Metal‐Free C−H Functionalization via Diaryliodonium Salts with a Chemically Robust Dummy Ligand

A two‐step strategy for the transition‐metal‐free C−H functionalization of arenes using unsymmetrical iodonium salts as versatile synthetic linchpins is presented. The key to the success of this strategy is the identification of the 3,5‐dimethyl‐4‐isoxazolyl (DMIX) group as a superior dummy ligand,...

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Veröffentlicht in:	Angewandte Chemie International Edition 2022-07, Vol.61 (28), p.e202201240-n/a
Hauptverfasser:	Chen, Yixuan, Gu, Yuefei, Meng, Huan, Shao, Qianzhen, Xu, Zhenchuang, Bao, Wenjing, Gu, Yucheng, Xue, Xiao‐Song, Zhao, Yanchuan
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Coupling Cross-Coupling C−H Functionalization Diaryliodonium Salts Hypervalent Compounds Ligands Metals Salts Structural Diversification
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