Synthesis of nanoporous carbohydrate metal-organic framework and encapsulation of acetaldehyde
Gamma cyclodextrin (γ-CD) metal organic frameworks (CDMOFs) were synthesized by coordinating γ-CDs with potassium hydroxide (KOH), referred hereafter as CDMOF-a, and potassium benzoate (C7H5KO2), denoted as CDMOF-b. The obtained CDMOF structures were characterized using nitrogen sorption isotherm, t...
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Veröffentlicht in: | Journal of crystal growth 2016-10, Vol.451, p.72-78 |
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creator | Al-Ghamdi, Saleh Kathuria, Ajay Abiad, Mohamad Auras, Rafael |
description | Gamma cyclodextrin (γ-CD) metal organic frameworks (CDMOFs) were synthesized by coordinating γ-CDs with potassium hydroxide (KOH), referred hereafter as CDMOF-a, and potassium benzoate (C7H5KO2), denoted as CDMOF-b. The obtained CDMOF structures were characterized using nitrogen sorption isotherm, thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). High surface areas were achieved by the γ-CD based MOF structures where the Langmuir specific surface areas (SSA) of CDMOF-a and CDMOF-b were determined as 1376m2g−1 and 607m2g−1; respectively. The dehydrated CDMOF structures demonstrated good thermal stability up to 250°C as observed by the TGA studies. XRD results for CDMOF-a and CDMOF-b reveal a body centered-cubic (BCC) and trigonal crystal system; respectively. Due to its accessible porous structure and high surface area, acetaldehyde was successfully encapsulated in CDMOF-b. During the release kinetic studies, we observed peak release of 53μg of acetaldehyde per g of CDMOF-b, which was 100 times greater than previously reported encapsulation in β-CD. However, aldol condensation reaction occurred during encapsulation of acetaldehyde into CDMOF-a. This research work demonstrates the potential to encapsulate volatile organic compounds in CDMOF-b, and their associated release for applications including food, pharmaceuticals and packaging.
•Two different nanoporous high surface area CDMOFs were synthesized using slow vapor diffusion process.•Physical, thermal properties and crystal structure were studied.•Interactions between acetaldehyde and synthesized CDMOFs were examined.•Acetaldehyde was successfully encapsulated in a CDMOF.•Release kinetics of acetaldehyde was analyzed using gas chromatography and thermo-gravimetric analysis. |
doi_str_mv | 10.1016/j.jcrysgro.2016.07.004 |
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•Two different nanoporous high surface area CDMOFs were synthesized using slow vapor diffusion process.•Physical, thermal properties and crystal structure were studied.•Interactions between acetaldehyde and synthesized CDMOFs were examined.•Acetaldehyde was successfully encapsulated in a CDMOF.•Release kinetics of acetaldehyde was analyzed using gas chromatography and thermo-gravimetric analysis.</description><identifier>ISSN: 0022-0248</identifier><identifier>EISSN: 1873-5002</identifier><identifier>DOI: 10.1016/j.jcrysgro.2016.07.004</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>A1. Adsorption ; A1. Biomaterials ; A1. Diffusion ; A2. Growth from solutions ; acetaldehyde ; B1. Nanomaterials ; B1. Organic compounds ; condensation reactions ; coordination polymers ; cyclodextrins ; encapsulation ; nanopores ; nitrogen ; potassium benzoate ; potassium hydroxide ; sorption isotherms ; surface area ; thermal stability ; thermogravimetry ; volatile organic compounds ; X-ray diffraction</subject><ispartof>Journal of crystal growth, 2016-10, Vol.451, p.72-78</ispartof><rights>2016 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c496t-342ecf76ceb200d501d414f8f8b2d7ff683f83521569684442a64c723a90dfc63</citedby><cites>FETCH-LOGICAL-c496t-342ecf76ceb200d501d414f8f8b2d7ff683f83521569684442a64c723a90dfc63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jcrysgro.2016.07.004$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Al-Ghamdi, Saleh</creatorcontrib><creatorcontrib>Kathuria, Ajay</creatorcontrib><creatorcontrib>Abiad, Mohamad</creatorcontrib><creatorcontrib>Auras, Rafael</creatorcontrib><title>Synthesis of nanoporous carbohydrate metal-organic framework and encapsulation of acetaldehyde</title><title>Journal of crystal growth</title><description>Gamma cyclodextrin (γ-CD) metal organic frameworks (CDMOFs) were synthesized by coordinating γ-CDs with potassium hydroxide (KOH), referred hereafter as CDMOF-a, and potassium benzoate (C7H5KO2), denoted as CDMOF-b. The obtained CDMOF structures were characterized using nitrogen sorption isotherm, thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). High surface areas were achieved by the γ-CD based MOF structures where the Langmuir specific surface areas (SSA) of CDMOF-a and CDMOF-b were determined as 1376m2g−1 and 607m2g−1; respectively. The dehydrated CDMOF structures demonstrated good thermal stability up to 250°C as observed by the TGA studies. XRD results for CDMOF-a and CDMOF-b reveal a body centered-cubic (BCC) and trigonal crystal system; respectively. Due to its accessible porous structure and high surface area, acetaldehyde was successfully encapsulated in CDMOF-b. During the release kinetic studies, we observed peak release of 53μg of acetaldehyde per g of CDMOF-b, which was 100 times greater than previously reported encapsulation in β-CD. However, aldol condensation reaction occurred during encapsulation of acetaldehyde into CDMOF-a. This research work demonstrates the potential to encapsulate volatile organic compounds in CDMOF-b, and their associated release for applications including food, pharmaceuticals and packaging.
•Two different nanoporous high surface area CDMOFs were synthesized using slow vapor diffusion process.•Physical, thermal properties and crystal structure were studied.•Interactions between acetaldehyde and synthesized CDMOFs were examined.•Acetaldehyde was successfully encapsulated in a CDMOF.•Release kinetics of acetaldehyde was analyzed using gas chromatography and thermo-gravimetric analysis.</description><subject>A1. Adsorption</subject><subject>A1. Biomaterials</subject><subject>A1. Diffusion</subject><subject>A2. Growth from solutions</subject><subject>acetaldehyde</subject><subject>B1. Nanomaterials</subject><subject>B1. Organic compounds</subject><subject>condensation reactions</subject><subject>coordination polymers</subject><subject>cyclodextrins</subject><subject>encapsulation</subject><subject>nanopores</subject><subject>nitrogen</subject><subject>potassium benzoate</subject><subject>potassium hydroxide</subject><subject>sorption isotherms</subject><subject>surface area</subject><subject>thermal stability</subject><subject>thermogravimetry</subject><subject>volatile organic compounds</subject><subject>X-ray diffraction</subject><issn>0022-0248</issn><issn>1873-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkM9LwzAYhoMoOKf_gvTopfVLmqbdTRn-goEH9WrIki9bZtfMpFP635syPXvJR-B5X3gfQi4pFBSouN4UGx2GuAq-YOlfQF0A8CMyoU1d5hUAOyaT9LIcGG9OyVmMG4BEUpiQ95eh69cYXcy8zTrV-Z0Pfh8zrcLSrwcTVI_ZFnvV5j6sVOd0ZoPa4rcPH5nqTIadVru4b1XvfDeWKD3SBlMYz8mJVW3Ei987JW_3d6_zx3zx_PA0v13kms9En5ecoba10LhkAKYCajjltrHNkpnaWtGUtikrRisxEw3nnCnBdc1KNQNjtSin5OrQuwv-c4-xl1sXNbat6jCtkUwImDVlXY2oOKA6-BgDWrkLbqvCICnIUajcyD-hchQqoZZJaAreHIKYhnw5DDJql9ajcQF1L413_1X8AIZxhGk</recordid><startdate>20161001</startdate><enddate>20161001</enddate><creator>Al-Ghamdi, Saleh</creator><creator>Kathuria, Ajay</creator><creator>Abiad, Mohamad</creator><creator>Auras, Rafael</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20161001</creationdate><title>Synthesis of nanoporous carbohydrate metal-organic framework and encapsulation of acetaldehyde</title><author>Al-Ghamdi, Saleh ; Kathuria, Ajay ; Abiad, Mohamad ; Auras, Rafael</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c496t-342ecf76ceb200d501d414f8f8b2d7ff683f83521569684442a64c723a90dfc63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>A1. Adsorption</topic><topic>A1. Biomaterials</topic><topic>A1. Diffusion</topic><topic>A2. Growth from solutions</topic><topic>acetaldehyde</topic><topic>B1. Nanomaterials</topic><topic>B1. Organic compounds</topic><topic>condensation reactions</topic><topic>coordination polymers</topic><topic>cyclodextrins</topic><topic>encapsulation</topic><topic>nanopores</topic><topic>nitrogen</topic><topic>potassium benzoate</topic><topic>potassium hydroxide</topic><topic>sorption isotherms</topic><topic>surface area</topic><topic>thermal stability</topic><topic>thermogravimetry</topic><topic>volatile organic compounds</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Al-Ghamdi, Saleh</creatorcontrib><creatorcontrib>Kathuria, Ajay</creatorcontrib><creatorcontrib>Abiad, Mohamad</creatorcontrib><creatorcontrib>Auras, Rafael</creatorcontrib><collection>CrossRef</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Journal of crystal growth</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Al-Ghamdi, Saleh</au><au>Kathuria, Ajay</au><au>Abiad, Mohamad</au><au>Auras, Rafael</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of nanoporous carbohydrate metal-organic framework and encapsulation of acetaldehyde</atitle><jtitle>Journal of crystal growth</jtitle><date>2016-10-01</date><risdate>2016</risdate><volume>451</volume><spage>72</spage><epage>78</epage><pages>72-78</pages><issn>0022-0248</issn><eissn>1873-5002</eissn><abstract>Gamma cyclodextrin (γ-CD) metal organic frameworks (CDMOFs) were synthesized by coordinating γ-CDs with potassium hydroxide (KOH), referred hereafter as CDMOF-a, and potassium benzoate (C7H5KO2), denoted as CDMOF-b. The obtained CDMOF structures were characterized using nitrogen sorption isotherm, thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). High surface areas were achieved by the γ-CD based MOF structures where the Langmuir specific surface areas (SSA) of CDMOF-a and CDMOF-b were determined as 1376m2g−1 and 607m2g−1; respectively. The dehydrated CDMOF structures demonstrated good thermal stability up to 250°C as observed by the TGA studies. XRD results for CDMOF-a and CDMOF-b reveal a body centered-cubic (BCC) and trigonal crystal system; respectively. Due to its accessible porous structure and high surface area, acetaldehyde was successfully encapsulated in CDMOF-b. During the release kinetic studies, we observed peak release of 53μg of acetaldehyde per g of CDMOF-b, which was 100 times greater than previously reported encapsulation in β-CD. However, aldol condensation reaction occurred during encapsulation of acetaldehyde into CDMOF-a. This research work demonstrates the potential to encapsulate volatile organic compounds in CDMOF-b, and their associated release for applications including food, pharmaceuticals and packaging.
•Two different nanoporous high surface area CDMOFs were synthesized using slow vapor diffusion process.•Physical, thermal properties and crystal structure were studied.•Interactions between acetaldehyde and synthesized CDMOFs were examined.•Acetaldehyde was successfully encapsulated in a CDMOF.•Release kinetics of acetaldehyde was analyzed using gas chromatography and thermo-gravimetric analysis.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jcrysgro.2016.07.004</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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subjects | A1. Adsorption A1. Biomaterials A1. Diffusion A2. Growth from solutions acetaldehyde B1. Nanomaterials B1. Organic compounds condensation reactions coordination polymers cyclodextrins encapsulation nanopores nitrogen potassium benzoate potassium hydroxide sorption isotherms surface area thermal stability thermogravimetry volatile organic compounds X-ray diffraction |
title | Synthesis of nanoporous carbohydrate metal-organic framework and encapsulation of acetaldehyde |
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