A FeCo2O4 nanowire array enabled electrochemical nitrate conversion to ammonia
Electrocatalytic nitrate (NO3−) reduction not only generates high-value ammonia (NH3) but holds significant potential in the control of NO3− contaminants in natural environments. Here, a bimetallic FeCo2O4 spinel nanowire array grown on carbon cloth is proposed as an efficient electrocatalyst for th...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-04, Vol.58 (28), p.4480-4483 |
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container_title | Chemical communications (Cambridge, England) |
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creator | Li, Jun Zhao, Donglin Zhang, Longcheng Luchao Yue Luo, Yongsong Liu, Qian Li, Na Abdulmohsen Ali Alshehri Hamdy, Mohamed S Li, Quan Sun, Xuping |
description | Electrocatalytic nitrate (NO3−) reduction not only generates high-value ammonia (NH3) but holds significant potential in the control of NO3− contaminants in natural environments. Here, a bimetallic FeCo2O4 spinel nanowire array grown on carbon cloth is proposed as an efficient electrocatalyst for the conversion of NO3− to NH3 with a high faradaic efficiency of up to 95.9% and a large NH3 yield of 4988 μg h−1 cm−2. Furthermore, it also exhibits excellent stability during 16 h electrolysis. |
doi_str_mv | 10.1039/d2cc00189f |
format | Article |
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Here, a bimetallic FeCo2O4 spinel nanowire array grown on carbon cloth is proposed as an efficient electrocatalyst for the conversion of NO3− to NH3 with a high faradaic efficiency of up to 95.9% and a large NH3 yield of 4988 μg h−1 cm−2. Furthermore, it also exhibits excellent stability during 16 h electrolysis.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d2cc00189f</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Ammonia ; Arrays ; Bimetals ; Contaminants ; Conversion ; Electrocatalysts ; Electrolysis ; Nanowires</subject><ispartof>Chemical communications (Cambridge, England), 2022-04, Vol.58 (28), p.4480-4483</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Li, Jun</creatorcontrib><creatorcontrib>Zhao, Donglin</creatorcontrib><creatorcontrib>Zhang, Longcheng</creatorcontrib><creatorcontrib>Luchao Yue</creatorcontrib><creatorcontrib>Luo, Yongsong</creatorcontrib><creatorcontrib>Liu, Qian</creatorcontrib><creatorcontrib>Li, Na</creatorcontrib><creatorcontrib>Abdulmohsen Ali Alshehri</creatorcontrib><creatorcontrib>Hamdy, Mohamed S</creatorcontrib><creatorcontrib>Li, Quan</creatorcontrib><creatorcontrib>Sun, Xuping</creatorcontrib><title>A FeCo2O4 nanowire array enabled electrochemical nitrate conversion to ammonia</title><title>Chemical communications (Cambridge, England)</title><description>Electrocatalytic nitrate (NO3−) reduction not only generates high-value ammonia (NH3) but holds significant potential in the control of NO3− contaminants in natural environments. Here, a bimetallic FeCo2O4 spinel nanowire array grown on carbon cloth is proposed as an efficient electrocatalyst for the conversion of NO3− to NH3 with a high faradaic efficiency of up to 95.9% and a large NH3 yield of 4988 μg h−1 cm−2. Furthermore, it also exhibits excellent stability during 16 h electrolysis.</description><subject>Ammonia</subject><subject>Arrays</subject><subject>Bimetals</subject><subject>Contaminants</subject><subject>Conversion</subject><subject>Electrocatalysts</subject><subject>Electrolysis</subject><subject>Nanowires</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdjktLA0EQhAdRMEYv_oIBL15We56ZPYbgC4K5KHgLndke3LA7E2c2iv_eDXqyKOg6fFQXY5cCbgSo-raR3gMIV4cjNhHK6spo93Z8yKauZkqbU3ZWyhZGCeMm7HnO72mR5ErziDF9tZk45ozfnCJuOmo4deSHnPw79a3Hjsd2yDgQ9yl-Ui5tinxIHPs-xRbP2UnArtDF352y1_u7l8VjtVw9PC3my2onhR2q0ITgRitUNQhRg7SudgIQJWy0ImUbERoSCowlS6Ac1N6bYIW3BjdWTdn1b-8up489lWHdt8VT12GktC9rabUAkFqZEb36h27TPsdx3YEa_4qZkuoHmMJdJg</recordid><startdate>20220405</startdate><enddate>20220405</enddate><creator>Li, Jun</creator><creator>Zhao, Donglin</creator><creator>Zhang, Longcheng</creator><creator>Luchao Yue</creator><creator>Luo, Yongsong</creator><creator>Liu, Qian</creator><creator>Li, Na</creator><creator>Abdulmohsen Ali Alshehri</creator><creator>Hamdy, Mohamed S</creator><creator>Li, Quan</creator><creator>Sun, Xuping</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20220405</creationdate><title>A FeCo2O4 nanowire array enabled electrochemical nitrate conversion to ammonia</title><author>Li, Jun ; Zhao, Donglin ; Zhang, Longcheng ; Luchao Yue ; Luo, Yongsong ; Liu, Qian ; Li, Na ; Abdulmohsen Ali Alshehri ; Hamdy, Mohamed S ; Li, Quan ; Sun, Xuping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p216t-fdff8ff83a39011902689810aa20b43e36d1fde13056e6e03809cc5f61c65ab63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Ammonia</topic><topic>Arrays</topic><topic>Bimetals</topic><topic>Contaminants</topic><topic>Conversion</topic><topic>Electrocatalysts</topic><topic>Electrolysis</topic><topic>Nanowires</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Jun</creatorcontrib><creatorcontrib>Zhao, Donglin</creatorcontrib><creatorcontrib>Zhang, Longcheng</creatorcontrib><creatorcontrib>Luchao Yue</creatorcontrib><creatorcontrib>Luo, Yongsong</creatorcontrib><creatorcontrib>Liu, Qian</creatorcontrib><creatorcontrib>Li, Na</creatorcontrib><creatorcontrib>Abdulmohsen Ali Alshehri</creatorcontrib><creatorcontrib>Hamdy, Mohamed S</creatorcontrib><creatorcontrib>Li, Quan</creatorcontrib><creatorcontrib>Sun, Xuping</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Jun</au><au>Zhao, Donglin</au><au>Zhang, Longcheng</au><au>Luchao Yue</au><au>Luo, Yongsong</au><au>Liu, Qian</au><au>Li, Na</au><au>Abdulmohsen Ali Alshehri</au><au>Hamdy, Mohamed S</au><au>Li, Quan</au><au>Sun, Xuping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A FeCo2O4 nanowire array enabled electrochemical nitrate conversion to ammonia</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2022-04-05</date><risdate>2022</risdate><volume>58</volume><issue>28</issue><spage>4480</spage><epage>4483</epage><pages>4480-4483</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Electrocatalytic nitrate (NO3−) reduction not only generates high-value ammonia (NH3) but holds significant potential in the control of NO3− contaminants in natural environments. 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source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
subjects | Ammonia Arrays Bimetals Contaminants Conversion Electrocatalysts Electrolysis Nanowires |
title | A FeCo2O4 nanowire array enabled electrochemical nitrate conversion to ammonia |
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