A Series of Soluble Thieno-Fused Coronene Nanoribbons of Precise Lengths

A Series of Soluble Thieno-Fused Coronene Nanoribbons of Precise Lengths

Among graphene nanoribbons (GNRs), reports on coronene-based GNRs were very rare, despite the unique optoelectronic properties of coronene. Herein, the synthesis of a series of structurally precise and soluble thieno-fused coronene nanoribbons (CR-1 to CR-4) with up to four coronene units connected...

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Veröffentlicht in:Journal of the American Chemical Society 2022-06, Vol.144 (22), p.9883-9892
Hauptverfasser: Yang, Xuan, Elbert, Sven M., Rominger, Frank, Mastalerz, Michael
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container_title Journal of the American Chemical Society
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creator Yang, Xuan
Elbert, Sven M.
Rominger, Frank
Mastalerz, Michael
description Among graphene nanoribbons (GNRs), reports on coronene-based GNRs were very rare, despite the unique optoelectronic properties of coronene. Herein, the synthesis of a series of structurally precise and soluble thieno-fused coronene nanoribbons (CR-1 to CR-4) with up to four coronene units connected through benzene rings along their K-regions is described by two different synthetic approaches. Due to the triptycene end-caps, all CRs are soluble, allowing the characterization of such structures in solution and the study of the length-dependent photophysical properties that are supported by theoretical calculations.
doi_str_mv 10.1021/jacs.2c02645
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title A Series of Soluble Thieno-Fused Coronene Nanoribbons of Precise Lengths
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