Liquid–liquid extraction of cationic metal complexes with p-nonylphenol solvent: : Application to crown and thiacrown ether complexes of lead (II) and copper (II)
The hydrophobicity of alkylphenols increases with an increase of alkyl chain length; p-nonylphenol floats on the surface of aqueous solution as a hemispherical droplet. We have found that cationic metal complexes with crown ether and thiacrown ether ligands can be quantitatively extracted into the p...
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| Veröffentlicht in: | Analytica chimica acta 1998-05, Vol.363 (2), p.165-170 |
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| container_title | Analytica chimica acta |
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| creator | Ikeda, Kouji Abe, Shigeki |
| description | The hydrophobicity of alkylphenols increases with an increase of alkyl chain length;
p-nonylphenol floats on the surface of aqueous solution as a hemispherical droplet. We have found that cationic metal complexes with crown ether and thiacrown ether ligands can be quantitatively extracted into the
p-nonylphenol phase in the presence of small anions e.g. butyrate rather than bulky counter anions. The coordination ability of
p-nonylphenol solvent is ascertained by the extraction data on lead (II)-crown ether and copper (I, II)-thiacrown ether complexes. The potential usefulness of
p-nonylphenol as an extraction solvent in ion-pair system is shown. |
| doi_str_mv | 10.1016/S0003-2670(98)00126-3 |
| format | Article |
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p-nonylphenol floats on the surface of aqueous solution as a hemispherical droplet. We have found that cationic metal complexes with crown ether and thiacrown ether ligands can be quantitatively extracted into the
p-nonylphenol phase in the presence of small anions e.g. butyrate rather than bulky counter anions. The coordination ability of
p-nonylphenol solvent is ascertained by the extraction data on lead (II)-crown ether and copper (I, II)-thiacrown ether complexes. The potential usefulness of
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p-nonylphenol floats on the surface of aqueous solution as a hemispherical droplet. We have found that cationic metal complexes with crown ether and thiacrown ether ligands can be quantitatively extracted into the
p-nonylphenol phase in the presence of small anions e.g. butyrate rather than bulky counter anions. The coordination ability of
p-nonylphenol solvent is ascertained by the extraction data on lead (II)-crown ether and copper (I, II)-thiacrown ether complexes. The potential usefulness of
p-nonylphenol as an extraction solvent in ion-pair system is shown.</description><subject>Analytical chemistry</subject><subject>Chemical and thermal methods</subject><subject>Chemistry</subject><subject>Copper</subject><subject>Crown ether</subject><subject>Exact sciences and technology</subject><subject>Lead</subject><subject>Liquid–liquid extraction</subject><subject>p-nonylphenol</subject><subject>Thiacrown ether</subject><issn>0003-2670</issn><issn>1873-4324</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNpNkU1uFDEQhVsIJIbAEZC8QChZNPiv3e1sUBQFGGmkLBLWlmOXNUYe27E9-dlxB67AyThJemYiRG2qnvS9qpJe170n-BPBRHy-whiznooRH8vpBGNCRc9edAsyjaznjPKX3eIf8rp7U-vPWVKC-aL7s_K3W2___vod9gOCh1a0aT5FlBwyejd5gzbQdEAmbXKAB6jo3rc1yn1M8THkNcQUUE3hDmI7RafoLOfgD17UEjIl3Ueko0Vt7fVBQVtD-W_hfCyAtuh4uTzZoyblPBM7_bZ75XSo8O65H3U_vl5cn3_vV5ffludnqx6okK03INxcN-6GD9hNlvPROckHqcFORFoMQsuBU8H4ODAzAnd8IONAJ2OEHSU76j4e9uaSbrdQm9r4aiAEHSFtq6Jitko8zeCHZ1BXo4MrOhpfVS5-o8ujonQUjJEZ-3LAYH76zkNR1XiIBqwvYJqyySuC1S5EtQ9R7RJSclL7EBVjT8D4k5k</recordid><startdate>19980515</startdate><enddate>19980515</enddate><creator>Ikeda, Kouji</creator><creator>Abe, Shigeki</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19980515</creationdate><title>Liquid–liquid extraction of cationic metal complexes with p-nonylphenol solvent: : Application to crown and thiacrown ether complexes of lead (II) and copper (II)</title><author>Ikeda, Kouji ; Abe, Shigeki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e269t-ce6ffffbfb450f8d447ff9459aed819d0e6a9542634753c7e4f4517528cc6d793</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Analytical chemistry</topic><topic>Chemical and thermal methods</topic><topic>Chemistry</topic><topic>Copper</topic><topic>Crown ether</topic><topic>Exact sciences and technology</topic><topic>Lead</topic><topic>Liquid–liquid extraction</topic><topic>p-nonylphenol</topic><topic>Thiacrown ether</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ikeda, Kouji</creatorcontrib><creatorcontrib>Abe, Shigeki</creatorcontrib><collection>Pascal-Francis</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Analytica chimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ikeda, Kouji</au><au>Abe, Shigeki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Liquid–liquid extraction of cationic metal complexes with p-nonylphenol solvent: : Application to crown and thiacrown ether complexes of lead (II) and copper (II)</atitle><jtitle>Analytica chimica acta</jtitle><date>1998-05-15</date><risdate>1998</risdate><volume>363</volume><issue>2</issue><spage>165</spage><epage>170</epage><pages>165-170</pages><issn>0003-2670</issn><eissn>1873-4324</eissn><coden>ACACAM</coden><abstract>The hydrophobicity of alkylphenols increases with an increase of alkyl chain length;
p-nonylphenol floats on the surface of aqueous solution as a hemispherical droplet. We have found that cationic metal complexes with crown ether and thiacrown ether ligands can be quantitatively extracted into the
p-nonylphenol phase in the presence of small anions e.g. butyrate rather than bulky counter anions. The coordination ability of
p-nonylphenol solvent is ascertained by the extraction data on lead (II)-crown ether and copper (I, II)-thiacrown ether complexes. The potential usefulness of
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| ispartof | Analytica chimica acta, 1998-05, Vol.363 (2), p.165-170 |
| issn | 0003-2670 1873-4324 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_26634908 |
| source | Elsevier ScienceDirect Journals |
| subjects | Analytical chemistry Chemical and thermal methods Chemistry Copper Crown ether Exact sciences and technology Lead Liquid–liquid extraction p-nonylphenol Thiacrown ether |
| title | Liquid–liquid extraction of cationic metal complexes with p-nonylphenol solvent: : Application to crown and thiacrown ether complexes of lead (II) and copper (II) |
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