Tetragonal and rhombohedral phase co-existence in the system : PbZrO3-PbTiO3-Pb(Fe1/5, Ni1/5, Sb1/5, Sb3/5)O3

Various compositions of xPbZrO3-yPbTiO3-zPb(Fe1/5, Ni1/5, Sb3/5)O3 piezoelectric ceramics, having a Zr/Ti ratio between 45.1/49.9 and 51.1/43.9, were prepared using the usual ceramic techniques, in the temperature range 850-1200 C. The electromechanical coupling factor, piezoelectric constant and Yo...

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Veröffentlicht in:Ceramics international 1996, Vol.22 (4), p.281-286
Hauptverfasser: BOUTARFAIA, A, BOUAOUD, S. E
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description Various compositions of xPbZrO3-yPbTiO3-zPb(Fe1/5, Ni1/5, Sb3/5)O3 piezoelectric ceramics, having a Zr/Ti ratio between 45.1/49.9 and 51.1/43.9, were prepared using the usual ceramic techniques, in the temperature range 850-1200 C. The electromechanical coupling factor, piezoelectric constant and Young's modulus were measured as a function of the Zr/Ti ratio. The results obtained are discussed on the basis of the effects of varying the Zr/Ti ratio. The effects of sintering temperature on microstructure were studied by SEM. Grain growth is enhanced by increasing the temperature. XRD demonstrated the co-existence of both tetragonal and rhombohedral phases. The lattice parameter measurements showed that tetragonal and rhombohedral unit cells of the two phases depend on the sintering temperature. 17 refs.
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subjects Applied sciences
Building materials. Ceramics. Glasses
Ceramic industries
Chemical industry and chemicals
Electrotechnical and electronic ceramics
Exact sciences and technology
Technical ceramics
title Tetragonal and rhombohedral phase co-existence in the system : PbZrO3-PbTiO3-Pb(Fe1/5, Ni1/5, Sb1/5, Sb3/5)O3
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