Calorimetric Techniques Applied to the Determination of Isosteric Heat of Desorption for Potato
Temperature had an influence on desorption isotherms of potato measured at six different temperatures (4, 14, 21, 28, 35 and 50°C). The parameters of the Oswin, Henderson, Halsey and GAB models, for isotherm representation, were identified. Water activity at any temperature could be calculated by me...
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Veröffentlicht in: | Journal of the science of food and agriculture 1997-05, Vol.74 (1), p.57-63 |
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creator | Sánchez, Emma S Juan, Nieves San Simal, Susana Rosselló, Carmen |
description | Temperature had an influence on desorption isotherms of potato measured at six different temperatures (4, 14, 21, 28, 35 and 50°C). The parameters of the Oswin, Henderson, Halsey and GAB models, for isotherm representation, were identified. Water activity at any temperature could be calculated by means of only one equation using the GAB model, which gave the best fit to experimental data in all the range of water activity studied (0·4–0·9). Isosteric heats of water desorption of potato, were determined from the desorption isotherms following the Clausius–Clapeyron equation and from two thermal analysis techniques (DSC and TG). Similar results were obtained through the two methods, indicating that calorimetric techniques are adequate to obtain the isosteric heat of desorption of products with a high starch content. © 1997 SCI. |
doi_str_mv | 10.1002/(SICI)1097-0010(199705)74:1<57::AID-JSFA770>3.0.CO;2-8 |
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The parameters of the Oswin, Henderson, Halsey and GAB models, for isotherm representation, were identified. Water activity at any temperature could be calculated by means of only one equation using the GAB model, which gave the best fit to experimental data in all the range of water activity studied (0·4–0·9). Isosteric heats of water desorption of potato, were determined from the desorption isotherms following the Clausius–Clapeyron equation and from two thermal analysis techniques (DSC and TG). 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Sci. Food Agric</addtitle><description>Temperature had an influence on desorption isotherms of potato measured at six different temperatures (4, 14, 21, 28, 35 and 50°C). The parameters of the Oswin, Henderson, Halsey and GAB models, for isotherm representation, were identified. Water activity at any temperature could be calculated by means of only one equation using the GAB model, which gave the best fit to experimental data in all the range of water activity studied (0·4–0·9). Isosteric heats of water desorption of potato, were determined from the desorption isotherms following the Clausius–Clapeyron equation and from two thermal analysis techniques (DSC and TG). Similar results were obtained through the two methods, indicating that calorimetric techniques are adequate to obtain the isosteric heat of desorption of products with a high starch content. © 1997 SCI.</description><subject>Biological and medical sciences</subject><subject>desorption</subject><subject>differential scanning calorimetry</subject><subject>Food industries</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>isosteric heat</subject><subject>isotherm</subject><subject>potato</subject><subject>Starch and starchy product industries</subject><subject>thermogravimetry</subject><issn>0022-5142</issn><issn>1097-0010</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><sourceid>K30</sourceid><recordid>eNp9kdFv0zAQxiMEEmXwP0QCoe0h5WwncVLQpCplW6aKTmww8XRyHEfzSONgp4L99zik9AEQT5bO3_3u7vuC4JTAnADQN8fXZVGeEMh5BEDgmOQ5h-SExwvyLuGLxbJcRZfXZ0vO4ZTNYV5s3tIoexTMDi2Pg5kH0SghMX0aPHPuHgDyPE1nARaiNVZv1WC1DG-UvOv0t51y4bLvW63qcDDhcKfClRqU3epODNp0oWnC0hnnS77pQolhrKyUM7b_9d8YG16ZQQzmefCkEa1TL_bvUfDp7P1NcRGtN-dlsVxHMo4BokRUquLE38tqngPPKM3TBqSQueRKVqRJSJbQiom45ik0rPJ3CSKaVNWiToAdBa8nbm_NuP-AW-2kalvRKbNzSNM4835QL3z5h_De7Gznd0OSMW9KzNiI-zyppDXOWdVg700S9gEJ4JgK4pgKjhbjaDFOqSCPkWDCEX0quE8FGQIWG6SYefCr_XjhpGgbKzqp3YFO09Qfyr3syyT7rlv18Nfw_8_-9-jfJc-OJrb2Af44sIX9iilnPMHbD-d4la9JXny8xFv2E6vYu7Y</recordid><startdate>199705</startdate><enddate>199705</enddate><creator>Sánchez, Emma S</creator><creator>Juan, Nieves San</creator><creator>Simal, Susana</creator><creator>Rosselló, Carmen</creator><general>John Wiley & Sons, Ltd</general><general>Wiley</general><general>Published for the Society of Chemical Industry by Elsevier Applied Science</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>HJHVS</scope><scope>IZSXY</scope><scope>K30</scope><scope>PAAUG</scope><scope>PAWHS</scope><scope>PAWZZ</scope><scope>PAXOH</scope><scope>PBHAV</scope><scope>PBQSW</scope><scope>PBYQZ</scope><scope>PCIWU</scope><scope>PCMID</scope><scope>PCZJX</scope><scope>PDGRG</scope><scope>PDWWI</scope><scope>PETMR</scope><scope>PFVGT</scope><scope>PGXDX</scope><scope>PIHIL</scope><scope>PISVA</scope><scope>PJCTQ</scope><scope>PJTMS</scope><scope>PLCHJ</scope><scope>PMHAD</scope><scope>PNQDJ</scope><scope>POUND</scope><scope>PPLAD</scope><scope>PQAPC</scope><scope>PQCAN</scope><scope>PQCMW</scope><scope>PQEME</scope><scope>PQHKH</scope><scope>PQMID</scope><scope>PQNCT</scope><scope>PQNET</scope><scope>PQSCT</scope><scope>PQSET</scope><scope>PSVJG</scope><scope>PVMQY</scope><scope>PZGFC</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>199705</creationdate><title>Calorimetric Techniques Applied to the Determination of Isosteric Heat of Desorption for Potato</title><author>Sánchez, Emma S ; Juan, Nieves San ; Simal, Susana ; Rosselló, Carmen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4400-5abeb711003d790782296f0cac9c7ecb1f51852b3a4d760f3b001a1af6edad503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>Biological and medical sciences</topic><topic>desorption</topic><topic>differential scanning calorimetry</topic><topic>Food industries</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>isosteric heat</topic><topic>isotherm</topic><topic>potato</topic><topic>Starch and starchy product industries</topic><topic>thermogravimetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sánchez, Emma S</creatorcontrib><creatorcontrib>Juan, Nieves San</creatorcontrib><creatorcontrib>Simal, Susana</creatorcontrib><creatorcontrib>Rosselló, Carmen</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Periodicals Index Online Segment 19</collection><collection>Periodicals Index Online Segment 30</collection><collection>Periodicals Index Online</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - West</collection><collection>Primary Sources Access (Plan D) - International</collection><collection>Primary Sources Access & Build (Plan A) - MEA</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - Midwest</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - Northeast</collection><collection>Primary Sources Access (Plan D) - Southeast</collection><collection>Primary Sources Access (Plan D) - North Central</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - Southeast</collection><collection>Primary Sources Access (Plan D) - South Central</collection><collection>Primary Sources Access & Build (Plan A) - UK / I</collection><collection>Primary Sources Access (Plan D) - Canada</collection><collection>Primary Sources Access (Plan D) - EMEALA</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - North Central</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - South Central</collection><collection>Primary Sources Access & Build (Plan A) - International</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - International</collection><collection>Primary Sources Access (Plan D) - West</collection><collection>Periodicals Index Online Segments 1-50</collection><collection>Primary Sources Access (Plan D) - APAC</collection><collection>Primary Sources Access (Plan D) - Midwest</collection><collection>Primary Sources Access (Plan D) - MEA</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - Canada</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - UK / I</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - EMEALA</collection><collection>Primary Sources Access & Build (Plan A) - APAC</collection><collection>Primary Sources Access & Build (Plan A) - Canada</collection><collection>Primary Sources Access & Build (Plan A) - West</collection><collection>Primary Sources Access & Build (Plan A) - EMEALA</collection><collection>Primary Sources Access (Plan D) - Northeast</collection><collection>Primary Sources Access & Build (Plan A) - Midwest</collection><collection>Primary Sources Access & Build (Plan A) - North Central</collection><collection>Primary Sources Access & Build (Plan A) - Northeast</collection><collection>Primary Sources Access & Build (Plan A) - South Central</collection><collection>Primary Sources Access & Build (Plan A) - Southeast</collection><collection>Primary Sources Access (Plan D) - UK / I</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - APAC</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - MEA</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Journal of the science of food and agriculture</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sánchez, Emma S</au><au>Juan, Nieves San</au><au>Simal, Susana</au><au>Rosselló, Carmen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Calorimetric Techniques Applied to the Determination of Isosteric Heat of Desorption for Potato</atitle><jtitle>Journal of the science of food and agriculture</jtitle><addtitle>J. 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Similar results were obtained through the two methods, indicating that calorimetric techniques are adequate to obtain the isosteric heat of desorption of products with a high starch content. © 1997 SCI.</abstract><cop>London</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/(SICI)1097-0010(199705)74:1<57::AID-JSFA770>3.0.CO;2-8</doi><tpages>7</tpages></addata></record> |
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subjects | Biological and medical sciences desorption differential scanning calorimetry Food industries Fundamental and applied biological sciences. Psychology isosteric heat isotherm potato Starch and starchy product industries thermogravimetry |
title | Calorimetric Techniques Applied to the Determination of Isosteric Heat of Desorption for Potato |
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