Recent advances in the conversion of furfural into bio-chemicals through chemo- and bio-catalysis
Furfural is a promising renewable platform molecule derived from hemi-cellulose, which can be further converted to fossil fuel alternatives and valuable chemicals due to its highly functionalized molecular structure. This mini-review summarizes the recent progress in the chemo-catalytic and/or bio-c...
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| Veröffentlicht in: | RSC advances 2021-08, Vol.11 (43), p.2742-2758 |
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| creator | Zhang, Xu Xu, Siquan Li, Qinfang Zhou, Guilin Xia, Haian |
| description | Furfural is a promising renewable platform molecule derived from hemi-cellulose, which can be further converted to fossil fuel alternatives and valuable chemicals due to its highly functionalized molecular structure. This mini-review summarizes the recent progress in the chemo-catalytic and/or bio-catalytic conversion of furfural into high-value-added chemicals, including furfurylamine, C
6
carboxylic acid,
i.e.
, furandicarboxylic acid, furfural alcohol, aromatics, levulinic acid, maleic acid, succinic acid, furoic acid, and cyclopentanone, particularly the advances in the catalytic valorization of furfural into useful chemicals in the last few years. The possible reaction mechanisms for the conversion of furfural into bio-chemicals are summarized and discussed. The future prospective and challenges in the utilization of furfural through chemo- and bio-catalysis are also put forward for the further design and optimization of catalytic processes for the conversion of furfural.
Furfural is a promising renewable platform molecule derived from hemi-cellulose, which can be further converted to fossil fuel alternatives and valuable chemicals due to its highly functionalized molecular structure. |
| doi_str_mv | 10.1039/d1ra04633k |
| format | Article |
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6
carboxylic acid,
i.e.
, furandicarboxylic acid, furfural alcohol, aromatics, levulinic acid, maleic acid, succinic acid, furoic acid, and cyclopentanone, particularly the advances in the catalytic valorization of furfural into useful chemicals in the last few years. The possible reaction mechanisms for the conversion of furfural into bio-chemicals are summarized and discussed. The future prospective and challenges in the utilization of furfural through chemo- and bio-catalysis are also put forward for the further design and optimization of catalytic processes for the conversion of furfural.
Furfural is a promising renewable platform molecule derived from hemi-cellulose, which can be further converted to fossil fuel alternatives and valuable chemicals due to its highly functionalized molecular structure.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d1ra04633k</identifier><identifier>PMID: 35479988</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Acids ; Alternative fuels ; Carboxylic acids ; Catalysis ; Catalytic converters ; Chemistry ; Conversion ; Design optimization ; Fossil fuels ; Furfural ; Furoic acid ; Levulinic acid ; Maleic acid ; Molecular structure ; Reaction mechanisms ; Succinic acid</subject><ispartof>RSC advances, 2021-08, Vol.11 (43), p.2742-2758</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2021</rights><rights>This journal is © The Royal Society of Chemistry 2021 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c428t-6ac52067df519e06da0ad54390b1c7793870b692f2f33a3d4e92c8a25f21650b3</citedby><cites>FETCH-LOGICAL-c428t-6ac52067df519e06da0ad54390b1c7793870b692f2f33a3d4e92c8a25f21650b3</cites><orcidid>0000-0002-2072-9275 ; 0000-0002-7889-8928</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037638/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037638/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27903,27904,53769,53771</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35479988$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Xu</creatorcontrib><creatorcontrib>Xu, Siquan</creatorcontrib><creatorcontrib>Li, Qinfang</creatorcontrib><creatorcontrib>Zhou, Guilin</creatorcontrib><creatorcontrib>Xia, Haian</creatorcontrib><title>Recent advances in the conversion of furfural into bio-chemicals through chemo- and bio-catalysis</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Furfural is a promising renewable platform molecule derived from hemi-cellulose, which can be further converted to fossil fuel alternatives and valuable chemicals due to its highly functionalized molecular structure. This mini-review summarizes the recent progress in the chemo-catalytic and/or bio-catalytic conversion of furfural into high-value-added chemicals, including furfurylamine, C
6
carboxylic acid,
i.e.
, furandicarboxylic acid, furfural alcohol, aromatics, levulinic acid, maleic acid, succinic acid, furoic acid, and cyclopentanone, particularly the advances in the catalytic valorization of furfural into useful chemicals in the last few years. The possible reaction mechanisms for the conversion of furfural into bio-chemicals are summarized and discussed. The future prospective and challenges in the utilization of furfural through chemo- and bio-catalysis are also put forward for the further design and optimization of catalytic processes for the conversion of furfural.
Furfural is a promising renewable platform molecule derived from hemi-cellulose, which can be further converted to fossil fuel alternatives and valuable chemicals due to its highly functionalized molecular structure.</description><subject>Acids</subject><subject>Alternative fuels</subject><subject>Carboxylic acids</subject><subject>Catalysis</subject><subject>Catalytic converters</subject><subject>Chemistry</subject><subject>Conversion</subject><subject>Design optimization</subject><subject>Fossil fuels</subject><subject>Furfural</subject><subject>Furoic acid</subject><subject>Levulinic acid</subject><subject>Maleic acid</subject><subject>Molecular structure</subject><subject>Reaction mechanisms</subject><subject>Succinic acid</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkd1LHDEUxUOpqKy--N4S6EsRRvM9k5eCWL9woSD6HO5kMm7sbGKTmQX_e7Ndu7UNgVxyfhzO5SB0RMkJJVyfdjQBEYrznx_QPitTxYjSH9_Ne-gw5ydSjpKUKbqL9rgUtdZNs4_gzlkXRgzdCoJ1GfuAx4XDNoaVS9nHgGOP-ymVC0NRx4hbHyu7cEtvYciFTnF6XOD1T6wwhG4DwAjDS_b5AO30hXOHb-8MPVxe3J9fV_MfVzfnZ_PKCtaMlQIrS9q66yXVjqgOCHRScE1aauta86YmrdKsZz3nwDvhNLMNMNkzqiRp-Qx92_g-T-3SdeutSmLznPwS0ouJ4M2_SvAL8xhXRhNeK94Ug69vBin-mlwezdJn64YBgotTNkxJVQtGJS_ol__QpzilUNYzTEotqBCCFup4Q9kUc06u34ahxKzLM9_p3dnv8m4L_Pl9_C36p6oCfNoAKdut-rd9_gpiZ57E</recordid><startdate>20210802</startdate><enddate>20210802</enddate><creator>Zhang, Xu</creator><creator>Xu, Siquan</creator><creator>Li, Qinfang</creator><creator>Zhou, Guilin</creator><creator>Xia, Haian</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-2072-9275</orcidid><orcidid>https://orcid.org/0000-0002-7889-8928</orcidid></search><sort><creationdate>20210802</creationdate><title>Recent advances in the conversion of furfural into bio-chemicals through chemo- and bio-catalysis</title><author>Zhang, Xu ; Xu, Siquan ; Li, Qinfang ; Zhou, Guilin ; Xia, Haian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c428t-6ac52067df519e06da0ad54390b1c7793870b692f2f33a3d4e92c8a25f21650b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acids</topic><topic>Alternative fuels</topic><topic>Carboxylic acids</topic><topic>Catalysis</topic><topic>Catalytic converters</topic><topic>Chemistry</topic><topic>Conversion</topic><topic>Design optimization</topic><topic>Fossil fuels</topic><topic>Furfural</topic><topic>Furoic acid</topic><topic>Levulinic acid</topic><topic>Maleic acid</topic><topic>Molecular structure</topic><topic>Reaction mechanisms</topic><topic>Succinic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Xu</creatorcontrib><creatorcontrib>Xu, Siquan</creatorcontrib><creatorcontrib>Li, Qinfang</creatorcontrib><creatorcontrib>Zhou, Guilin</creatorcontrib><creatorcontrib>Xia, Haian</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Xu</au><au>Xu, Siquan</au><au>Li, Qinfang</au><au>Zhou, Guilin</au><au>Xia, Haian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent advances in the conversion of furfural into bio-chemicals through chemo- and bio-catalysis</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2021-08-02</date><risdate>2021</risdate><volume>11</volume><issue>43</issue><spage>2742</spage><epage>2758</epage><pages>2742-2758</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Furfural is a promising renewable platform molecule derived from hemi-cellulose, which can be further converted to fossil fuel alternatives and valuable chemicals due to its highly functionalized molecular structure. This mini-review summarizes the recent progress in the chemo-catalytic and/or bio-catalytic conversion of furfural into high-value-added chemicals, including furfurylamine, C
6
carboxylic acid,
i.e.
, furandicarboxylic acid, furfural alcohol, aromatics, levulinic acid, maleic acid, succinic acid, furoic acid, and cyclopentanone, particularly the advances in the catalytic valorization of furfural into useful chemicals in the last few years. The possible reaction mechanisms for the conversion of furfural into bio-chemicals are summarized and discussed. The future prospective and challenges in the utilization of furfural through chemo- and bio-catalysis are also put forward for the further design and optimization of catalytic processes for the conversion of furfural.
Furfural is a promising renewable platform molecule derived from hemi-cellulose, which can be further converted to fossil fuel alternatives and valuable chemicals due to its highly functionalized molecular structure.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35479988</pmid><doi>10.1039/d1ra04633k</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0002-2072-9275</orcidid><orcidid>https://orcid.org/0000-0002-7889-8928</orcidid><oa>free_for_read</oa></addata></record> |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central |
| subjects | Acids Alternative fuels Carboxylic acids Catalysis Catalytic converters Chemistry Conversion Design optimization Fossil fuels Furfural Furoic acid Levulinic acid Maleic acid Molecular structure Reaction mechanisms Succinic acid |
| title | Recent advances in the conversion of furfural into bio-chemicals through chemo- and bio-catalysis |
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