Fast Controlled Living Polymerization of Arylisocyanide Initiated by Aromatic Nucleophile Adduct of Nickel Isocyanide Complex

The fast living polymerization of chiral arylisocyanide in the presence of the aromatic nucleophile adduct of tetra(t-butylisocyano)nickel(II) complex as an initiator gave the predominantly one-handed helical polyisocyanide with narrow polydispersity. X-ray crystal structures of initiators and MALDI...

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Veröffentlicht in:ACS macro letters 2013-10, Vol.2 (10), p.906-911
Hauptverfasser: Asaoka, Sadayuki, Joza, Ayako, Minagawa, Sakiko, Song, Lijun, Suzuki, Yukimitsu, Iyoda, Tomokazu
Format: Artikel
Sprache:eng
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