Electrochemistry of powder materials Exact sciences and technology General and physical chemistry Kinetics and mechanism of reactions Multilayer slab system Polyaniline PtO 2 |
| title | Electrochemistry of powder material studied by means of the cavity microelectrode (CME) |
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