Chemical, Mechanical, and Tribological Properties of Pulsed-Laser-Deposited Titanium Carbide and Vanadium Carbide
The chemical, mechanical, and tribological properties of pulsed‐laser‐deposited TiC and VC films are reported in this paper. Films were deposited by ablating carbide targets using a KrF (λ= 248 nm) laser. Chemical analysis of the films by XPS revealed oxygen was the major impurity; the lowest oxygen...
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| Veröffentlicht in: | Journal of the American Ceramic Society 1997-05, Vol.80 (5), p.1277-1280 |
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| creator | Krzanowski, James E. Leuchtner, Robert E. |
| description | The chemical, mechanical, and tribological properties of pulsed‐laser‐deposited TiC and VC films are reported in this paper. Films were deposited by ablating carbide targets using a KrF (λ= 248 nm) laser. Chemical analysis of the films by XPS revealed oxygen was the major impurity; the lowest oxygen concentration obtained in a film was 5 atom%. Oxygen was located primarily on the carbon sublattice of the TiC structure. The films were always substoichiometric, as expected, and the carbon in the films was identified primarily as carbidic carbon. Nanoindentation hardness tests gave values of 39 GPa for TiC and 26 GPa for VC. The friction coefficient for the TiC films was 0.22, while the VC film exhibited rapid material transfer from the steel ball to the substrate resulting in steel‐on‐steel tribological behavior. |
| doi_str_mv | 10.1111/j.1151-2916.1997.tb02976.x |
| format | Article |
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Films were deposited by ablating carbide targets using a KrF (λ= 248 nm) laser. Chemical analysis of the films by XPS revealed oxygen was the major impurity; the lowest oxygen concentration obtained in a film was 5 atom%. Oxygen was located primarily on the carbon sublattice of the TiC structure. The films were always substoichiometric, as expected, and the carbon in the films was identified primarily as carbidic carbon. Nanoindentation hardness tests gave values of 39 GPa for TiC and 26 GPa for VC. 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Films were deposited by ablating carbide targets using a KrF (λ= 248 nm) laser. Chemical analysis of the films by XPS revealed oxygen was the major impurity; the lowest oxygen concentration obtained in a film was 5 atom%. Oxygen was located primarily on the carbon sublattice of the TiC structure. The films were always substoichiometric, as expected, and the carbon in the films was identified primarily as carbidic carbon. Nanoindentation hardness tests gave values of 39 GPa for TiC and 26 GPa for VC. The friction coefficient for the TiC films was 0.22, while the VC film exhibited rapid material transfer from the steel ball to the substrate resulting in steel‐on‐steel tribological behavior.</description><subject>40 CHEMISTRY</subject><subject>ABLATION</subject><subject>CHEMICAL COMPOSITION</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>FRICTION FACTOR</subject><subject>HARDNESS</subject><subject>MATERIALS SCIENCE</subject><subject>Physical properties of thin films, nonelectronic</subject><subject>Physics</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><subject>TITANIUM CARBIDES</subject><subject>TRIBOLOGY</subject><subject>VANADIUM CARBIDES</subject><subject>VAPOR DEPOSITED COATINGS</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqVkU1v1DAQhi0EEkvpfwgIcSKL7fgrnCihlFbbZYXKx81ynAnrJRtv7azY_nscsqo4gi_jGT_zjjUvQs8JnpN0Xm9S4CSnJRFzUpZyPtSYllLMDw_QjPDj00M0wxjTXCqKH6MnMW5SSkrFZui2WsPWWdO9yq7Brk0_3U3fZDfB1b7zP8ZKtgp-B2FwEDPfZqt9F6HJFyZCyN_Dzkc3QOpwQxLYb7PKhNo18Efmq-lN81fxKXrUmtR-eown6MuH85vqY774dHFZnS1yy2QhcyoBl1RZwYoCN7RQirQGN9JSwFy11DCjsBSct0IyVRBb18DaBrMGK1nzpjhBzyZdHweno00_tGvr-x7soDmhWBSJeTkxu-Bv9xAHvXXRQteZHvw-aiqYkgUl_wRSpUQC30ygDT7GAK3eBbc14U4TrEfL9EaPlunRFz1apo-W6UNqfnGcYmJaehtMb128V6CSCFbShL2dsF-ug7v_GKCvzqpzQqVMEvkk4eIAh3sJE35qkbbP9bflhV4uq9Xnd4rr78VvsCC53A</recordid><startdate>199705</startdate><enddate>199705</enddate><creator>Krzanowski, James E.</creator><creator>Leuchtner, Robert E.</creator><general>American Ceramics Society</general><general>Blackwell</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>H8D</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>199705</creationdate><title>Chemical, Mechanical, and Tribological Properties of Pulsed-Laser-Deposited Titanium Carbide and Vanadium Carbide</title><author>Krzanowski, James E. ; Leuchtner, Robert E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4737-27e0928c64330d23881fa0d7c2e058f2a4a807655f674831cbbe4fd04d087b5d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>40 CHEMISTRY</topic><topic>ABLATION</topic><topic>CHEMICAL COMPOSITION</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>FRICTION FACTOR</topic><topic>HARDNESS</topic><topic>MATERIALS SCIENCE</topic><topic>Physical properties of thin films, nonelectronic</topic><topic>Physics</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><topic>TITANIUM CARBIDES</topic><topic>TRIBOLOGY</topic><topic>VANADIUM CARBIDES</topic><topic>VAPOR DEPOSITED COATINGS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Krzanowski, James E.</creatorcontrib><creatorcontrib>Leuchtner, Robert E.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Krzanowski, James E.</au><au>Leuchtner, Robert E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chemical, Mechanical, and Tribological Properties of Pulsed-Laser-Deposited Titanium Carbide and Vanadium Carbide</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>1997-05</date><risdate>1997</risdate><volume>80</volume><issue>5</issue><spage>1277</spage><epage>1280</epage><pages>1277-1280</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><coden>JACTAW</coden><abstract>The chemical, mechanical, and tribological properties of pulsed‐laser‐deposited TiC and VC films are reported in this paper. Films were deposited by ablating carbide targets using a KrF (λ= 248 nm) laser. Chemical analysis of the films by XPS revealed oxygen was the major impurity; the lowest oxygen concentration obtained in a film was 5 atom%. Oxygen was located primarily on the carbon sublattice of the TiC structure. The films were always substoichiometric, as expected, and the carbon in the films was identified primarily as carbidic carbon. Nanoindentation hardness tests gave values of 39 GPa for TiC and 26 GPa for VC. The friction coefficient for the TiC films was 0.22, while the VC film exhibited rapid material transfer from the steel ball to the substrate resulting in steel‐on‐steel tribological behavior.</abstract><cop>Westerville, Ohio</cop><pub>American Ceramics Society</pub><doi>10.1111/j.1151-2916.1997.tb02976.x</doi><tpages>4</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | 40 CHEMISTRY ABLATION CHEMICAL COMPOSITION Condensed matter: structure, mechanical and thermal properties Exact sciences and technology FRICTION FACTOR HARDNESS MATERIALS SCIENCE Physical properties of thin films, nonelectronic Physics Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) TITANIUM CARBIDES TRIBOLOGY VANADIUM CARBIDES VAPOR DEPOSITED COATINGS |
| title | Chemical, Mechanical, and Tribological Properties of Pulsed-Laser-Deposited Titanium Carbide and Vanadium Carbide |
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