Miscibility of polystyrene with poly(ethylene oxide) and poly(ethylene glycol)
The intrinsic viscosity of polystyrene–poly(ethylene oxide) (PS–PEO) and PS–poly(ethylene glycol) (PEG) blends have been measured in benzene as a function of blend composition for various molecular weights of PEO and PEG at 303.15 K. The compatibility of polymer pairs in solution were determined on...
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| Veröffentlicht in: | Journal of applied polymer science 1998-08, Vol.69 (8), p.1471-1482 |
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| container_title | Journal of applied polymer science |
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| creator | Abdel-Azim, Abdel-Azim A. Atta, Aiman M. Farahat, Medhat S. Boutros, Wagdy Y. |
| description | The intrinsic viscosity of polystyrene–poly(ethylene oxide) (PS–PEO) and PS–poly(ethylene glycol) (PEG) blends have been measured in benzene as a function of blend composition for various molecular weights of PEO and PEG at 303.15 K. The compatibility of polymer pairs in solution were determined on the basis of the interaction parameter term, Δb, and the difference between the experimental and theoretical weight‐average intrinsic viscosities of the two polymers, Δ[η]. The theoretical weight‐average intrinsic viscosities were calculated by interpolation of the individual intrinsic viscosities of the blend components. The compatibility data based on [η] determined by a single specific viscosity measurement, as a quick method for the determination of the intrinsic viscosity, were compared with that obtained from [η] determined via the Huggins equation. The effect of molecular weights of the blend components and the polymer structure on the extent of compatibility was studied. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 1471–1482, 1998 |
| doi_str_mv | 10.1002/(SICI)1097-4628(19980822)69:8<1471::AID-APP1>3.0.CO;2-9 |
| format | Article |
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The compatibility of polymer pairs in solution were determined on the basis of the interaction parameter term, Δb, and the difference between the experimental and theoretical weight‐average intrinsic viscosities of the two polymers, Δ[η]. The theoretical weight‐average intrinsic viscosities were calculated by interpolation of the individual intrinsic viscosities of the blend components. The compatibility data based on [η] determined by a single specific viscosity measurement, as a quick method for the determination of the intrinsic viscosity, were compared with that obtained from [η] determined via the Huggins equation. The effect of molecular weights of the blend components and the polymer structure on the extent of compatibility was studied. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 1471–1482, 1998</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/(SICI)1097-4628(19980822)69:8<1471::AID-APP1>3.0.CO;2-9</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>Applied sciences ; Exact sciences and technology ; intrinsic viscosity ; Organic polymers ; Physicochemistry of polymers ; poly(ethylene glycol) ; poly(ethylene oxide) ; polystyrene ; Properties and characterization ; single point measurement ; Solution and gel properties ; specific viscosity</subject><ispartof>Journal of applied polymer science, 1998-08, Vol.69 (8), p.1471-1482</ispartof><rights>Copyright © 1998 John Wiley & Sons, Inc.</rights><rights>1998 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2F%28SICI%291097-4628%2819980822%2969%3A8%3C1471%3A%3AAID-APP1%3E3.0.CO%3B2-9$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2F%28SICI%291097-4628%2819980822%2969%3A8%3C1471%3A%3AAID-APP1%3E3.0.CO%3B2-9$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2349723$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Abdel-Azim, Abdel-Azim A.</creatorcontrib><creatorcontrib>Atta, Aiman M.</creatorcontrib><creatorcontrib>Farahat, Medhat S.</creatorcontrib><creatorcontrib>Boutros, Wagdy Y.</creatorcontrib><title>Miscibility of polystyrene with poly(ethylene oxide) and poly(ethylene glycol)</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The intrinsic viscosity of polystyrene–poly(ethylene oxide) (PS–PEO) and PS–poly(ethylene glycol) (PEG) blends have been measured in benzene as a function of blend composition for various molecular weights of PEO and PEG at 303.15 K. The compatibility of polymer pairs in solution were determined on the basis of the interaction parameter term, Δb, and the difference between the experimental and theoretical weight‐average intrinsic viscosities of the two polymers, Δ[η]. The theoretical weight‐average intrinsic viscosities were calculated by interpolation of the individual intrinsic viscosities of the blend components. The compatibility data based on [η] determined by a single specific viscosity measurement, as a quick method for the determination of the intrinsic viscosity, were compared with that obtained from [η] determined via the Huggins equation. The effect of molecular weights of the blend components and the polymer structure on the extent of compatibility was studied. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 1471–1482, 1998</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>intrinsic viscosity</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>poly(ethylene glycol)</subject><subject>poly(ethylene oxide)</subject><subject>polystyrene</subject><subject>Properties and characterization</subject><subject>single point measurement</subject><subject>Solution and gel properties</subject><subject>specific viscosity</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkF1v0zAUhi0EEmXwH3qBUHuRznb8WRCoCmOr9tEhCrs8ch2HGbymxJm2_HucdSsSTOLKOsfHz3v8IPSB4AnBmO6PvsyL-ZhgLTMmqBoRrRVWlI6Fnqp3hEkync7mH7PZ-Tl5n0_wpFi8pZl-gga7N0_RIJFIprTmz9GLGH9gTAjHYoDOTn20fuWDb7thXQ03dehi2zVu7YY3vr28a4xce9mFvlXf-tKNh2Zd_nXxPXS2DuOX6FllQnSv7s899PXTwbI4yk4Wh_NidpJZxhTJBOeGcmqYVYpirjWRq7KilSTSrCR1yjCuMJO5xBVVdGWcMKokpWXKaqNcvofebLmbpv517WILV-kfLgSzdvV1BCqEoIzjNHixHbRNHWPjKtg0_so0HRAMvV-A3i_0rqB3BQ9-QWhIVfILkPxC7xdywFAsgIJO5Nf3K5hoTagas7Y-7vA0Z1rS_M8CNz647p_0_4c_kn1XJ3K2JfvYutsd2TQ_QSRzHC7ODmF5rD4vKfkGx_lvaWSppQ</recordid><startdate>19980822</startdate><enddate>19980822</enddate><creator>Abdel-Azim, Abdel-Azim A.</creator><creator>Atta, Aiman M.</creator><creator>Farahat, Medhat S.</creator><creator>Boutros, Wagdy Y.</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19980822</creationdate><title>Miscibility of polystyrene with poly(ethylene oxide) and poly(ethylene glycol)</title><author>Abdel-Azim, Abdel-Azim A. ; Atta, Aiman M. ; Farahat, Medhat S. ; Boutros, Wagdy Y.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4481-655a252a4c882059917bdf2f717ab72e8a458047370f282bae6a8d1dc48c9a8e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>intrinsic viscosity</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>poly(ethylene glycol)</topic><topic>poly(ethylene oxide)</topic><topic>polystyrene</topic><topic>Properties and characterization</topic><topic>single point measurement</topic><topic>Solution and gel properties</topic><topic>specific viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abdel-Azim, Abdel-Azim A.</creatorcontrib><creatorcontrib>Atta, Aiman M.</creatorcontrib><creatorcontrib>Farahat, Medhat S.</creatorcontrib><creatorcontrib>Boutros, Wagdy Y.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abdel-Azim, Abdel-Azim A.</au><au>Atta, Aiman M.</au><au>Farahat, Medhat S.</au><au>Boutros, Wagdy Y.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Miscibility of polystyrene with poly(ethylene oxide) and poly(ethylene glycol)</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1998-08-22</date><risdate>1998</risdate><volume>69</volume><issue>8</issue><spage>1471</spage><epage>1482</epage><pages>1471-1482</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The intrinsic viscosity of polystyrene–poly(ethylene oxide) (PS–PEO) and PS–poly(ethylene glycol) (PEG) blends have been measured in benzene as a function of blend composition for various molecular weights of PEO and PEG at 303.15 K. The compatibility of polymer pairs in solution were determined on the basis of the interaction parameter term, Δb, and the difference between the experimental and theoretical weight‐average intrinsic viscosities of the two polymers, Δ[η]. The theoretical weight‐average intrinsic viscosities were calculated by interpolation of the individual intrinsic viscosities of the blend components. The compatibility data based on [η] determined by a single specific viscosity measurement, as a quick method for the determination of the intrinsic viscosity, were compared with that obtained from [η] determined via the Huggins equation. The effect of molecular weights of the blend components and the polymer structure on the extent of compatibility was studied. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 1471–1482, 1998</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/(SICI)1097-4628(19980822)69:8<1471::AID-APP1>3.0.CO;2-9</doi><tpages>12</tpages></addata></record> |
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| subjects | Applied sciences Exact sciences and technology intrinsic viscosity Organic polymers Physicochemistry of polymers poly(ethylene glycol) poly(ethylene oxide) polystyrene Properties and characterization single point measurement Solution and gel properties specific viscosity |
| title | Miscibility of polystyrene with poly(ethylene oxide) and poly(ethylene glycol) |
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