New macromolecules for solid polymeric electrolytes
The polyphosphazene MEEP, [NP(OCH 2CH 2OCH 2CH 2OCH 3) 2] n , was first reported 12 years ago as a significant advance in the design of solid polymer electrolytes (P. M. Blonsky, D. F. Shriver, P. E. Austin and H. R Allcock, J. Am. Chem. Soc. 106, 6854 (1984)) [1]. Since that time, more than 30 new...
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| Veröffentlicht in: | Electrochimica acta 1998-01, Vol.43 (10), p.1145-1150 |
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| container_title | Electrochimica acta |
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| creator | Allcock, Harry R. Napierala, Mark E. Olmeijer, David L. Cameron, Charles G. Kuharcik, Susan E. Reed, Carey S. O’Connor, Stephen J.M. |
| description | The polyphosphazene MEEP, [NP(OCH
2CH
2OCH
2CH
2OCH
3)
2]
n
, was first reported 12 years ago as a significant advance in the design of solid polymer electrolytes (P. M. Blonsky, D. F. Shriver, P. E. Austin and H. R Allcock, J. Am. Chem. Soc.
106, 6854 (1984))
[1]. Since that time, more than 30 new polymers have been synthesized in our laboratory, which build on the basic structure and theory developed for MEEP. The new polymers possess a phosphazene backbone, which is the basis of the molecular flexibility, with a variety of different alkyl ether and alkoxy side groups. The ionic conductivity of these polymers in the presence of lithium triflate has been studied as a function of the different polymer side groups. Several systems that improve on the properties of MEEP have been identified. The behaviour of selected polymers in operating rechargeable batteries has also been investigated. |
| doi_str_mv | 10.1016/S0013-4686(97)10012-3 |
| format | Article |
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2CH
2OCH
2CH
2OCH
3)
2]
n
, was first reported 12 years ago as a significant advance in the design of solid polymer electrolytes (P. M. Blonsky, D. F. Shriver, P. E. Austin and H. R Allcock, J. Am. Chem. Soc.
106, 6854 (1984))
[1]. Since that time, more than 30 new polymers have been synthesized in our laboratory, which build on the basic structure and theory developed for MEEP. The new polymers possess a phosphazene backbone, which is the basis of the molecular flexibility, with a variety of different alkyl ether and alkoxy side groups. The ionic conductivity of these polymers in the presence of lithium triflate has been studied as a function of the different polymer side groups. Several systems that improve on the properties of MEEP have been identified. The behaviour of selected polymers in operating rechargeable batteries has also been investigated.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/S0013-4686(97)10012-3</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; batteries ; Chemistry ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrochemistry ; electrolytes ; Exact sciences and technology ; General and physical chemistry ; ionic conduction ; polymers ; polyphosphazenes ; Properties of electrolytes: conductivity</subject><ispartof>Electrochimica acta, 1998-01, Vol.43 (10), p.1145-1150</ispartof><rights>1997 Elsevier Science Ltd</rights><rights>1998 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c404t-9f11c4326f3670b1f85804b054db39d80c8da37c7bdfa7ec2110a0dd47899f683</citedby><cites>FETCH-LOGICAL-c404t-9f11c4326f3670b1f85804b054db39d80c8da37c7bdfa7ec2110a0dd47899f683</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0013468697100123$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,3537,23909,23910,25118,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2329168$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Allcock, Harry R.</creatorcontrib><creatorcontrib>Napierala, Mark E.</creatorcontrib><creatorcontrib>Olmeijer, David L.</creatorcontrib><creatorcontrib>Cameron, Charles G.</creatorcontrib><creatorcontrib>Kuharcik, Susan E.</creatorcontrib><creatorcontrib>Reed, Carey S.</creatorcontrib><creatorcontrib>O’Connor, Stephen J.M.</creatorcontrib><title>New macromolecules for solid polymeric electrolytes</title><title>Electrochimica acta</title><description>The polyphosphazene MEEP, [NP(OCH
2CH
2OCH
2CH
2OCH
3)
2]
n
, was first reported 12 years ago as a significant advance in the design of solid polymer electrolytes (P. M. Blonsky, D. F. Shriver, P. E. Austin and H. R Allcock, J. Am. Chem. Soc.
106, 6854 (1984))
[1]. Since that time, more than 30 new polymers have been synthesized in our laboratory, which build on the basic structure and theory developed for MEEP. The new polymers possess a phosphazene backbone, which is the basis of the molecular flexibility, with a variety of different alkyl ether and alkoxy side groups. The ionic conductivity of these polymers in the presence of lithium triflate has been studied as a function of the different polymer side groups. Several systems that improve on the properties of MEEP have been identified. The behaviour of selected polymers in operating rechargeable batteries has also been investigated.</description><subject>Applied sciences</subject><subject>batteries</subject><subject>Chemistry</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrochemistry</subject><subject>electrolytes</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>ionic conduction</subject><subject>polymers</subject><subject>polyphosphazenes</subject><subject>Properties of electrolytes: conductivity</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFUMtKBDEQDKLguvoJwhxE9DDamWTzOIksvmDRg3oOmTwgMrNZk1ll_97sg716aoqu6uoqhM4x3GDA7PYdAJOaMsGuJL_GBTU1OUAjLDipiZjIQzTaU47RSc5fAMAZhxEir-636rVJsY-dM8vO5crHVOXYBVstYrfqXQqmcmU5pAIHl0_Rkddddme7OUafjw8f0-d69vb0Mr2f1YYCHWrpMTaUNMyTYtViLyYCaAsTalsirQAjrCbc8NZ6zZ1pMAYN1lIupPRMkDG63N5dpPi9dHlQfcjGdZ2eu7jMqmFMAqW0ECdbYomRc3JeLVLodVopDGpdkdpUpNb5leRqU5EiRXexM9DZ6M4nPTch78UNaSTe_HG3pbkS9ie4pLIJbm6cDam0omwM_xj9AVFxegk</recordid><startdate>19980101</startdate><enddate>19980101</enddate><creator>Allcock, Harry R.</creator><creator>Napierala, Mark E.</creator><creator>Olmeijer, David L.</creator><creator>Cameron, Charles G.</creator><creator>Kuharcik, Susan E.</creator><creator>Reed, Carey S.</creator><creator>O’Connor, Stephen J.M.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>19980101</creationdate><title>New macromolecules for solid polymeric electrolytes</title><author>Allcock, Harry R. ; Napierala, Mark E. ; Olmeijer, David L. ; Cameron, Charles G. ; Kuharcik, Susan E. ; Reed, Carey S. ; O’Connor, Stephen J.M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c404t-9f11c4326f3670b1f85804b054db39d80c8da37c7bdfa7ec2110a0dd47899f683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>batteries</topic><topic>Chemistry</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrochemistry</topic><topic>electrolytes</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>ionic conduction</topic><topic>polymers</topic><topic>polyphosphazenes</topic><topic>Properties of electrolytes: conductivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Allcock, Harry R.</creatorcontrib><creatorcontrib>Napierala, Mark E.</creatorcontrib><creatorcontrib>Olmeijer, David L.</creatorcontrib><creatorcontrib>Cameron, Charles G.</creatorcontrib><creatorcontrib>Kuharcik, Susan E.</creatorcontrib><creatorcontrib>Reed, Carey S.</creatorcontrib><creatorcontrib>O’Connor, Stephen J.M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Allcock, Harry R.</au><au>Napierala, Mark E.</au><au>Olmeijer, David L.</au><au>Cameron, Charles G.</au><au>Kuharcik, Susan E.</au><au>Reed, Carey S.</au><au>O’Connor, Stephen J.M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New macromolecules for solid polymeric electrolytes</atitle><jtitle>Electrochimica acta</jtitle><date>1998-01-01</date><risdate>1998</risdate><volume>43</volume><issue>10</issue><spage>1145</spage><epage>1150</epage><pages>1145-1150</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>The polyphosphazene MEEP, [NP(OCH
2CH
2OCH
2CH
2OCH
3)
2]
n
, was first reported 12 years ago as a significant advance in the design of solid polymer electrolytes (P. M. Blonsky, D. F. Shriver, P. E. Austin and H. R Allcock, J. Am. Chem. Soc.
106, 6854 (1984))
[1]. Since that time, more than 30 new polymers have been synthesized in our laboratory, which build on the basic structure and theory developed for MEEP. The new polymers possess a phosphazene backbone, which is the basis of the molecular flexibility, with a variety of different alkyl ether and alkoxy side groups. The ionic conductivity of these polymers in the presence of lithium triflate has been studied as a function of the different polymer side groups. Several systems that improve on the properties of MEEP have been identified. The behaviour of selected polymers in operating rechargeable batteries has also been investigated.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0013-4686(97)10012-3</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 1998-01, Vol.43 (10), p.1145-1150 |
| issn | 0013-4686 1873-3859 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences batteries Chemistry Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrochemistry electrolytes Exact sciences and technology General and physical chemistry ionic conduction polymers polyphosphazenes Properties of electrolytes: conductivity |
| title | New macromolecules for solid polymeric electrolytes |
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