Lithium borate gel films prepared from aqueous solution
Transparent, durable films of lithium diborate gel can easily be prepared on a variety of substrates from supersaturated aqueous solutions of lithium hydroxide monohydrate and boric acid by spin-coating. The gel to dried gel to glass to crystalline lithium tetraborate (Li2B4O7) transformation has be...
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| Veröffentlicht in: | Journal of materials science 1998-08, Vol.33 (15), p.3853-3858 |
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| container_issue | 15 |
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| container_title | Journal of materials science |
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| creator | HEMRY, J. D WEINBERG, M. C UHLMANN, D. R |
| description | Transparent, durable films of lithium diborate gel can easily be prepared on a variety of substrates from supersaturated aqueous solutions of lithium hydroxide monohydrate and boric acid by spin-coating. The gel to dried gel to glass to crystalline lithium tetraborate (Li2B4O7) transformation has been studied by infrared spectroscopy of thin films cast on potassium bromide windows. Examination by scanning electron microscopy disclosed that distinctly different crystal morphology was associated with a difference in the transformation rate observed between gel and dried gel films. Films of 250 nm to 30 μm in thickness have been produced. |
| doi_str_mv | 10.1023/A:1004699322404 |
| format | Article |
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D ; WEINBERG, M. C ; UHLMANN, D. R</creator><contributor>WCA</contributor><creatorcontrib>HEMRY, J. D ; WEINBERG, M. C ; UHLMANN, D. R ; WCA</creatorcontrib><description>Transparent, durable films of lithium diborate gel can easily be prepared on a variety of substrates from supersaturated aqueous solutions of lithium hydroxide monohydrate and boric acid by spin-coating. The gel to dried gel to glass to crystalline lithium tetraborate (Li2B4O7) transformation has been studied by infrared spectroscopy of thin films cast on potassium bromide windows. Examination by scanning electron microscopy disclosed that distinctly different crystal morphology was associated with a difference in the transformation rate observed between gel and dried gel films. Films of 250 nm to 30 μm in thickness have been produced.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1023/A:1004699322404</identifier><identifier>CODEN: JMTSAS</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Aqueous solutions ; Chemistry ; Colloidal gels. Colloidal sols ; Colloidal state and disperse state ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Cross-disciplinary physics: materials science; rheology ; Crystal morphology ; Disperse systems ; Exact sciences and technology ; General and physical chemistry ; Liquid phase epitaxy; deposition from liquid phases (melts, solutions, and surface layers on liquids) ; Lithium ; Lithium borates ; Lithium hydroxides ; Materials science ; Methods of deposition of films and coatings; film growth and epitaxy ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Other solid inorganic materials ; Photoluminescence ; Physics ; Potassium bromides ; Scanning electron microscopy ; Spin coating ; Substrates ; Thin films ; Transformations</subject><ispartof>Journal of materials science, 1998-08, Vol.33 (15), p.3853-3858</ispartof><rights>1998 INIST-CNRS</rights><rights>Journal of Materials Science is a copyright of Springer, (1998). 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R</creatorcontrib><title>Lithium borate gel films prepared from aqueous solution</title><title>Journal of materials science</title><description>Transparent, durable films of lithium diborate gel can easily be prepared on a variety of substrates from supersaturated aqueous solutions of lithium hydroxide monohydrate and boric acid by spin-coating. The gel to dried gel to glass to crystalline lithium tetraborate (Li2B4O7) transformation has been studied by infrared spectroscopy of thin films cast on potassium bromide windows. Examination by scanning electron microscopy disclosed that distinctly different crystal morphology was associated with a difference in the transformation rate observed between gel and dried gel films. Films of 250 nm to 30 μm in thickness have been produced.</description><subject>Aqueous solutions</subject><subject>Chemistry</subject><subject>Colloidal gels. Colloidal sols</subject><subject>Colloidal state and disperse state</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Crystal morphology</subject><subject>Disperse systems</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Liquid phase epitaxy; deposition from liquid phases (melts, solutions, and surface layers on liquids)</subject><subject>Lithium</subject><subject>Lithium borates</subject><subject>Lithium hydroxides</subject><subject>Materials science</subject><subject>Methods of deposition of films and coatings; film growth and epitaxy</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Other solid inorganic materials</subject><subject>Photoluminescence</subject><subject>Physics</subject><subject>Potassium bromides</subject><subject>Scanning electron microscopy</subject><subject>Spin coating</subject><subject>Substrates</subject><subject>Thin films</subject><subject>Transformations</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdzr1LxDAcxvEgCp6ns2tAcav-8p64HYdvcOCic0naRHO0TU3awf_eijc5PcuHhy9ClwRuCVB2t7knAFwawyjlwI_QigjFKq6BHaMVAKUV5ZKcorNS9gAgFCUrpHZx-oxzj13KdvL4w3c4xK4veMx-tNm3OOTUY_s1-zQXXFI3TzEN5-gk2K74i8Ou0fvjw9v2udq9Pr1sN7uqoVpNFeNMCuqE0sFpTVoXpJKq9V4GZ6U1BhgHaZhuPSWWBye8MNyDlk0DTrZsjW7-fsecloQy1X0sje86O_z21FRKDsvLAq_-wX2a87C01ZQKo7QxRizq-qBsaWwXsh2aWOoxx97m75pywhQB9gNe7mHD</recordid><startdate>19980801</startdate><enddate>19980801</enddate><creator>HEMRY, J. 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Examination by scanning electron microscopy disclosed that distinctly different crystal morphology was associated with a difference in the transformation rate observed between gel and dried gel films. Films of 250 nm to 30 μm in thickness have been produced.</abstract><cop>Heidelberg</cop><pub>Springer</pub><doi>10.1023/A:1004699322404</doi><tpages>6</tpages></addata></record> |
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| subjects | Aqueous solutions Chemistry Colloidal gels. Colloidal sols Colloidal state and disperse state Condensed matter: electronic structure, electrical, magnetic, and optical properties Cross-disciplinary physics: materials science rheology Crystal morphology Disperse systems Exact sciences and technology General and physical chemistry Liquid phase epitaxy deposition from liquid phases (melts, solutions, and surface layers on liquids) Lithium Lithium borates Lithium hydroxides Materials science Methods of deposition of films and coatings film growth and epitaxy Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Other solid inorganic materials Photoluminescence Physics Potassium bromides Scanning electron microscopy Spin coating Substrates Thin films Transformations |
| title | Lithium borate gel films prepared from aqueous solution |
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