Enantioselective Rh-Catalyzed Azide-Internal-Alkyne Cycloaddition for the Construction of Axially Chiral 1,2,3-Triazoles

Significant advances have been achieved for the construction of chiral skeletons containing 1,2,3-triazoles via transition-metal-catalyzed asymmetric azide–alkyne cycloaddition; however, most of them have been limited to terminal alkynes in the synthesis of central chirality via desymmetrization and...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2022-04, Vol.144 (15), p.6981-6991
Hauptverfasser:	Guo, Wen-Ting, Zhu, Bo-Han, Chen, Yi, Yang, Jian, Qian, Peng-Cheng, Deng, Chao, Ye, Long-Wu, Li, Long
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Azides Catalysis Cycloaddition Reaction Rhodium Stereoisomerism Triazoles
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!