Interface structure of faceted lath-shaped Cr precipitates in a Cu–0.33 wt% Cr alloy

The interface structure of lath-shaped, faceted Cr-rich precipitates in a Cu–0.33 wt%Cr alloy was investigated by transmission electron microscopy using diffraction contrast and weak beam dark field imaging techniques. The lath axis was aligned precisely with the [5 6 ̄ 1] f invariant line direction...

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Veröffentlicht in:Acta Materialia 1998-03, Vol.46 (6), p.2063-2081
Hauptverfasser: Luo, C.P., Dahmen, U.
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description The interface structure of lath-shaped, faceted Cr-rich precipitates in a Cu–0.33 wt%Cr alloy was investigated by transmission electron microscopy using diffraction contrast and weak beam dark field imaging techniques. The lath axis was aligned precisely with the [5 6 ̄ 1] f invariant line direction, and its cross-sectional shape was characterized by four distinct facets with different defect contents. The major facet near (335) f appeared defect-free. The (111) f and (552) f facets showed a single set of ledges with a step height of ∼1.1 nm and an associated displacement vector along ∼[335] f. The curved ∼(44 3 ̄ ) f side facets contained an array of dislocations spaced ∼8.1 nm apart with a Burgers vector that could reasonably be characterized as 1/3[111] f or 1/2[110] b, i.e. as d.s.c. lattice dislocations accommodating the misfit in interplanar spacing of the parallel close-packed planes in the two phases. A detailed model of the interface is in excellent agreement with the observed defect structure and the previously determined crystallographic characteristics. The model shows that the major facet near (335) f which appears to be defect free, actually contains a closely spaced array of dislocations in near-screw orientation. The uniform ledge height of ∼1.1 nm in all interfaces is the plane spacing of the primary O-lattice planes of Zhang and Purdy.
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The lath axis was aligned precisely with the [5 6 ̄ 1] f invariant line direction, and its cross-sectional shape was characterized by four distinct facets with different defect contents. The major facet near (335) f appeared defect-free. The (111) f and (552) f facets showed a single set of ledges with a step height of ∼1.1 nm and an associated displacement vector along ∼[335] f. The curved ∼(44 3 ̄ ) f side facets contained an array of dislocations spaced ∼8.1 nm apart with a Burgers vector that could reasonably be characterized as 1/3[111] f or 1/2[110] b, i.e. as d.s.c. lattice dislocations accommodating the misfit in interplanar spacing of the parallel close-packed planes in the two phases. A detailed model of the interface is in excellent agreement with the observed defect structure and the previously determined crystallographic characteristics. 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Metallurgy</topic><topic>MICROSTRUCTURE</topic><topic>Phase diagrams and microstructures developed by solidification and solid-solid phase transformations</topic><topic>Physics</topic><topic>PRECIPITATION</topic><topic>Solid-phase precipitation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Luo, C.P.</creatorcontrib><creatorcontrib>Dahmen, U.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>OSTI.GOV</collection><jtitle>Acta Materialia</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Luo, C.P.</au><au>Dahmen, U.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interface structure of faceted lath-shaped Cr precipitates in a Cu–0.33 wt% Cr alloy</atitle><jtitle>Acta Materialia</jtitle><date>1998-03-23</date><risdate>1998</risdate><volume>46</volume><issue>6</issue><spage>2063</spage><epage>2081</epage><pages>2063-2081</pages><issn>1359-6454</issn><eissn>1873-2453</eissn><abstract>The interface structure of lath-shaped, faceted Cr-rich precipitates in a Cu–0.33 wt%Cr alloy was investigated by transmission electron microscopy using diffraction contrast and weak beam dark field imaging techniques. The lath axis was aligned precisely with the [5 6 ̄ 1] f invariant line direction, and its cross-sectional shape was characterized by four distinct facets with different defect contents. The major facet near (335) f appeared defect-free. The (111) f and (552) f facets showed a single set of ledges with a step height of ∼1.1 nm and an associated displacement vector along ∼[335] f. The curved ∼(44 3 ̄ ) f side facets contained an array of dislocations spaced ∼8.1 nm apart with a Burgers vector that could reasonably be characterized as 1/3[111] f or 1/2[110] b, i.e. as d.s.c. lattice dislocations accommodating the misfit in interplanar spacing of the parallel close-packed planes in the two phases. A detailed model of the interface is in excellent agreement with the observed defect structure and the previously determined crystallographic characteristics. The model shows that the major facet near (335) f which appears to be defect free, actually contains a closely spaced array of dislocations in near-screw orientation. The uniform ledge height of ∼1.1 nm in all interfaces is the plane spacing of the primary O-lattice planes of Zhang and Purdy.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S1359-6454(97)00380-7</doi><tpages>19</tpages></addata></record>
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subjects Applied sciences
CHROMIUM ALLOYS
COPPER BASE ALLOYS
Cross-disciplinary physics: materials science
rheology
CRYSTAL DEFECTS
Exact sciences and technology
INTERFACES
MATERIALS SCIENCE
Metals. Metallurgy
MICROSTRUCTURE
Phase diagrams and microstructures developed by solidification and solid-solid phase transformations
Physics
PRECIPITATION
Solid-phase precipitation
title Interface structure of faceted lath-shaped Cr precipitates in a Cu–0.33 wt% Cr alloy
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