Preparation and mechanical properties of polypropylene-clay hybrids using a maleic anhydride-modified polypropylene oligomer
Polypropylene‐clay hybrids (PPCH) were prepared using a maleic anhydride‐modified PP oligomer (PP‐MA) as a compatibilizer. PP was melt‐blended with organophilic clay which was intercalated with PP‐MA. In these PPCHs, the particles of silicate layers were dispersed at the nanometer level. The particl...
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Veröffentlicht in: | Journal of applied polymer science 1998-01, Vol.67 (1), p.87-92 |
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creator | Hasegawa, Naoki Kawasumi, Masaya Kato, Makoto Usuki, Arimitsu Okada, Akane |
description | Polypropylene‐clay hybrids (PPCH) were prepared using a maleic anhydride‐modified PP oligomer (PP‐MA) as a compatibilizer. PP was melt‐blended with organophilic clay which was intercalated with PP‐MA. In these PPCHs, the particles of silicate layers were dispersed at the nanometer level. The particles became smaller and were dispersed more uniformly, as the ratio of PP‐MA to the clay was increased. The dynamic storage moduli of the PPCHs were higher than that of PP up to 130°C. For example, the modulus of the PPCH with 5 wt % clay and 22 wt % PP‐MA was 1.8 times higher compared to that of PP at 80°C. As the dispersibility of the clays was improved, the reinforcement effect of the clays increased. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 67: 87–92, 1998 |
doi_str_mv | 10.1002/(SICI)1097-4628(19980103)67:1<87::AID-APP10>3.0.CO;2-2 |
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PP was melt‐blended with organophilic clay which was intercalated with PP‐MA. In these PPCHs, the particles of silicate layers were dispersed at the nanometer level. The particles became smaller and were dispersed more uniformly, as the ratio of PP‐MA to the clay was increased. The dynamic storage moduli of the PPCHs were higher than that of PP up to 130°C. For example, the modulus of the PPCH with 5 wt % clay and 22 wt % PP‐MA was 1.8 times higher compared to that of PP at 80°C. As the dispersibility of the clays was improved, the reinforcement effect of the clays increased. © 1998 John Wiley & Sons, Inc. 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Appl. Polym. Sci</addtitle><description>Polypropylene‐clay hybrids (PPCH) were prepared using a maleic anhydride‐modified PP oligomer (PP‐MA) as a compatibilizer. PP was melt‐blended with organophilic clay which was intercalated with PP‐MA. In these PPCHs, the particles of silicate layers were dispersed at the nanometer level. The particles became smaller and were dispersed more uniformly, as the ratio of PP‐MA to the clay was increased. The dynamic storage moduli of the PPCHs were higher than that of PP up to 130°C. For example, the modulus of the PPCH with 5 wt % clay and 22 wt % PP‐MA was 1.8 times higher compared to that of PP at 80°C. As the dispersibility of the clays was improved, the reinforcement effect of the clays increased. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 67: 87–92, 1998</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkd1rE0EUxRdRMFb_h30QaR82zkd2ZidKIaxNDZQmoLaPl9mZu83ofnUmwS74x7trakAUfBq4c87vXs6JonNKppQQ9vb00ypfnVGiZDITLDulSmWEEn4m5Jy-z-R8vlh9SBabDSXnfEqm-fodS9iTaHK0PI0mA4gmmVLp8-hFCF8JoTQlYhL92HjstNc71zaxbmxco9nqxhldxZ1vO_Q7hyFuy7hrq36c9BU2mJhK9_G2L7yzId4H19zFOq51hc4MmG1vhw9M6ta60qH90xy3lbtra_Qvo2elrgK-enxPoi_Li8_5x-RqfbnKF1eJSSknSVZIQ4nVtEQz02g50VwXpVBEC6SpkDJLKVOCoWWaW5uWVhWFKmaWU4NS8pPozYE7nHC_x7CD2gWDVaUbbPcBmJBUUcUG4c1BaHwbgscSOu9q7XugBMYyAMYyYEwWxmThdxkgJFDIJMBQBvwqAzgQyNfAYAS_frxAhyHa0uvGuHCkM5JJIWaD7PYg--4q7P9a_r_d_1p9GAzk5EB2YYcPR7L23wY3lyncXl9CmqrN8uZ6CZz_BDs7vIk</recordid><startdate>19980103</startdate><enddate>19980103</enddate><creator>Hasegawa, Naoki</creator><creator>Kawasumi, Masaya</creator><creator>Kato, Makoto</creator><creator>Usuki, Arimitsu</creator><creator>Okada, Akane</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19980103</creationdate><title>Preparation and mechanical properties of polypropylene-clay hybrids using a maleic anhydride-modified polypropylene oligomer</title><author>Hasegawa, Naoki ; Kawasumi, Masaya ; Kato, Makoto ; Usuki, Arimitsu ; Okada, Akane</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5130-8b7c10da1fec4aed30a3abf690a6e156778512962ed2a3dd5fd9bb9b4d31ce773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hasegawa, Naoki</creatorcontrib><creatorcontrib>Kawasumi, Masaya</creatorcontrib><creatorcontrib>Kato, Makoto</creatorcontrib><creatorcontrib>Usuki, Arimitsu</creatorcontrib><creatorcontrib>Okada, Akane</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hasegawa, Naoki</au><au>Kawasumi, Masaya</au><au>Kato, Makoto</au><au>Usuki, Arimitsu</au><au>Okada, Akane</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and mechanical properties of polypropylene-clay hybrids using a maleic anhydride-modified polypropylene oligomer</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1998-01-03</date><risdate>1998</risdate><volume>67</volume><issue>1</issue><spage>87</spage><epage>92</epage><pages>87-92</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Polypropylene‐clay hybrids (PPCH) were prepared using a maleic anhydride‐modified PP oligomer (PP‐MA) as a compatibilizer. PP was melt‐blended with organophilic clay which was intercalated with PP‐MA. In these PPCHs, the particles of silicate layers were dispersed at the nanometer level. The particles became smaller and were dispersed more uniformly, as the ratio of PP‐MA to the clay was increased. The dynamic storage moduli of the PPCHs were higher than that of PP up to 130°C. For example, the modulus of the PPCH with 5 wt % clay and 22 wt % PP‐MA was 1.8 times higher compared to that of PP at 80°C. As the dispersibility of the clays was improved, the reinforcement effect of the clays increased. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 67: 87–92, 1998</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/(SICI)1097-4628(19980103)67:1<87::AID-APP10>3.0.CO;2-2</doi><tpages>6</tpages></addata></record> |
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subjects | Applied sciences Composites Exact sciences and technology Forms of application and semi-finished materials Polymer industry, paints, wood Technology of polymers |
title | Preparation and mechanical properties of polypropylene-clay hybrids using a maleic anhydride-modified polypropylene oligomer |
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