Tetragonal and rhombohedral phase co-existence in the system : PbZrO3-PbTiO3-Pb(Fe1/5, Ni1/5, Sb1/5, Sb3/5)O3
Various compositions of xPbZrO3-yPbTiO3-zPb(Fe1/5, Ni1/5, Sb3/5)O3 piezoelectric ceramics, having a Zr/Ti ratio between 45.1/49.9 and 51.1/43.9, were prepared using the usual ceramic techniques, in the temperature range 850-1200 C. The electromechanical coupling factor, piezoelectric constant and Yo...
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Veröffentlicht in: | Ceramics international 1996, Vol.22 (4), p.281-286 |
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description | Various compositions of xPbZrO3-yPbTiO3-zPb(Fe1/5, Ni1/5, Sb3/5)O3 piezoelectric ceramics, having a Zr/Ti ratio between 45.1/49.9 and 51.1/43.9, were prepared using the usual ceramic techniques, in the temperature range 850-1200 C. The electromechanical coupling factor, piezoelectric constant and Young's modulus were measured as a function of the Zr/Ti ratio. The results obtained are discussed on the basis of the effects of varying the Zr/Ti ratio. The effects of sintering temperature on microstructure were studied by SEM. Grain growth is enhanced by increasing the temperature. XRD demonstrated the co-existence of both tetragonal and rhombohedral phases. The lattice parameter measurements showed that tetragonal and rhombohedral unit cells of the two phases depend on the sintering temperature. 17 refs. |
doi_str_mv | 10.1016/0272-8842(95)00102-6 |
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subjects | Applied sciences Building materials. Ceramics. Glasses Ceramic industries Chemical industry and chemicals Electrotechnical and electronic ceramics Exact sciences and technology Technical ceramics |
title | Tetragonal and rhombohedral phase co-existence in the system : PbZrO3-PbTiO3-Pb(Fe1/5, Ni1/5, Sb1/5, Sb3/5)O3 |
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