The influence of an oxide layer on hydrogen permeation through steel
Most experiments studying hydrogen permeation use a Devanathan cell with a membrane covered on the exit side by a palladium layer. To examine the results of dispensing with the palladium layer, the effect of hydrogen permeation through an oxide layer on the exit side of an iron membrane was studied....
Gespeichert in:
Veröffentlicht in: | Corrosion science 1996-09, Vol.38 (9), p.1535-1544 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 1544 |
---|---|
container_issue | 9 |
container_start_page | 1535 |
container_title | Corrosion science |
container_volume | 38 |
creator | Casanova, T. Crousier, J. |
description | Most experiments studying hydrogen permeation use a Devanathan cell with a membrane covered on the exit side by a palladium layer. To examine the results of dispensing with the palladium layer, the effect of hydrogen permeation through an oxide layer on the exit side of an iron membrane was studied. The results show that an iron membrane without a palladium layer on the hydrogen exit side can be used, if the aim of the experiments is to detect the variation of the steady state hydrogen permeation current as a function of the experiments carried out in the input cell, running comparative experiments. The passive layer formed on the exit side, from de-aerated NaOH solution, was perfectly stable even for long periods of hydrogen permeation. This result shows that the charge transfer takes place at the iron-iron oxide interface. The effect of hydrogen evolution on an oxide layer built on the input side of the membrane a was also studied. Preliminary work on bulk iron showed the electrochemical formation and reduction of a passive layer on iron. During hydrogen evolution, the iron oxide layer on the input side was rapidly reduced in two steps, according to the study on bulk iron. The two step reduction was displayed by modifications of the permeation currents which depend on the efficiency of the barrier effect of the oxides. |
doi_str_mv | 10.1016/0010-938X(96)00045-5 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_26394721</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>0010938X96000455</els_id><sourcerecordid>1688526279</sourcerecordid><originalsourceid>FETCH-LOGICAL-c499t-2a36e32e18d2cd5ce4820f298f22349d9cd4796a48faf091c7ac4ce16ddbccf13</originalsourceid><addsrcrecordid>eNp9kE1LAzEQhoMoWKv_wEMOIvWwmmSz2c1FkPoJBS8VvIWYTNrIdlOTrdh_b5aKx56GeXlmXngQOqfkmhIqbgihpJBl8z6R4ooQwquiOkAj2tSyIFyKQzT6R47RSUqfGWI5GaH7-RKw71y7gc4ADg7rDocfbwG3egsRhw4vtzaGBXR4DXEFuvc565cxbBZLnHqA9hQdOd0mOPubY_T2-DCfPhez16eX6d2sMFzKvmC6FFAyoI1lxlYGeMOIY7JxjJVcWmksr6XQvHHaEUlNrQ03QIW1H8Y4Wo7R5e7vOoavDaRerXwy0La6g7BJiolS8poN4GQvSEXTVEywWmaU71ATQ0oRnFpHv9JxqyhRg101qFODOiWHJdtVVT67-GvQyejWRd0Zn_5vS1bl3yJjtzsMspZvD1El4wfT1kcwvbLB7-_5BSBOjfQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1688526279</pqid></control><display><type>article</type><title>The influence of an oxide layer on hydrogen permeation through steel</title><source>Elsevier ScienceDirect Journals Complete - AutoHoldings</source><creator>Casanova, T. ; Crousier, J.</creator><creatorcontrib>Casanova, T. ; Crousier, J.</creatorcontrib><description>Most experiments studying hydrogen permeation use a Devanathan cell with a membrane covered on the exit side by a palladium layer. To examine the results of dispensing with the palladium layer, the effect of hydrogen permeation through an oxide layer on the exit side of an iron membrane was studied. The results show that an iron membrane without a palladium layer on the hydrogen exit side can be used, if the aim of the experiments is to detect the variation of the steady state hydrogen permeation current as a function of the experiments carried out in the input cell, running comparative experiments. The passive layer formed on the exit side, from de-aerated NaOH solution, was perfectly stable even for long periods of hydrogen permeation. This result shows that the charge transfer takes place at the iron-iron oxide interface. The effect of hydrogen evolution on an oxide layer built on the input side of the membrane a was also studied. Preliminary work on bulk iron showed the electrochemical formation and reduction of a passive layer on iron. During hydrogen evolution, the iron oxide layer on the input side was rapidly reduced in two steps, according to the study on bulk iron. The two step reduction was displayed by modifications of the permeation currents which depend on the efficiency of the barrier effect of the oxides.</description><identifier>ISSN: 0010-938X</identifier><identifier>EISSN: 1879-0496</identifier><identifier>DOI: 10.1016/0010-938X(96)00045-5</identifier><identifier>CODEN: CRRSAA</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>A. mild steel ; Applied sciences ; B. hydrogen permeation ; C. oxide coatings ; Corrosion ; Corrosion mechanisms ; Exact sciences and technology ; Metals. Metallurgy</subject><ispartof>Corrosion science, 1996-09, Vol.38 (9), p.1535-1544</ispartof><rights>1996</rights><rights>1996 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c499t-2a36e32e18d2cd5ce4820f298f22349d9cd4796a48faf091c7ac4ce16ddbccf13</citedby><cites>FETCH-LOGICAL-c499t-2a36e32e18d2cd5ce4820f298f22349d9cd4796a48faf091c7ac4ce16ddbccf13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0010-938X(96)00045-5$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3549,27923,27924,45994</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3257936$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Casanova, T.</creatorcontrib><creatorcontrib>Crousier, J.</creatorcontrib><title>The influence of an oxide layer on hydrogen permeation through steel</title><title>Corrosion science</title><description>Most experiments studying hydrogen permeation use a Devanathan cell with a membrane covered on the exit side by a palladium layer. To examine the results of dispensing with the palladium layer, the effect of hydrogen permeation through an oxide layer on the exit side of an iron membrane was studied. The results show that an iron membrane without a palladium layer on the hydrogen exit side can be used, if the aim of the experiments is to detect the variation of the steady state hydrogen permeation current as a function of the experiments carried out in the input cell, running comparative experiments. The passive layer formed on the exit side, from de-aerated NaOH solution, was perfectly stable even for long periods of hydrogen permeation. This result shows that the charge transfer takes place at the iron-iron oxide interface. The effect of hydrogen evolution on an oxide layer built on the input side of the membrane a was also studied. Preliminary work on bulk iron showed the electrochemical formation and reduction of a passive layer on iron. During hydrogen evolution, the iron oxide layer on the input side was rapidly reduced in two steps, according to the study on bulk iron. The two step reduction was displayed by modifications of the permeation currents which depend on the efficiency of the barrier effect of the oxides.</description><subject>A. mild steel</subject><subject>Applied sciences</subject><subject>B. hydrogen permeation</subject><subject>C. oxide coatings</subject><subject>Corrosion</subject><subject>Corrosion mechanisms</subject><subject>Exact sciences and technology</subject><subject>Metals. Metallurgy</subject><issn>0010-938X</issn><issn>1879-0496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKv_wEMOIvWwmmSz2c1FkPoJBS8VvIWYTNrIdlOTrdh_b5aKx56GeXlmXngQOqfkmhIqbgihpJBl8z6R4ooQwquiOkAj2tSyIFyKQzT6R47RSUqfGWI5GaH7-RKw71y7gc4ADg7rDocfbwG3egsRhw4vtzaGBXR4DXEFuvc565cxbBZLnHqA9hQdOd0mOPubY_T2-DCfPhez16eX6d2sMFzKvmC6FFAyoI1lxlYGeMOIY7JxjJVcWmksr6XQvHHaEUlNrQ03QIW1H8Y4Wo7R5e7vOoavDaRerXwy0La6g7BJiolS8poN4GQvSEXTVEywWmaU71ATQ0oRnFpHv9JxqyhRg101qFODOiWHJdtVVT67-GvQyejWRd0Zn_5vS1bl3yJjtzsMspZvD1El4wfT1kcwvbLB7-_5BSBOjfQ</recordid><startdate>19960901</startdate><enddate>19960901</enddate><creator>Casanova, T.</creator><creator>Crousier, J.</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>8FD</scope><scope>JG9</scope><scope>8BQ</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>19960901</creationdate><title>The influence of an oxide layer on hydrogen permeation through steel</title><author>Casanova, T. ; Crousier, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c499t-2a36e32e18d2cd5ce4820f298f22349d9cd4796a48faf091c7ac4ce16ddbccf13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>A. mild steel</topic><topic>Applied sciences</topic><topic>B. hydrogen permeation</topic><topic>C. oxide coatings</topic><topic>Corrosion</topic><topic>Corrosion mechanisms</topic><topic>Exact sciences and technology</topic><topic>Metals. Metallurgy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Casanova, T.</creatorcontrib><creatorcontrib>Crousier, J.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>METADEX</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Corrosion science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Casanova, T.</au><au>Crousier, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The influence of an oxide layer on hydrogen permeation through steel</atitle><jtitle>Corrosion science</jtitle><date>1996-09-01</date><risdate>1996</risdate><volume>38</volume><issue>9</issue><spage>1535</spage><epage>1544</epage><pages>1535-1544</pages><issn>0010-938X</issn><eissn>1879-0496</eissn><coden>CRRSAA</coden><abstract>Most experiments studying hydrogen permeation use a Devanathan cell with a membrane covered on the exit side by a palladium layer. To examine the results of dispensing with the palladium layer, the effect of hydrogen permeation through an oxide layer on the exit side of an iron membrane was studied. The results show that an iron membrane without a palladium layer on the hydrogen exit side can be used, if the aim of the experiments is to detect the variation of the steady state hydrogen permeation current as a function of the experiments carried out in the input cell, running comparative experiments. The passive layer formed on the exit side, from de-aerated NaOH solution, was perfectly stable even for long periods of hydrogen permeation. This result shows that the charge transfer takes place at the iron-iron oxide interface. The effect of hydrogen evolution on an oxide layer built on the input side of the membrane a was also studied. Preliminary work on bulk iron showed the electrochemical formation and reduction of a passive layer on iron. During hydrogen evolution, the iron oxide layer on the input side was rapidly reduced in two steps, according to the study on bulk iron. The two step reduction was displayed by modifications of the permeation currents which depend on the efficiency of the barrier effect of the oxides.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/0010-938X(96)00045-5</doi><tpages>10</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0010-938X |
ispartof | Corrosion science, 1996-09, Vol.38 (9), p.1535-1544 |
issn | 0010-938X 1879-0496 |
language | eng |
recordid | cdi_proquest_miscellaneous_26394721 |
source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
subjects | A. mild steel Applied sciences B. hydrogen permeation C. oxide coatings Corrosion Corrosion mechanisms Exact sciences and technology Metals. Metallurgy |
title | The influence of an oxide layer on hydrogen permeation through steel |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-09T04%3A19%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20influence%20of%20an%20oxide%20layer%20on%20hydrogen%20permeation%20through%20steel&rft.jtitle=Corrosion%20science&rft.au=Casanova,%20T.&rft.date=1996-09-01&rft.volume=38&rft.issue=9&rft.spage=1535&rft.epage=1544&rft.pages=1535-1544&rft.issn=0010-938X&rft.eissn=1879-0496&rft.coden=CRRSAA&rft_id=info:doi/10.1016/0010-938X(96)00045-5&rft_dat=%3Cproquest_cross%3E1688526279%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1688526279&rft_id=info:pmid/&rft_els_id=0010938X96000455&rfr_iscdi=true |