Grain boundary segregation and precipitation in aluminium alloys

The solute enrichment at the grain boundary determined by TEM with a nanoprobe can only be understood qualitatively. EDS-analysis in combination with electron diffraction proves that precipitates with a Mg/Si-ratio of approx1.3 and a structure similar to the Q-phase (at larger aging times) are prese...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Scripta materialia 2001-02, Vol.44 (2), p.281-286
Hauptverfasser: de Hass, M., De Hosson, J.Th.M.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 286
container_issue 2
container_start_page 281
container_title Scripta materialia
container_volume 44
creator de Hass, M.
De Hosson, J.Th.M.
description The solute enrichment at the grain boundary determined by TEM with a nanoprobe can only be understood qualitatively. EDS-analysis in combination with electron diffraction proves that precipitates with a Mg/Si-ratio of approx1.3 and a structure similar to the Q-phase (at larger aging times) are present at the grain boundaries of AA6061. The Cu-content is lower than the stoichiometric value, which may indicate that the Q-phase is preceded by the beta -phase. The model originally developed for 7XXX-series aluminium alloys is applied to AA6061 and AA7050. Predicted values of the GB precipitate growth are in fair agreement with experimental ones. Calculated inter-distances are in between measured longitudinal and transveral inter-distances. This is explained by the model assuming a square collector plate while a rectangular shape is expected.
doi_str_mv 10.1016/S1359-6462(00)00577-7
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_26759329</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1359646200005777</els_id><sourcerecordid>26759329</sourcerecordid><originalsourceid>FETCH-LOGICAL-c413t-4c8060b3e56e3c920f4b278b0bf4807c352a33a7b662818540955fe5ccdba55e3</originalsourceid><addsrcrecordid>eNqFkE1LxDAQhoMouK7-BKEgiB6qk-_2pLLoKix4UM8hTdMl0i-TVth_b3a7evU0w_C8M8yD0DmGGwxY3L5hyvNUMEGuAK4BuJSpPEAznEmSZoyLw9j_IsfoJIRPABCY4Bm6X3rt2qToxrbUfpMEu_Z2rQfXtYluy6T31rjeDdMkkroeG9e6sYld3W3CKTqqdB3s2b7O0cfT4_viOV29Ll8WD6vUMEyHlJkMBBTUcmGpyQlUrCAyK6CoWAbSUE40pVoWQpAMZ5xBznlluTFloTm3dI4up729775GGwbVuGBsXevWdmNQREieU5JHkE-g8V0I3laq966JvykMautL7XyprQwFoHa-lIy5i_0BHYyuK69b48JfOI9JwiJ1N1E2_vrtrFfBONsaW7poalBl5_658wM0236C</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>26759329</pqid></control><display><type>article</type><title>Grain boundary segregation and precipitation in aluminium alloys</title><source>Elsevier ScienceDirect Journals</source><creator>de Hass, M. ; De Hosson, J.Th.M.</creator><creatorcontrib>de Hass, M. ; De Hosson, J.Th.M.</creatorcontrib><description>The solute enrichment at the grain boundary determined by TEM with a nanoprobe can only be understood qualitatively. EDS-analysis in combination with electron diffraction proves that precipitates with a Mg/Si-ratio of approx1.3 and a structure similar to the Q-phase (at larger aging times) are present at the grain boundaries of AA6061. The Cu-content is lower than the stoichiometric value, which may indicate that the Q-phase is preceded by the beta -phase. The model originally developed for 7XXX-series aluminium alloys is applied to AA6061 and AA7050. Predicted values of the GB precipitate growth are in fair agreement with experimental ones. Calculated inter-distances are in between measured longitudinal and transveral inter-distances. This is explained by the model assuming a square collector plate while a rectangular shape is expected.</description><identifier>ISSN: 1359-6462</identifier><identifier>EISSN: 1872-8456</identifier><identifier>DOI: 10.1016/S1359-6462(00)00577-7</identifier><language>eng</language><publisher>New York, NY: Elsevier Ltd</publisher><subject>Aluminum alloys ; Applied sciences ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Grain boundaries ; Materials science ; Metals. Metallurgy ; Phase diagrams and microstructures developed by solidification and solid-solid phase transformations ; Physics ; Precipitation ; Segregation ; Solid-phase precipitation ; Transmission electron microscopy</subject><ispartof>Scripta materialia, 2001-02, Vol.44 (2), p.281-286</ispartof><rights>2001 Acta Metallurgica Inc.</rights><rights>2001 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c413t-4c8060b3e56e3c920f4b278b0bf4807c352a33a7b662818540955fe5ccdba55e3</citedby><cites>FETCH-LOGICAL-c413t-4c8060b3e56e3c920f4b278b0bf4807c352a33a7b662818540955fe5ccdba55e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S1359-6462(00)00577-7$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27907,27908,45978</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=901624$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>de Hass, M.</creatorcontrib><creatorcontrib>De Hosson, J.Th.M.</creatorcontrib><title>Grain boundary segregation and precipitation in aluminium alloys</title><title>Scripta materialia</title><description>The solute enrichment at the grain boundary determined by TEM with a nanoprobe can only be understood qualitatively. EDS-analysis in combination with electron diffraction proves that precipitates with a Mg/Si-ratio of approx1.3 and a structure similar to the Q-phase (at larger aging times) are present at the grain boundaries of AA6061. The Cu-content is lower than the stoichiometric value, which may indicate that the Q-phase is preceded by the beta -phase. The model originally developed for 7XXX-series aluminium alloys is applied to AA6061 and AA7050. Predicted values of the GB precipitate growth are in fair agreement with experimental ones. Calculated inter-distances are in between measured longitudinal and transveral inter-distances. This is explained by the model assuming a square collector plate while a rectangular shape is expected.</description><subject>Aluminum alloys</subject><subject>Applied sciences</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Grain boundaries</subject><subject>Materials science</subject><subject>Metals. Metallurgy</subject><subject>Phase diagrams and microstructures developed by solidification and solid-solid phase transformations</subject><subject>Physics</subject><subject>Precipitation</subject><subject>Segregation</subject><subject>Solid-phase precipitation</subject><subject>Transmission electron microscopy</subject><issn>1359-6462</issn><issn>1872-8456</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LxDAQhoMouK7-BKEgiB6qk-_2pLLoKix4UM8hTdMl0i-TVth_b3a7evU0w_C8M8yD0DmGGwxY3L5hyvNUMEGuAK4BuJSpPEAznEmSZoyLw9j_IsfoJIRPABCY4Bm6X3rt2qToxrbUfpMEu_Z2rQfXtYluy6T31rjeDdMkkroeG9e6sYld3W3CKTqqdB3s2b7O0cfT4_viOV29Ll8WD6vUMEyHlJkMBBTUcmGpyQlUrCAyK6CoWAbSUE40pVoWQpAMZ5xBznlluTFloTm3dI4up729775GGwbVuGBsXevWdmNQREieU5JHkE-g8V0I3laq966JvykMautL7XyprQwFoHa-lIy5i_0BHYyuK69b48JfOI9JwiJ1N1E2_vrtrFfBONsaW7poalBl5_658wM0236C</recordid><startdate>20010202</startdate><enddate>20010202</enddate><creator>de Hass, M.</creator><creator>De Hosson, J.Th.M.</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>8BQ</scope><scope>8FD</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20010202</creationdate><title>Grain boundary segregation and precipitation in aluminium alloys</title><author>de Hass, M. ; De Hosson, J.Th.M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c413t-4c8060b3e56e3c920f4b278b0bf4807c352a33a7b662818540955fe5ccdba55e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Aluminum alloys</topic><topic>Applied sciences</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Grain boundaries</topic><topic>Materials science</topic><topic>Metals. Metallurgy</topic><topic>Phase diagrams and microstructures developed by solidification and solid-solid phase transformations</topic><topic>Physics</topic><topic>Precipitation</topic><topic>Segregation</topic><topic>Solid-phase precipitation</topic><topic>Transmission electron microscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>de Hass, M.</creatorcontrib><creatorcontrib>De Hosson, J.Th.M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Scripta materialia</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Hass, M.</au><au>De Hosson, J.Th.M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Grain boundary segregation and precipitation in aluminium alloys</atitle><jtitle>Scripta materialia</jtitle><date>2001-02-02</date><risdate>2001</risdate><volume>44</volume><issue>2</issue><spage>281</spage><epage>286</epage><pages>281-286</pages><issn>1359-6462</issn><eissn>1872-8456</eissn><abstract>The solute enrichment at the grain boundary determined by TEM with a nanoprobe can only be understood qualitatively. EDS-analysis in combination with electron diffraction proves that precipitates with a Mg/Si-ratio of approx1.3 and a structure similar to the Q-phase (at larger aging times) are present at the grain boundaries of AA6061. The Cu-content is lower than the stoichiometric value, which may indicate that the Q-phase is preceded by the beta -phase. The model originally developed for 7XXX-series aluminium alloys is applied to AA6061 and AA7050. Predicted values of the GB precipitate growth are in fair agreement with experimental ones. Calculated inter-distances are in between measured longitudinal and transveral inter-distances. This is explained by the model assuming a square collector plate while a rectangular shape is expected.</abstract><cop>New York, NY</cop><pub>Elsevier Ltd</pub><doi>10.1016/S1359-6462(00)00577-7</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1359-6462
ispartof Scripta materialia, 2001-02, Vol.44 (2), p.281-286
issn 1359-6462
1872-8456
language eng
recordid cdi_proquest_miscellaneous_26759329
source Elsevier ScienceDirect Journals
subjects Aluminum alloys
Applied sciences
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Grain boundaries
Materials science
Metals. Metallurgy
Phase diagrams and microstructures developed by solidification and solid-solid phase transformations
Physics
Precipitation
Segregation
Solid-phase precipitation
Transmission electron microscopy
title Grain boundary segregation and precipitation in aluminium alloys
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T23%3A21%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Grain%20boundary%20segregation%20and%20precipitation%20in%20aluminium%20alloys&rft.jtitle=Scripta%20materialia&rft.au=de%20Hass,%20M.&rft.date=2001-02-02&rft.volume=44&rft.issue=2&rft.spage=281&rft.epage=286&rft.pages=281-286&rft.issn=1359-6462&rft.eissn=1872-8456&rft_id=info:doi/10.1016/S1359-6462(00)00577-7&rft_dat=%3Cproquest_cross%3E26759329%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=26759329&rft_id=info:pmid/&rft_els_id=S1359646200005777&rfr_iscdi=true