A molten salt-based nitridation approach for synthesizing nanostructured InN electrode materials
Single-phase InN nanocrystals were synthesized for the first time by a molten salt-based nitridation approach using InCl 3 and LiNH 2 as indium and nitrogen sources, respectively. A molten salt, KCl-LiCl, during nitridation, enabled us to obtain InN nanocrystals at relatively low temperatures rangin...
Gespeichert in:
| Veröffentlicht in: | RSC advances 2020-10, Vol.1 (61), p.37576-37581 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 37581 |
|---|---|
| container_issue | 61 |
| container_start_page | 37576 |
| container_title | RSC advances |
| container_volume | 1 |
| creator | Purwiandono, Gani Manseki, Kazuhiro Sugiura, Takashi |
| description | Single-phase InN nanocrystals were synthesized for the first time by a molten salt-based nitridation approach using InCl
3
and LiNH
2
as indium and nitrogen sources, respectively. A molten salt, KCl-LiCl, during nitridation, enabled us to obtain InN nanocrystals at relatively low temperatures ranging from 400 °C to 500 °C. SEM and HR-TEM measurements coupled with XRD data revealed that InN nanocrystals were formed with average grain sizes of approximately 50-60 nm. Notably, the photoelectrochemical cell fabricated using the InN nanocrystals synthesized at 450 °C exhibited a photocurrent response under light irradiation from 400 nm to 880 nm. The precise control of the growth of InN particles using our synthetic approach provides opportunities for developing versatile nitride nanocrystals.
Single-phase InN nanocrystals were synthesized for the first time by a molten salt-based nitridation approach using InCl
3
and LiNH
2
as indium and nitrogen sources, respectively. |
| doi_str_mv | 10.1039/d0ra07172b |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_2661079551</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2661079551</sourcerecordid><originalsourceid>FETCH-LOGICAL-c454t-1adc8c2df44d48db940da6cc77ffce178a8f9763c544c09c51d26d5ffc5fbdba3</originalsourceid><addsrcrecordid>eNp9kc1rFTEUxYMottRuuq9E3JTCaJJJMpON8GyrFoqC6DrN5KMvZSYZk0yh_euNvvpaXXg398L53cO9HAAOMHqDUSveGpQU6nBHhidglyDKG4K4ePpo3gH7OV-jWpxhwvFzsNMyRjBp6S64XMEpjsUGmNVYmkFla2DwJXmjio8BqnlOUek1dDHBfBvK2mZ_58MVDCrEXNKiy5Lq0nn4DO1odUnRWDipYpNXY34Bnrna7P593wPfP5x9O_nUXHz5eH6yumg0ZbQ0WBnda2IcpYb2ZhAUGcW17jrntMVdr3onOt5qRqlGQjNsCDesiswNZlDtHni38Z2XYbJG21CSGuWc_KTSrYzKy7-V4NfyKt5IgViHW1YNju4NUvyx2Fzk5LO246iCjUuWhHOMOsEYrujrf9DruKRQ35OEUtG3guG-UscbSqeYc7JuewxG8ld28hR9Xf3O7n2FXz4-f4v-SaoCrzZAynqrPoQvZ-Mqc_g_pv0J4nisrw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2449839518</pqid></control><display><type>article</type><title>A molten salt-based nitridation approach for synthesizing nanostructured InN electrode materials</title><source>DOAJ Directory of Open Access Journals</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central</source><source>PubMed Central Open Access</source><creator>Purwiandono, Gani ; Manseki, Kazuhiro ; Sugiura, Takashi</creator><creatorcontrib>Purwiandono, Gani ; Manseki, Kazuhiro ; Sugiura, Takashi</creatorcontrib><description>Single-phase InN nanocrystals were synthesized for the first time by a molten salt-based nitridation approach using InCl
3
and LiNH
2
as indium and nitrogen sources, respectively. A molten salt, KCl-LiCl, during nitridation, enabled us to obtain InN nanocrystals at relatively low temperatures ranging from 400 °C to 500 °C. SEM and HR-TEM measurements coupled with XRD data revealed that InN nanocrystals were formed with average grain sizes of approximately 50-60 nm. Notably, the photoelectrochemical cell fabricated using the InN nanocrystals synthesized at 450 °C exhibited a photocurrent response under light irradiation from 400 nm to 880 nm. The precise control of the growth of InN particles using our synthetic approach provides opportunities for developing versatile nitride nanocrystals.
Single-phase InN nanocrystals were synthesized for the first time by a molten salt-based nitridation approach using InCl
3
and LiNH
2
as indium and nitrogen sources, respectively.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d0ra07172b</identifier><identifier>PMID: 35521234</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chemistry ; Electrode materials ; Grain size ; Indium nitride ; Light irradiation ; Lithium chloride ; Low temperature ; Molten salts ; Nanocrystals ; Photoelectric effect ; Photoelectric emission ; Photoelectrochemical devices ; Synthesis</subject><ispartof>RSC advances, 2020-10, Vol.1 (61), p.37576-37581</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2020</rights><rights>This journal is © The Royal Society of Chemistry 2020 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c454t-1adc8c2df44d48db940da6cc77ffce178a8f9763c544c09c51d26d5ffc5fbdba3</citedby><cites>FETCH-LOGICAL-c454t-1adc8c2df44d48db940da6cc77ffce178a8f9763c544c09c51d26d5ffc5fbdba3</cites><orcidid>0000-0002-1199-5766</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057135/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057135/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35521234$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Purwiandono, Gani</creatorcontrib><creatorcontrib>Manseki, Kazuhiro</creatorcontrib><creatorcontrib>Sugiura, Takashi</creatorcontrib><title>A molten salt-based nitridation approach for synthesizing nanostructured InN electrode materials</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Single-phase InN nanocrystals were synthesized for the first time by a molten salt-based nitridation approach using InCl
3
and LiNH
2
as indium and nitrogen sources, respectively. A molten salt, KCl-LiCl, during nitridation, enabled us to obtain InN nanocrystals at relatively low temperatures ranging from 400 °C to 500 °C. SEM and HR-TEM measurements coupled with XRD data revealed that InN nanocrystals were formed with average grain sizes of approximately 50-60 nm. Notably, the photoelectrochemical cell fabricated using the InN nanocrystals synthesized at 450 °C exhibited a photocurrent response under light irradiation from 400 nm to 880 nm. The precise control of the growth of InN particles using our synthetic approach provides opportunities for developing versatile nitride nanocrystals.
Single-phase InN nanocrystals were synthesized for the first time by a molten salt-based nitridation approach using InCl
3
and LiNH
2
as indium and nitrogen sources, respectively.</description><subject>Chemistry</subject><subject>Electrode materials</subject><subject>Grain size</subject><subject>Indium nitride</subject><subject>Light irradiation</subject><subject>Lithium chloride</subject><subject>Low temperature</subject><subject>Molten salts</subject><subject>Nanocrystals</subject><subject>Photoelectric effect</subject><subject>Photoelectric emission</subject><subject>Photoelectrochemical devices</subject><subject>Synthesis</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kc1rFTEUxYMottRuuq9E3JTCaJJJMpON8GyrFoqC6DrN5KMvZSYZk0yh_euNvvpaXXg398L53cO9HAAOMHqDUSveGpQU6nBHhidglyDKG4K4ePpo3gH7OV-jWpxhwvFzsNMyRjBp6S64XMEpjsUGmNVYmkFla2DwJXmjio8BqnlOUek1dDHBfBvK2mZ_58MVDCrEXNKiy5Lq0nn4DO1odUnRWDipYpNXY34Bnrna7P593wPfP5x9O_nUXHz5eH6yumg0ZbQ0WBnda2IcpYb2ZhAUGcW17jrntMVdr3onOt5qRqlGQjNsCDesiswNZlDtHni38Z2XYbJG21CSGuWc_KTSrYzKy7-V4NfyKt5IgViHW1YNju4NUvyx2Fzk5LO246iCjUuWhHOMOsEYrujrf9DruKRQ35OEUtG3guG-UscbSqeYc7JuewxG8ld28hR9Xf3O7n2FXz4-f4v-SaoCrzZAynqrPoQvZ-Mqc_g_pv0J4nisrw</recordid><startdate>20201012</startdate><enddate>20201012</enddate><creator>Purwiandono, Gani</creator><creator>Manseki, Kazuhiro</creator><creator>Sugiura, Takashi</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-1199-5766</orcidid></search><sort><creationdate>20201012</creationdate><title>A molten salt-based nitridation approach for synthesizing nanostructured InN electrode materials</title><author>Purwiandono, Gani ; Manseki, Kazuhiro ; Sugiura, Takashi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c454t-1adc8c2df44d48db940da6cc77ffce178a8f9763c544c09c51d26d5ffc5fbdba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Chemistry</topic><topic>Electrode materials</topic><topic>Grain size</topic><topic>Indium nitride</topic><topic>Light irradiation</topic><topic>Lithium chloride</topic><topic>Low temperature</topic><topic>Molten salts</topic><topic>Nanocrystals</topic><topic>Photoelectric effect</topic><topic>Photoelectric emission</topic><topic>Photoelectrochemical devices</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Purwiandono, Gani</creatorcontrib><creatorcontrib>Manseki, Kazuhiro</creatorcontrib><creatorcontrib>Sugiura, Takashi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Purwiandono, Gani</au><au>Manseki, Kazuhiro</au><au>Sugiura, Takashi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A molten salt-based nitridation approach for synthesizing nanostructured InN electrode materials</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2020-10-12</date><risdate>2020</risdate><volume>1</volume><issue>61</issue><spage>37576</spage><epage>37581</epage><pages>37576-37581</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Single-phase InN nanocrystals were synthesized for the first time by a molten salt-based nitridation approach using InCl
3
and LiNH
2
as indium and nitrogen sources, respectively. A molten salt, KCl-LiCl, during nitridation, enabled us to obtain InN nanocrystals at relatively low temperatures ranging from 400 °C to 500 °C. SEM and HR-TEM measurements coupled with XRD data revealed that InN nanocrystals were formed with average grain sizes of approximately 50-60 nm. Notably, the photoelectrochemical cell fabricated using the InN nanocrystals synthesized at 450 °C exhibited a photocurrent response under light irradiation from 400 nm to 880 nm. The precise control of the growth of InN particles using our synthetic approach provides opportunities for developing versatile nitride nanocrystals.
Single-phase InN nanocrystals were synthesized for the first time by a molten salt-based nitridation approach using InCl
3
and LiNH
2
as indium and nitrogen sources, respectively.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35521234</pmid><doi>10.1039/d0ra07172b</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-1199-5766</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2020-10, Vol.1 (61), p.37576-37581 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2661079551 |
| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; PubMed Central Open Access |
| subjects | Chemistry Electrode materials Grain size Indium nitride Light irradiation Lithium chloride Low temperature Molten salts Nanocrystals Photoelectric effect Photoelectric emission Photoelectrochemical devices Synthesis |
| title | A molten salt-based nitridation approach for synthesizing nanostructured InN electrode materials |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-04T02%3A10%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20molten%20salt-based%20nitridation%20approach%20for%20synthesizing%20nanostructured%20InN%20electrode%20materials&rft.jtitle=RSC%20advances&rft.au=Purwiandono,%20Gani&rft.date=2020-10-12&rft.volume=1&rft.issue=61&rft.spage=37576&rft.epage=37581&rft.pages=37576-37581&rft.issn=2046-2069&rft.eissn=2046-2069&rft_id=info:doi/10.1039/d0ra07172b&rft_dat=%3Cproquest_pubme%3E2661079551%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2449839518&rft_id=info:pmid/35521234&rfr_iscdi=true |