Fabrication and mechanical characterization of glass fiber reinforced UV-cured composites from epoxidized vegetable oils
Novel fiberglass‐reinforced composites were fabricated by the ultraviolet and visible (solar) irradiation of epoxidized vegetable oils in the presence of onium salt cationic photoinitiators. A variety of layup techniques and experimental conditions were explored to optimize composite fabrication. It...
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Veröffentlicht in: | Journal of applied polymer science 1997-06, Vol.64 (11), p.2073-2087 |
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creator | Crivello, J. V. Narayan, R. Sternstein, S.S. |
description | Novel fiberglass‐reinforced composites were fabricated by the ultraviolet and visible (solar) irradiation of epoxidized vegetable oils in the presence of onium salt cationic photoinitiators. A variety of layup techniques and experimental conditions were explored to optimize composite fabrication. It was demonstrated that composites prepared by wet layup techniques containing up to five plies of glass cloth could be cured by a direct, 25‐min exposure to solar irradiation. A series of composite samples were prepared using mixtures of epoxidized vegetable oils and synthetic epoxy resins, and their mechanical properties were evaluated. Based on these measurements, it may be concluded that photochemical routes to the fabrication of composites derived from epoxidized vegetable oils provide a simple, direct, and inexpensive route to the fabrication of composites with many potential low‐performance applications. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 2073–2087, 1997 |
doi_str_mv | 10.1002/(SICI)1097-4628(19970613)64:11<2073::AID-APP3>3.0.CO;2-G |
format | Article |
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V. ; Narayan, R. ; Sternstein, S.S.</creator><creatorcontrib>Crivello, J. V. ; Narayan, R. ; Sternstein, S.S.</creatorcontrib><description>Novel fiberglass‐reinforced composites were fabricated by the ultraviolet and visible (solar) irradiation of epoxidized vegetable oils in the presence of onium salt cationic photoinitiators. A variety of layup techniques and experimental conditions were explored to optimize composite fabrication. It was demonstrated that composites prepared by wet layup techniques containing up to five plies of glass cloth could be cured by a direct, 25‐min exposure to solar irradiation. A series of composite samples were prepared using mixtures of epoxidized vegetable oils and synthetic epoxy resins, and their mechanical properties were evaluated. Based on these measurements, it may be concluded that photochemical routes to the fabrication of composites derived from epoxidized vegetable oils provide a simple, direct, and inexpensive route to the fabrication of composites with many potential low‐performance applications. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 2073–2087, 1997</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/(SICI)1097-4628(19970613)64:11<2073::AID-APP3>3.0.CO;2-G</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>Applied sciences ; composites ; epoxidized vegetable oils ; Exact sciences and technology ; Forms of application and semi-finished materials ; Laminates ; photocuring ; Polymer industry, paints, wood ; solar curing ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 1997-06, Vol.64 (11), p.2073-2087</ispartof><rights>Copyright © 1997 John Wiley & Sons, Inc.</rights><rights>1997 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2F%28SICI%291097-4628%2819970613%2964%3A11%3C2073%3A%3AAID-APP3%3E3.0.CO%3B2-G$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2F%28SICI%291097-4628%2819970613%2964%3A11%3C2073%3A%3AAID-APP3%3E3.0.CO%3B2-G$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2666129$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Crivello, J. V.</creatorcontrib><creatorcontrib>Narayan, R.</creatorcontrib><creatorcontrib>Sternstein, S.S.</creatorcontrib><title>Fabrication and mechanical characterization of glass fiber reinforced UV-cured composites from epoxidized vegetable oils</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Novel fiberglass‐reinforced composites were fabricated by the ultraviolet and visible (solar) irradiation of epoxidized vegetable oils in the presence of onium salt cationic photoinitiators. A variety of layup techniques and experimental conditions were explored to optimize composite fabrication. It was demonstrated that composites prepared by wet layup techniques containing up to five plies of glass cloth could be cured by a direct, 25‐min exposure to solar irradiation. A series of composite samples were prepared using mixtures of epoxidized vegetable oils and synthetic epoxy resins, and their mechanical properties were evaluated. Based on these measurements, it may be concluded that photochemical routes to the fabrication of composites derived from epoxidized vegetable oils provide a simple, direct, and inexpensive route to the fabrication of composites with many potential low‐performance applications. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 2073–2087, 1997</description><subject>Applied sciences</subject><subject>composites</subject><subject>epoxidized vegetable oils</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Laminates</subject><subject>photocuring</subject><subject>Polymer industry, paints, wood</subject><subject>solar curing</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqNkU1vEzEQhlcIJELhP-wBofawwR-73jggRLSlIVIhFZSP28jrjIvL7jrYmzbtr8dLSjjAgYs94xk_M3rfJHlNyZgSwp4fflxUiyNKZJnlgk0OqZQlEZQfiXxK6UtGSj6dzhbH2ezsjL_iYzKuli9YNr-XjPaf7iejiKLZRMriYfIohEtCKC2IGCXbE1V7q1VvXZeqbpW2qL-pLr40aQy80j16e7urO5NeNCqE1NgaferRdsZ5jav00-dMb3wMtGvXLtgeY5N3bYprt7UrextLV3iBvaobTJ1twuPkgVFNwCd390FyfvLmvHqbnS7ni2p2mumCFjyetWY1qyU1yFSNda4InSBHzShRnPFcSMM0KQ2hyjCVM2OUNCUvY8pLfpA822HX3v3YYOihtUFj06gO3SYAEwUtmcxj49ddo_YuBI8G1t62yt8AJTA4ATA4AYOoMIgKv50AkQOlMDgBEJ2AwQngQKBaAoN5RD-920GFqKvxqtM27PlMCEGZ_LPBtW3w5q_x_zH9H8N_5RGd7dA29Ljdo5X_DiJKVcCX93PIP4iKH4sS3vGfWAy6tA</recordid><startdate>19970613</startdate><enddate>19970613</enddate><creator>Crivello, J. V.</creator><creator>Narayan, R.</creator><creator>Sternstein, S.S.</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19970613</creationdate><title>Fabrication and mechanical characterization of glass fiber reinforced UV-cured composites from epoxidized vegetable oils</title><author>Crivello, J. V. ; Narayan, R. ; Sternstein, S.S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5153-c5bc2b2b91fe2abeb4a018e3ec210a323469f2c07f01af2a42ffa9f7371af373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>Applied sciences</topic><topic>composites</topic><topic>epoxidized vegetable oils</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Laminates</topic><topic>photocuring</topic><topic>Polymer industry, paints, wood</topic><topic>solar curing</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Crivello, J. V.</creatorcontrib><creatorcontrib>Narayan, R.</creatorcontrib><creatorcontrib>Sternstein, S.S.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Crivello, J. V.</au><au>Narayan, R.</au><au>Sternstein, S.S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication and mechanical characterization of glass fiber reinforced UV-cured composites from epoxidized vegetable oils</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1997-06-13</date><risdate>1997</risdate><volume>64</volume><issue>11</issue><spage>2073</spage><epage>2087</epage><pages>2073-2087</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Novel fiberglass‐reinforced composites were fabricated by the ultraviolet and visible (solar) irradiation of epoxidized vegetable oils in the presence of onium salt cationic photoinitiators. A variety of layup techniques and experimental conditions were explored to optimize composite fabrication. It was demonstrated that composites prepared by wet layup techniques containing up to five plies of glass cloth could be cured by a direct, 25‐min exposure to solar irradiation. A series of composite samples were prepared using mixtures of epoxidized vegetable oils and synthetic epoxy resins, and their mechanical properties were evaluated. Based on these measurements, it may be concluded that photochemical routes to the fabrication of composites derived from epoxidized vegetable oils provide a simple, direct, and inexpensive route to the fabrication of composites with many potential low‐performance applications. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 2073–2087, 1997</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/(SICI)1097-4628(19970613)64:11<2073::AID-APP3>3.0.CO;2-G</doi><tpages>15</tpages></addata></record> |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | Applied sciences composites epoxidized vegetable oils Exact sciences and technology Forms of application and semi-finished materials Laminates photocuring Polymer industry, paints, wood solar curing Technology of polymers |
title | Fabrication and mechanical characterization of glass fiber reinforced UV-cured composites from epoxidized vegetable oils |
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