Anodic oxidation of methyl formate and its relationship to the reactions of methanol and formic acid
Experiments have been performed to examine the anodic oxidation of methyl formate in sulphuric acid using a platinum–ruthenium electrocatalyst, and to relate the process to the anodic oxidation of methanol and formic acid. Formic acid is more readily anodically oxidised than methanol, with up to fiv...
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| Veröffentlicht in: | Electrochimica acta 1998-01, Vol.43 (12), p.1705-1714 |
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| container_issue | 12 |
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| container_title | Electrochimica acta |
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| creator | Kucernak, A.R. Burstein, G.T. Barnett, C.J. Williams, K.R. |
| description | Experiments have been performed to examine the anodic oxidation of methyl formate in sulphuric acid using a platinum–ruthenium electrocatalyst, and to relate the process to the anodic oxidation of methanol and formic acid. Formic acid is more readily anodically oxidised than methanol, with up to five times the rate being observed, dependent on potential and temperature. The rate of reaction of methyl formate is comparable with that of formic acid. It is reasoned that the oxidation of the ester occurs most rapidly on the formate component, with methanol being generated by hydrolysis. The initial activation overpotential barrier required to oxidise these materials at a significant rate is common to all three fuels. |
| doi_str_mv | 10.1016/S0013-4686(97)00321-6 |
| format | Article |
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Formic acid is more readily anodically oxidised than methanol, with up to five times the rate being observed, dependent on potential and temperature. The rate of reaction of methyl formate is comparable with that of formic acid. It is reasoned that the oxidation of the ester occurs most rapidly on the formate component, with methanol being generated by hydrolysis. The initial activation overpotential barrier required to oxidise these materials at a significant rate is common to all three fuels.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/S0013-4686(97)00321-6</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Chemistry ; Electrochemistry ; Energy ; Energy. 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Formic acid is more readily anodically oxidised than methanol, with up to five times the rate being observed, dependent on potential and temperature. The rate of reaction of methyl formate is comparable with that of formic acid. It is reasoned that the oxidation of the ester occurs most rapidly on the formate component, with methanol being generated by hydrolysis. The initial activation overpotential barrier required to oxidise these materials at a significant rate is common to all three fuels.</description><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Electrochemistry</subject><subject>Energy</subject><subject>Energy. 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Thermal use of fuels</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Kinetics and mechanism of reactions</topic><topic>Transport and storage of energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kucernak, A.R.</creatorcontrib><creatorcontrib>Burstein, G.T.</creatorcontrib><creatorcontrib>Barnett, C.J.</creatorcontrib><creatorcontrib>Williams, K.R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kucernak, A.R.</au><au>Burstein, G.T.</au><au>Barnett, C.J.</au><au>Williams, K.R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anodic oxidation of methyl formate and its relationship to the reactions of methanol and formic acid</atitle><jtitle>Electrochimica acta</jtitle><date>1998-01-01</date><risdate>1998</risdate><volume>43</volume><issue>12</issue><spage>1705</spage><epage>1714</epage><pages>1705-1714</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>Experiments have been performed to examine the anodic oxidation of methyl formate in sulphuric acid using a platinum–ruthenium electrocatalyst, and to relate the process to the anodic oxidation of methanol and formic acid. 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| issn | 0013-4686 1873-3859 |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Applied sciences Chemistry Electrochemistry Energy Energy. Thermal use of fuels Exact sciences and technology General and physical chemistry Kinetics and mechanism of reactions Transport and storage of energy |
| title | Anodic oxidation of methyl formate and its relationship to the reactions of methanol and formic acid |
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