The rhombic honeycomb - a new mode of self-assembly in liquid crystalline soft matter
Rod-like liquid crystalline (LC) polyphilic compounds with a linear oligo(phenyleneethynylene) core, sticky glycerol groups at each end and two long alkyl side chains (C 20 -C 32 ) at opposite sides form rhombic honeycombs with inner angles around 60/120°, occurring between triangular and square til...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-06, Vol.58 (5), p.754-757 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Saeed, Azhar Poppe, Marco Wagner, Matthias B Hauche, Sebastian Anders, Christian Cao, Yu Zhang, Lei Tschierske, Carsten Liu, Feng |
| description | Rod-like liquid crystalline (LC) polyphilic compounds with a linear oligo(phenyleneethynylene) core, sticky glycerol groups at each end and two long alkyl side chains (C
20
-C
32
) at opposite sides form rhombic honeycombs with inner angles around 60/120°, occurring between triangular and square tiling patterns.
Self-assembly of rod-like molecules with sticky ends (blue) and lateral chains (red) depending on chain volume and strength of core-chain segregation, forms honeycombs with triangular (
p
6
mm
), rectangular (
c
2
mm
), and square (
p
4
mm
) cells. |
| doi_str_mv | 10.1039/d2cc01907h |
| format | Article |
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20
-C
32
) at opposite sides form rhombic honeycombs with inner angles around 60/120°, occurring between triangular and square tiling patterns.
Self-assembly of rod-like molecules with sticky ends (blue) and lateral chains (red) depending on chain volume and strength of core-chain segregation, forms honeycombs with triangular (
p
6
mm
), rectangular (
c
2
mm
), and square (
p
4
mm
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20
-C
32
) at opposite sides form rhombic honeycombs with inner angles around 60/120°, occurring between triangular and square tiling patterns.
Self-assembly of rod-like molecules with sticky ends (blue) and lateral chains (red) depending on chain volume and strength of core-chain segregation, forms honeycombs with triangular (
p
6
mm
), rectangular (
c
2
mm
), and square (
p
4
mm
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20
-C
32
) at opposite sides form rhombic honeycombs with inner angles around 60/120°, occurring between triangular and square tiling patterns.
Self-assembly of rod-like molecules with sticky ends (blue) and lateral chains (red) depending on chain volume and strength of core-chain segregation, forms honeycombs with triangular (
p
6
mm
), rectangular (
c
2
mm
), and square (
p
4
mm
) cells.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35648051</pmid><doi>10.1039/d2cc01907h</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-4880-824X</orcidid><orcidid>https://orcid.org/0000-0002-9134-8680</orcidid><orcidid>https://orcid.org/0000-0002-4163-3272</orcidid><orcidid>https://orcid.org/0000-0001-6224-5167</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2022-06, Vol.58 (5), p.754-757 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2672317811 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crystal structure Crystallinity Liquid crystals Self-assembly Tiling |
| title | The rhombic honeycomb - a new mode of self-assembly in liquid crystalline soft matter |
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