Photodecomposition of 1,1,2-trichloroethane: spectroscopic evidence for vinyl formation on Pt(111)

High-resolution electron energy loss spectroscopy (HREELS) and temperature programmed desorption (TPD) were applied to the study of 1,1,2-trichloroethane adsorbed on Pt(111) and its reaction products. Adsorption at 85 K occurred molecularly, as verified by HREELS and TDS measurements. Upon heating,...

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Veröffentlicht in:	Surface science 1998, Vol.396 (1), p.422-430
Hauptverfasser:	Hsiao, G.S., Erley, W., Ibach, H.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Atomic and molecular physics Chemistry Chlorocarbon Diffuse spectra predissociation, photodissociation Electron energy loss spectroscopy Exact sciences and technology General and physical chemistry Low index single crystal surfaces Molecular properties and interactions with photons Photochemistry Photon interactions with molecules Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Physics Platinum Surface chemical reaction Thermal desorption spectroscopy
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