Rapid, Solid-State Metathesis Routes to Metal Carbides

A fast, convenient synthesis of metal carbides at lower temperatures and involving shorter reaction times than conventional methods would be sure to find widespread application in industry, where transition metal carbides are used for cutting tools, crucibles, and catalysts. Such a reaction, the fir...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Weinheim) 1998-07, Vol.10 (10), p.805-808
Hauptverfasser: Nartowski, Artur M., Parkin, Ivan P., Craven, Alan J., MacKenzie, Maureen
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 808
container_issue 10
container_start_page 805
container_title Advanced materials (Weinheim)
container_volume 10
creator Nartowski, Artur M.
Parkin, Ivan P.
Craven, Alan J.
MacKenzie, Maureen
description A fast, convenient synthesis of metal carbides at lower temperatures and involving shorter reaction times than conventional methods would be sure to find widespread application in industry, where transition metal carbides are used for cutting tools, crucibles, and catalysts. Such a reaction, the first solid‐state metathesis of transition metal carbides via a fast (10 s), single‐step reaction, is described here. The products are reported to be highly crystalline in many cases, with good elemental purity, and it is expected that the technique can be extended to mixed metal carbides.
doi_str_mv 10.1002/(SICI)1521-4095(199807)10:10<805::AID-ADMA805>3.0.CO;2-2
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_26742144</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>26742144</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3875-24ae1a68b38bb9cab01adcb3224ff7ef0ad6951469ab44c95403c18f59bb9eff3</originalsourceid><addsrcrecordid>eNqFkFtr20AQRpfSQl03_0FPIYGuM3uV1i0lRs7F4AvYCQnkYVhJK6pErhytTOJ_H7lK89JCnob55pvzcAg5ZTBgAPzkaDWJJ8dMcUYlGHXEjIkgPGYwZPAjAjUcjiZjOhrPRu3yUwxgEC--c8o_kN7b00fSAyMUNVpGn8kX7-8BwGjQPaKXdlNk34JVVRYZXTW2ccHMteOX84UPltW2cT5oqj9hGcS2TorM-a_kU25L7w5eZ59cn59dxZd0uriYxKMpTUUUKsqldczqKBFRkpjUJsBsliaCc5nnocvBZtooJrWxiZSpURJEyqJcmbbu8lz0yWHH3dTV49b5BteFT11Z2t-u2nrkOpScSdkWb7tiWlfe1y7HTV2sbb1DBrgXibgXiXsnuHeCncjujK07xFYkvopEgYDxAjnyFn3XoZ-K0u3-4b6H_T_1b9TSaUcvfOOe3-i2fkAdilDhzfwC9Ww5n1_yKcbiBSMalR8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>26742144</pqid></control><display><type>article</type><title>Rapid, Solid-State Metathesis Routes to Metal Carbides</title><source>Access via Wiley Online Library</source><creator>Nartowski, Artur M. ; Parkin, Ivan P. ; Craven, Alan J. ; MacKenzie, Maureen</creator><creatorcontrib>Nartowski, Artur M. ; Parkin, Ivan P. ; Craven, Alan J. ; MacKenzie, Maureen</creatorcontrib><description>A fast, convenient synthesis of metal carbides at lower temperatures and involving shorter reaction times than conventional methods would be sure to find widespread application in industry, where transition metal carbides are used for cutting tools, crucibles, and catalysts. Such a reaction, the first solid‐state metathesis of transition metal carbides via a fast (10 s), single‐step reaction, is described here. The products are reported to be highly crystalline in many cases, with good elemental purity, and it is expected that the technique can be extended to mixed metal carbides.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/(SICI)1521-4095(199807)10:10&lt;805::AID-ADMA805&gt;3.0.CO;2-2</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag GmbH</publisher><ispartof>Advanced materials (Weinheim), 1998-07, Vol.10 (10), p.805-808</ispartof><rights>1998 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2F%28SICI%291521-4095%28199807%2910%3A10%3C805%3A%3AAID-ADMA805%3E3.0.CO%3B2-2$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2F%28SICI%291521-4095%28199807%2910%3A10%3C805%3A%3AAID-ADMA805%3E3.0.CO%3B2-2$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Nartowski, Artur M.</creatorcontrib><creatorcontrib>Parkin, Ivan P.</creatorcontrib><creatorcontrib>Craven, Alan J.</creatorcontrib><creatorcontrib>MacKenzie, Maureen</creatorcontrib><title>Rapid, Solid-State Metathesis Routes to Metal Carbides</title><title>Advanced materials (Weinheim)</title><addtitle>Adv. Mater</addtitle><description>A fast, convenient synthesis of metal carbides at lower temperatures and involving shorter reaction times than conventional methods would be sure to find widespread application in industry, where transition metal carbides are used for cutting tools, crucibles, and catalysts. Such a reaction, the first solid‐state metathesis of transition metal carbides via a fast (10 s), single‐step reaction, is described here. The products are reported to be highly crystalline in many cases, with good elemental purity, and it is expected that the technique can be extended to mixed metal carbides.</description><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkFtr20AQRpfSQl03_0FPIYGuM3uV1i0lRs7F4AvYCQnkYVhJK6pErhytTOJ_H7lK89JCnob55pvzcAg5ZTBgAPzkaDWJJ8dMcUYlGHXEjIkgPGYwZPAjAjUcjiZjOhrPRu3yUwxgEC--c8o_kN7b00fSAyMUNVpGn8kX7-8BwGjQPaKXdlNk34JVVRYZXTW2ccHMteOX84UPltW2cT5oqj9hGcS2TorM-a_kU25L7w5eZ59cn59dxZd0uriYxKMpTUUUKsqldczqKBFRkpjUJsBsliaCc5nnocvBZtooJrWxiZSpURJEyqJcmbbu8lz0yWHH3dTV49b5BteFT11Z2t-u2nrkOpScSdkWb7tiWlfe1y7HTV2sbb1DBrgXibgXiXsnuHeCncjujK07xFYkvopEgYDxAjnyFn3XoZ-K0u3-4b6H_T_1b9TSaUcvfOOe3-i2fkAdilDhzfwC9Ww5n1_yKcbiBSMalR8</recordid><startdate>199807</startdate><enddate>199807</enddate><creator>Nartowski, Artur M.</creator><creator>Parkin, Ivan P.</creator><creator>Craven, Alan J.</creator><creator>MacKenzie, Maureen</creator><general>WILEY-VCH Verlag GmbH</general><general>WILEY‐VCH Verlag GmbH</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>199807</creationdate><title>Rapid, Solid-State Metathesis Routes to Metal Carbides</title><author>Nartowski, Artur M. ; Parkin, Ivan P. ; Craven, Alan J. ; MacKenzie, Maureen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3875-24ae1a68b38bb9cab01adcb3224ff7ef0ad6951469ab44c95403c18f59bb9eff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nartowski, Artur M.</creatorcontrib><creatorcontrib>Parkin, Ivan P.</creatorcontrib><creatorcontrib>Craven, Alan J.</creatorcontrib><creatorcontrib>MacKenzie, Maureen</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nartowski, Artur M.</au><au>Parkin, Ivan P.</au><au>Craven, Alan J.</au><au>MacKenzie, Maureen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rapid, Solid-State Metathesis Routes to Metal Carbides</atitle><jtitle>Advanced materials (Weinheim)</jtitle><addtitle>Adv. Mater</addtitle><date>1998-07</date><risdate>1998</risdate><volume>10</volume><issue>10</issue><spage>805</spage><epage>808</epage><pages>805-808</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>A fast, convenient synthesis of metal carbides at lower temperatures and involving shorter reaction times than conventional methods would be sure to find widespread application in industry, where transition metal carbides are used for cutting tools, crucibles, and catalysts. Such a reaction, the first solid‐state metathesis of transition metal carbides via a fast (10 s), single‐step reaction, is described here. The products are reported to be highly crystalline in many cases, with good elemental purity, and it is expected that the technique can be extended to mixed metal carbides.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag GmbH</pub><doi>10.1002/(SICI)1521-4095(199807)10:10&lt;805::AID-ADMA805&gt;3.0.CO;2-2</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0935-9648
ispartof Advanced materials (Weinheim), 1998-07, Vol.10 (10), p.805-808
issn 0935-9648
1521-4095
language eng
recordid cdi_proquest_miscellaneous_26742144
source Access via Wiley Online Library
title Rapid, Solid-State Metathesis Routes to Metal Carbides
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T20%3A45%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rapid,%20Solid-State%20Metathesis%20Routes%20to%20Metal%20Carbides&rft.jtitle=Advanced%20materials%20(Weinheim)&rft.au=Nartowski,%20Artur%20M.&rft.date=1998-07&rft.volume=10&rft.issue=10&rft.spage=805&rft.epage=808&rft.pages=805-808&rft.issn=0935-9648&rft.eissn=1521-4095&rft_id=info:doi/10.1002/(SICI)1521-4095(199807)10:10%3C805::AID-ADMA805%3E3.0.CO;2-2&rft_dat=%3Cproquest_cross%3E26742144%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=26742144&rft_id=info:pmid/&rfr_iscdi=true