Two-Dimensional Negative Thermal Expansion in a Facile and Low-Cost Oxalate-Based Metal–Organic Framework

Two-dimensional negative thermal expansion (NTE) is achieved in a tetragonal oxalate-based metal–organic framework (MOF), CdZrSr­(C2O4)4, within a temperature range from 123 to 398 K [space group I4̅m2, αa = −2.4(7) M K–1, αc = 11.3(3) M K–1, and αV = 6.4(1) M K–1]. By combining variable-temperature...

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Veröffentlicht in:	Inorganic chemistry 2022-06, Vol.61 (23), p.8634-8638
Hauptverfasser:	Ma, Rui, Liu, Zhanning, Cao, Yili, Li, Qiang, Lin, Kun, Ohara, Koji, Chen, Xin, Chen, Liang, Xu, Hankun, Deng, Jinxia, Xing, Xianran
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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