Functional Covalent Layer-by-Layer Thin Films by [2 + 2] Cycloaddition–Retroelectrocyclization

Functional Covalent Layer-by-Layer Thin Films by [2 + 2] Cycloaddition–Retroelectrocyclization

Covalent layer-by-layer (LbL) thin films with the well-defined charge-transfer (CT) chromophores were fabricated by the highly efficient [2 + 2] cycloaddition–retroelectrocyclization (CA–RE) reaction between the dialkylaniline-substituted alkynes and 7,7,8,8-tetracyanoquinodimethane (TCNQ) moieties....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ACS macro letters 2018-06, Vol.7 (6), p.716-719
Hauptverfasser: Fujita, Hiroyuki, Michinobu, Tsuyoshi
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 719
container_issue 6
container_start_page 716
container_title ACS macro letters
container_volume 7
creator Fujita, Hiroyuki
Michinobu, Tsuyoshi
description Covalent layer-by-layer (LbL) thin films with the well-defined charge-transfer (CT) chromophores were fabricated by the highly efficient [2 + 2] cycloaddition–retroelectrocyclization (CA–RE) reaction between the dialkylaniline-substituted alkynes and 7,7,8,8-tetracyanoquinodimethane (TCNQ) moieties. The resulting thin films showed potent redox activities and Ag+ ion sensing ability due to the formed CT chromophores.
doi_str_mv 10.1021/acsmacrolett.8b00365
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2671270245</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2671270245</sourcerecordid><originalsourceid>FETCH-LOGICAL-a458t-a1c77523ce707b801d982023efa5839c0711dc62dd4ef7b1afa74a5112211153</originalsourceid><addsrcrecordid>eNp9kNFKwzAUhoMobsy9gUguBenMSZqmvZThVBgIsjuRmKYpdqTNbFqhXvkOvqFPYuum7Mpzc344__8f-BA6BTIDQuFSaV8qXTtrmmYWp4SwiB-gMYUIAog4O9zTIzT1fk364RHESXiMRoxHjCacjdHzoq10U7hKWTx3b8qaqsFL1Zk6SLvgR-DVS1HhRWFLj9MOP1J8gekTnnfaOpVlxZD--vh8ME3tjDW6X7q_Fe9quJygo1xZb6a7PUGrxfVqfhss72_u5lfLQIU8bgIFWghOmTaCiDQmkCUxJZSZXPGYJZoIgExHNMtCk4sUVK5EqDgApQDA2QSdb2s3tXttjW9kWXhtrFWVca2XNBJABaHhYA231p6f97XJ5aYuSlV3Eogc6Mp9unJHt4-d7T60aWmyv9Avy95AtoY-LteurXum_v_Ob2lYimY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2671270245</pqid></control><display><type>article</type><title>Functional Covalent Layer-by-Layer Thin Films by [2 + 2] Cycloaddition–Retroelectrocyclization</title><source>American Chemical Society Publications</source><creator>Fujita, Hiroyuki ; Michinobu, Tsuyoshi</creator><creatorcontrib>Fujita, Hiroyuki ; Michinobu, Tsuyoshi</creatorcontrib><description>Covalent layer-by-layer (LbL) thin films with the well-defined charge-transfer (CT) chromophores were fabricated by the highly efficient [2 + 2] cycloaddition–retroelectrocyclization (CA–RE) reaction between the dialkylaniline-substituted alkynes and 7,7,8,8-tetracyanoquinodimethane (TCNQ) moieties. The resulting thin films showed potent redox activities and Ag+ ion sensing ability due to the formed CT chromophores.</description><identifier>ISSN: 2161-1653</identifier><identifier>EISSN: 2161-1653</identifier><identifier>DOI: 10.1021/acsmacrolett.8b00365</identifier><identifier>PMID: 35632953</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>ACS macro letters, 2018-06, Vol.7 (6), p.716-719</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a458t-a1c77523ce707b801d982023efa5839c0711dc62dd4ef7b1afa74a5112211153</citedby><cites>FETCH-LOGICAL-a458t-a1c77523ce707b801d982023efa5839c0711dc62dd4ef7b1afa74a5112211153</cites><orcidid>0000-0001-6948-1189</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acsmacrolett.8b00365$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acsmacrolett.8b00365$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35632953$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fujita, Hiroyuki</creatorcontrib><creatorcontrib>Michinobu, Tsuyoshi</creatorcontrib><title>Functional Covalent Layer-by-Layer Thin Films by [2 + 2] Cycloaddition–Retroelectrocyclization</title><title>ACS macro letters</title><addtitle>ACS Macro Lett</addtitle><description>Covalent layer-by-layer (LbL) thin films with the well-defined charge-transfer (CT) chromophores were fabricated by the highly efficient [2 + 2] cycloaddition–retroelectrocyclization (CA–RE) reaction between the dialkylaniline-substituted alkynes and 7,7,8,8-tetracyanoquinodimethane (TCNQ) moieties. The resulting thin films showed potent redox activities and Ag+ ion sensing ability due to the formed CT chromophores.</description><issn>2161-1653</issn><issn>2161-1653</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kNFKwzAUhoMobsy9gUguBenMSZqmvZThVBgIsjuRmKYpdqTNbFqhXvkOvqFPYuum7Mpzc344__8f-BA6BTIDQuFSaV8qXTtrmmYWp4SwiB-gMYUIAog4O9zTIzT1fk364RHESXiMRoxHjCacjdHzoq10U7hKWTx3b8qaqsFL1Zk6SLvgR-DVS1HhRWFLj9MOP1J8gekTnnfaOpVlxZD--vh8ME3tjDW6X7q_Fe9quJygo1xZb6a7PUGrxfVqfhss72_u5lfLQIU8bgIFWghOmTaCiDQmkCUxJZSZXPGYJZoIgExHNMtCk4sUVK5EqDgApQDA2QSdb2s3tXttjW9kWXhtrFWVca2XNBJABaHhYA231p6f97XJ5aYuSlV3Eogc6Mp9unJHt4-d7T60aWmyv9Avy95AtoY-LteurXum_v_Ob2lYimY</recordid><startdate>20180619</startdate><enddate>20180619</enddate><creator>Fujita, Hiroyuki</creator><creator>Michinobu, Tsuyoshi</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6948-1189</orcidid></search><sort><creationdate>20180619</creationdate><title>Functional Covalent Layer-by-Layer Thin Films by [2 + 2] Cycloaddition–Retroelectrocyclization</title><author>Fujita, Hiroyuki ; Michinobu, Tsuyoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a458t-a1c77523ce707b801d982023efa5839c0711dc62dd4ef7b1afa74a5112211153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Fujita, Hiroyuki</creatorcontrib><creatorcontrib>Michinobu, Tsuyoshi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS macro letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fujita, Hiroyuki</au><au>Michinobu, Tsuyoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Functional Covalent Layer-by-Layer Thin Films by [2 + 2] Cycloaddition–Retroelectrocyclization</atitle><jtitle>ACS macro letters</jtitle><addtitle>ACS Macro Lett</addtitle><date>2018-06-19</date><risdate>2018</risdate><volume>7</volume><issue>6</issue><spage>716</spage><epage>719</epage><pages>716-719</pages><issn>2161-1653</issn><eissn>2161-1653</eissn><abstract>Covalent layer-by-layer (LbL) thin films with the well-defined charge-transfer (CT) chromophores were fabricated by the highly efficient [2 + 2] cycloaddition–retroelectrocyclization (CA–RE) reaction between the dialkylaniline-substituted alkynes and 7,7,8,8-tetracyanoquinodimethane (TCNQ) moieties. The resulting thin films showed potent redox activities and Ag+ ion sensing ability due to the formed CT chromophores.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>35632953</pmid><doi>10.1021/acsmacrolett.8b00365</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-6948-1189</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 2161-1653
ispartof ACS macro letters, 2018-06, Vol.7 (6), p.716-719
issn 2161-1653
2161-1653
language eng
recordid cdi_proquest_miscellaneous_2671270245
source American Chemical Society Publications
title Functional Covalent Layer-by-Layer Thin Films by [2 + 2] Cycloaddition–Retroelectrocyclization
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T19%3A48%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Functional%20Covalent%20Layer-by-Layer%20Thin%20Films%20by%20%5B2%20+%202%5D%20Cycloaddition%E2%80%93Retroelectrocyclization&rft.jtitle=ACS%20macro%20letters&rft.au=Fujita,%20Hiroyuki&rft.date=2018-06-19&rft.volume=7&rft.issue=6&rft.spage=716&rft.epage=719&rft.pages=716-719&rft.issn=2161-1653&rft.eissn=2161-1653&rft_id=info:doi/10.1021/acsmacrolett.8b00365&rft_dat=%3Cproquest_cross%3E2671270245%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2671270245&rft_id=info:pmid/35632953&rfr_iscdi=true