Use of inverse gas chromatography to quantify interactions in anhydride cured epoxy resins
Previous work has shown that the inverse gas chromatography (IGC) method combined with Flory–Huggins and solubility parameter theories could be used to quantify interactions in an amine cured epoxy resin matrix. In the present communication the same procedures have been adopted for an anhydride cure...
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| Veröffentlicht in: | Polymer international 1994-10, Vol.35 (2), p.135-143 |
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| container_title | Polymer international |
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| creator | Jackson, Paul L. Huglin, Malcolm B. Cervenka, Antonin |
| description | Previous work has shown that the inverse gas chromatography (IGC) method combined with Flory–Huggins and solubility parameter theories could be used to quantify interactions in an amine cured epoxy resin matrix. In the present communication the same procedures have been adopted for an anhydride cured epoxy resin matrix. The solubility parameter at 298 K thereby obtained for the cured resin was 20–6 (MPa)1/2, which lies between the corresponding values of 18.8(MPa)1/2 and 22.5 (MPa)1/2 for the precursors, viz. Epikote 828 (an epoxide resin) and phthalic anhydride, respectively. It was noted that great care must be exercised regarding choice of solvent used for deposition of phthalic anhydride on a glass bead support because of reaction to phthaclic acid. Similar consderations apply to the choice of probes used. |
| doi_str_mv | 10.1002/pi.1994.210350203 |
| format | Article |
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In the present communication the same procedures have been adopted for an anhydride cured epoxy resin matrix. The solubility parameter at 298 K thereby obtained for the cured resin was 20–6 (MPa)1/2, which lies between the corresponding values of 18.8(MPa)1/2 and 22.5 (MPa)1/2 for the precursors, viz. Epikote 828 (an epoxide resin) and phthalic anhydride, respectively. It was noted that great care must be exercised regarding choice of solvent used for deposition of phthalic anhydride on a glass bead support because of reaction to phthaclic acid. Similar consderations apply to the choice of probes used.</description><identifier>ISSN: 0959-8103</identifier><identifier>EISSN: 1097-0126</identifier><identifier>DOI: 10.1002/pi.1994.210350203</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>Applied sciences ; epoxy resin ; Exact sciences and technology ; inverse gas chromatography ; Organic polymers ; phthalic anhydride ; Physicochemistry of polymers ; Properties and characterization ; solubility parameter ; Thermal and thermodynamic properties</subject><ispartof>Polymer international, 1994-10, Vol.35 (2), p.135-143</ispartof><rights>1994 Society of Chemical Industry</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4233-ae3f353aa4fc9429f3e27ed50ad1456f6c5896180db3c18c7ac30be404860e163</citedby><cites>FETCH-LOGICAL-c4233-ae3f353aa4fc9429f3e27ed50ad1456f6c5896180db3c18c7ac30be404860e163</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpi.1994.210350203$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpi.1994.210350203$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4228044$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Jackson, Paul L.</creatorcontrib><creatorcontrib>Huglin, Malcolm B.</creatorcontrib><creatorcontrib>Cervenka, Antonin</creatorcontrib><title>Use of inverse gas chromatography to quantify interactions in anhydride cured epoxy resins</title><title>Polymer international</title><addtitle>Polym. Int</addtitle><description>Previous work has shown that the inverse gas chromatography (IGC) method combined with Flory–Huggins and solubility parameter theories could be used to quantify interactions in an amine cured epoxy resin matrix. In the present communication the same procedures have been adopted for an anhydride cured epoxy resin matrix. The solubility parameter at 298 K thereby obtained for the cured resin was 20–6 (MPa)1/2, which lies between the corresponding values of 18.8(MPa)1/2 and 22.5 (MPa)1/2 for the precursors, viz. Epikote 828 (an epoxide resin) and phthalic anhydride, respectively. It was noted that great care must be exercised regarding choice of solvent used for deposition of phthalic anhydride on a glass bead support because of reaction to phthaclic acid. Similar consderations apply to the choice of probes used.</description><subject>Applied sciences</subject><subject>epoxy resin</subject><subject>Exact sciences and technology</subject><subject>inverse gas chromatography</subject><subject>Organic polymers</subject><subject>phthalic anhydride</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>solubility parameter</subject><subject>Thermal and thermodynamic properties</subject><issn>0959-8103</issn><issn>1097-0126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNqNkF1rFDEUhoMouFZ_gHe5EO9mPfmcxDtZtBZKFWkpeBPSzEk3OjuZJrPa-fdO2bJ4p1cnhzzPe-Al5DWDNQPg78a0ZtbKNWcgFHAQT8iKgW0bYFw_JSuwyjZm-XxOXtT6AwCMtXZFvl9VpDnSNPzCsjxvfaVhW_LOT_m2-HE70ynTu70fphTnBZuw-DClPNRloX7Yzl1JHdKwL9hRHPP9TAvWNNSX5Fn0fcVXj_OEXH36eLn53Jx_OT3bfDhvguRCNB5FFEp4L2OwktsokLfYKfAdk0pHHZSxmhnobkRgJrQ-CLhBCdJoQKbFCXl7yB1Lvttjndwu1YB97wfM--q4VpYpw_4HNLLVYgHZAQwl11owurGknS-zY-Ae6nZjcg91u2Pdi_PmMdzX4PtY_BBSPYqScwNSLtj7A_Y79Tj_O9d9Pfv7RnOQU53w_ij78tPpVrTKXV-cukvxDTbi4tox8Qf13qBL</recordid><startdate>199410</startdate><enddate>199410</enddate><creator>Jackson, Paul L.</creator><creator>Huglin, Malcolm B.</creator><creator>Cervenka, Antonin</creator><general>John Wiley & Sons, Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>199410</creationdate><title>Use of inverse gas chromatography to quantify interactions in anhydride cured epoxy resins</title><author>Jackson, Paul L. ; Huglin, Malcolm B. ; Cervenka, Antonin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4233-ae3f353aa4fc9429f3e27ed50ad1456f6c5896180db3c18c7ac30be404860e163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>Applied sciences</topic><topic>epoxy resin</topic><topic>Exact sciences and technology</topic><topic>inverse gas chromatography</topic><topic>Organic polymers</topic><topic>phthalic anhydride</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>solubility parameter</topic><topic>Thermal and thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jackson, Paul L.</creatorcontrib><creatorcontrib>Huglin, Malcolm B.</creatorcontrib><creatorcontrib>Cervenka, Antonin</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Polymer international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jackson, Paul L.</au><au>Huglin, Malcolm B.</au><au>Cervenka, Antonin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Use of inverse gas chromatography to quantify interactions in anhydride cured epoxy resins</atitle><jtitle>Polymer international</jtitle><addtitle>Polym. Int</addtitle><date>1994-10</date><risdate>1994</risdate><volume>35</volume><issue>2</issue><spage>135</spage><epage>143</epage><pages>135-143</pages><issn>0959-8103</issn><eissn>1097-0126</eissn><abstract>Previous work has shown that the inverse gas chromatography (IGC) method combined with Flory–Huggins and solubility parameter theories could be used to quantify interactions in an amine cured epoxy resin matrix. In the present communication the same procedures have been adopted for an anhydride cured epoxy resin matrix. The solubility parameter at 298 K thereby obtained for the cured resin was 20–6 (MPa)1/2, which lies between the corresponding values of 18.8(MPa)1/2 and 22.5 (MPa)1/2 for the precursors, viz. Epikote 828 (an epoxide resin) and phthalic anhydride, respectively. It was noted that great care must be exercised regarding choice of solvent used for deposition of phthalic anhydride on a glass bead support because of reaction to phthaclic acid. Similar consderations apply to the choice of probes used.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pi.1994.210350203</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0959-8103 |
| ispartof | Polymer international, 1994-10, Vol.35 (2), p.135-143 |
| issn | 0959-8103 1097-0126 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_26591581 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences epoxy resin Exact sciences and technology inverse gas chromatography Organic polymers phthalic anhydride Physicochemistry of polymers Properties and characterization solubility parameter Thermal and thermodynamic properties |
| title | Use of inverse gas chromatography to quantify interactions in anhydride cured epoxy resins |
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