Mass fractionation of nickel isotopes in metallic cosmic spheres

The isotopic abundances of stable Ni isotopes were measured by inductively coupled plasma mass spectrometry (ICP/MS) in seven cosmic, metallic (Type I) spheres collected from the deep sea. Mass-dependent enrichments of the heavier isotopes range from 0.5–2.8% / AMU, values larger than those reported...

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Veröffentlicht in:Geochimica et cosmochimica acta 1994-12, Vol.58 (23), p.5319-5323
Hauptverfasser: Herzog, G.F., hall, G.S., Brownlee, D.E.
Format: Artikel
Sprache:eng
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Zusammenfassung:The isotopic abundances of stable Ni isotopes were measured by inductively coupled plasma mass spectrometry (ICP/MS) in seven cosmic, metallic (Type I) spheres collected from the deep sea. Mass-dependent enrichments of the heavier isotopes range from 0.5–2.8% / AMU, values larger than those reported previously for Ni in any solid, extraterrestrial sample. This mass fractionation most likely reflects the high-temperature vaporization and loss from some spheres of over 90% of the Ni initially present.
ISSN:0016-7037
1872-9533
DOI:10.1016/0016-7037(94)90315-8