Double layer capacitance on a rough metal surface: Surface roughness measured by “Debye ruler”

The properties of the double layer capacity on rough electrodes are discussed in terms of the recently developed linear Poisson-Boltzmann theory [L.I. Daikhin, A.A. Kornyshev, M. Urbakh, Phys. Rev. E 53, 6192 (1996)]. This theory offers a concept of a “Debye-length κ dependent roughness factor”, ie...

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Veröffentlicht in:	Electrochimica acta 1997, Vol.42 (19), p.2853-2860
Hauptverfasser:	Daikhin, L.I., Kornyshev, A.A., Urbakh, M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Electrochemistry Electrodes: preparations and properties Exact sciences and technology General and physical chemistry Other electrodes
Online-Zugang:	Volltext
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