Torsional chirality and molecular recognition: the homo and heterochiral dimers of thenyl and furfuryl alcohol

Furfuryl alcohol and thenyl alcohol contain a labile torsional chiral center, producing transiently chiral enantiomers interconverting in the nanosecond time-scale. We explored chiral molecular recognition using the weakly-bound intermolecular dimers of both alcohols, freezing stereomutation. Supers...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2022-04, Vol.24 (15), p.8999-9006
Hauptverfasser:	Juanes, Marcos, Saragi, Rizalina Tama, Pérez, Cristóbal, Enríquez, Lourdes, Jaraíz, Martín, Lesarri, Alberto
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Broadband Chirality Dimers Enantiomers Freezing Furans - chemistry Furfuryl alcohol Hydrogen Bonding Hydrogen bonds Polymers Recognition Stereochemistry Stereoisomerism
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