Water-Stable Eu6‑Cluster-Based fcu-MOF with Exposed Vinyl Groups for Ratiometric and Fluorescent Visual Sensing of Hydrogen Sulfide

Water-Stable Eu6‑Cluster-Based fcu-MOF with Exposed Vinyl Groups for Ratiometric and Fluorescent Visual Sensing of Hydrogen Sulfide

Detection of H2S in the biological system has attracted enormous attention in recent years. In this work, a new vinyl-functionalized metal–organic framework (MOF), [(Me2NH2)2] [Eu6(μ3-OH)8(BDC–CHCH2)6(H2O)6] (Eu-BDC–CHCH2, BDC–CHCH2 = 2-vinylterephthalic acid), was synthesized under solvothermal...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2022-03, Vol.61 (12), p.5067-5075
Hauptverfasser: Han, Xue, Liu, Jingwen, Yu, Kuangli, Lu, Yantong, Xiang, Wenqing, Zhao, Dian, He, Yabing
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 5075
container_issue 12
container_start_page 5067
container_title Inorganic chemistry
container_volume 61
creator Han, Xue
Liu, Jingwen
Yu, Kuangli
Lu, Yantong
Xiang, Wenqing
Zhao, Dian
He, Yabing
description Detection of H2S in the biological system has attracted enormous attention in recent years. In this work, a new vinyl-functionalized metal–organic framework (MOF), [(Me2NH2)2] [Eu6(μ3-OH)8(BDC–CHCH2)6(H2O)6] (Eu-BDC–CHCH2, BDC–CHCH2 = 2-vinylterephthalic acid), was synthesized under solvothermal conditions. The vinyl groups in the ligands can not only modulate the “antenna effect” of the ligand on Eu3+ ions but also serve as an exposed reactive site to allow for the quantitative detection of H2S by Eu-BDC–CHCH2. The ratiometric fluorescent probe has the advantages of water stability, acid-base stability (pH = 2–11), fast response (
doi_str_mv 10.1021/acs.inorgchem.2c00019
format Article
fullrecord <record><control><sourceid>proquest_acs_j</sourceid><recordid>TN_cdi_proquest_miscellaneous_2639228117</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2639228117</sourcerecordid><originalsourceid>FETCH-LOGICAL-a230t-79f00e0a72f8b838448b56286b195333c97fe3144248a78712bc8ad63d9aa1783</originalsourceid><addsrcrecordid>eNo9kMtKAzEYhYMoWKuPIGTpZmouM5nMUksvQqVgve2GTCbTpqRJTSZod258AF_RJ3GKxdX_c_g4HD4ALjEaYETwtZBhoK3zS7lSmwGRCCFcHIEezghKMoxej0EPoe7HjBWn4CyEdYcUNGU98PUiWuWTRSsqo-Aosp_P76GJYR_eiqBq2MiY3M_H8F23Kzj62Lp9-KztzsCJd3EbYOM8fBCtdhvVei2hsDUcm-i8ClLZtoNDFAYulA3aLqFr4HRXe7dUFi6iaXStzsFJI0xQF4fbB0_j0eNwmszmk7vhzSwRhKI2yYsGIYVEThpeccrTlFcZI5xVuMgopbLIG0VxmpKUi5znmFSSi5rRuhAC55z2wdVf79a7t6hCW250t9EYYZWLoSSMFoRwjPMOxX9oZ7dcu-htN6zEqNwrL_fhv_LyoJz-AtBaedo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2639228117</pqid></control><display><type>article</type><title>Water-Stable Eu6‑Cluster-Based fcu-MOF with Exposed Vinyl Groups for Ratiometric and Fluorescent Visual Sensing of Hydrogen Sulfide</title><source>ACS Publications</source><creator>Han, Xue ; Liu, Jingwen ; Yu, Kuangli ; Lu, Yantong ; Xiang, Wenqing ; Zhao, Dian ; He, Yabing</creator><creatorcontrib>Han, Xue ; Liu, Jingwen ; Yu, Kuangli ; Lu, Yantong ; Xiang, Wenqing ; Zhao, Dian ; He, Yabing</creatorcontrib><description>Detection of H2S in the biological system has attracted enormous attention in recent years. In this work, a new vinyl-functionalized metal–organic framework (MOF), [(Me2NH2)2] [Eu6(μ3-OH)8(BDC–CHCH2)6(H2O)6] (Eu-BDC–CHCH2, BDC–CHCH2 = 2-vinylterephthalic acid), was synthesized under solvothermal conditions. The vinyl groups in the ligands can not only modulate the “antenna effect” of the ligand on Eu3+ ions but also serve as an exposed reactive site to allow for the quantitative detection of H2S by Eu-BDC–CHCH2. The ratiometric fluorescent probe has the advantages of water stability, acid-base stability (pH = 2–11), fast response (&lt;2 min), high selectivity, and sensitivity (LOD = 38.4 μM). We also used Eu-BDC–CHCH2 to detect and analyze H2S in tap and lake waters, demonstrating the potential of the probe for biological and environmental applications. In addition, the MOF-based agarose hydrogel film allows for the visual detection of H2S via a smartphone by identifying the RGB values. The vinyl-functionalized MOF can thus be a powerful sensing platform for H2S.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.2c00019</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Inorganic chemistry, 2022-03, Vol.61 (12), p.5067-5075</ispartof><rights>2022 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-5255-4852 ; 0000-0002-0094-0591</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.2c00019$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00019$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,27057,27905,27906,56719,56769</link.rule.ids></links><search><creatorcontrib>Han, Xue</creatorcontrib><creatorcontrib>Liu, Jingwen</creatorcontrib><creatorcontrib>Yu, Kuangli</creatorcontrib><creatorcontrib>Lu, Yantong</creatorcontrib><creatorcontrib>Xiang, Wenqing</creatorcontrib><creatorcontrib>Zhao, Dian</creatorcontrib><creatorcontrib>He, Yabing</creatorcontrib><title>Water-Stable Eu6‑Cluster-Based fcu-MOF with Exposed Vinyl Groups for Ratiometric and Fluorescent Visual Sensing of Hydrogen Sulfide</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>Detection of H2S in the biological system has attracted enormous attention in recent years. In this work, a new vinyl-functionalized metal–organic framework (MOF), [(Me2NH2)2] [Eu6(μ3-OH)8(BDC–CHCH2)6(H2O)6] (Eu-BDC–CHCH2, BDC–CHCH2 = 2-vinylterephthalic acid), was synthesized under solvothermal conditions. The vinyl groups in the ligands can not only modulate the “antenna effect” of the ligand on Eu3+ ions but also serve as an exposed reactive site to allow for the quantitative detection of H2S by Eu-BDC–CHCH2. The ratiometric fluorescent probe has the advantages of water stability, acid-base stability (pH = 2–11), fast response (&lt;2 min), high selectivity, and sensitivity (LOD = 38.4 μM). We also used Eu-BDC–CHCH2 to detect and analyze H2S in tap and lake waters, demonstrating the potential of the probe for biological and environmental applications. In addition, the MOF-based agarose hydrogel film allows for the visual detection of H2S via a smartphone by identifying the RGB values. The vinyl-functionalized MOF can thus be a powerful sensing platform for H2S.</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNo9kMtKAzEYhYMoWKuPIGTpZmouM5nMUksvQqVgve2GTCbTpqRJTSZod258AF_RJ3GKxdX_c_g4HD4ALjEaYETwtZBhoK3zS7lSmwGRCCFcHIEezghKMoxej0EPoe7HjBWn4CyEdYcUNGU98PUiWuWTRSsqo-Aosp_P76GJYR_eiqBq2MiY3M_H8F23Kzj62Lp9-KztzsCJd3EbYOM8fBCtdhvVei2hsDUcm-i8ClLZtoNDFAYulA3aLqFr4HRXe7dUFi6iaXStzsFJI0xQF4fbB0_j0eNwmszmk7vhzSwRhKI2yYsGIYVEThpeccrTlFcZI5xVuMgopbLIG0VxmpKUi5znmFSSi5rRuhAC55z2wdVf79a7t6hCW250t9EYYZWLoSSMFoRwjPMOxX9oZ7dcu-htN6zEqNwrL_fhv_LyoJz-AtBaedo</recordid><startdate>20220328</startdate><enddate>20220328</enddate><creator>Han, Xue</creator><creator>Liu, Jingwen</creator><creator>Yu, Kuangli</creator><creator>Lu, Yantong</creator><creator>Xiang, Wenqing</creator><creator>Zhao, Dian</creator><creator>He, Yabing</creator><general>American Chemical Society</general><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5255-4852</orcidid><orcidid>https://orcid.org/0000-0002-0094-0591</orcidid></search><sort><creationdate>20220328</creationdate><title>Water-Stable Eu6‑Cluster-Based fcu-MOF with Exposed Vinyl Groups for Ratiometric and Fluorescent Visual Sensing of Hydrogen Sulfide</title><author>Han, Xue ; Liu, Jingwen ; Yu, Kuangli ; Lu, Yantong ; Xiang, Wenqing ; Zhao, Dian ; He, Yabing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a230t-79f00e0a72f8b838448b56286b195333c97fe3144248a78712bc8ad63d9aa1783</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Han, Xue</creatorcontrib><creatorcontrib>Liu, Jingwen</creatorcontrib><creatorcontrib>Yu, Kuangli</creatorcontrib><creatorcontrib>Lu, Yantong</creatorcontrib><creatorcontrib>Xiang, Wenqing</creatorcontrib><creatorcontrib>Zhao, Dian</creatorcontrib><creatorcontrib>He, Yabing</creatorcontrib><collection>MEDLINE - Academic</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Han, Xue</au><au>Liu, Jingwen</au><au>Yu, Kuangli</au><au>Lu, Yantong</au><au>Xiang, Wenqing</au><au>Zhao, Dian</au><au>He, Yabing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Water-Stable Eu6‑Cluster-Based fcu-MOF with Exposed Vinyl Groups for Ratiometric and Fluorescent Visual Sensing of Hydrogen Sulfide</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2022-03-28</date><risdate>2022</risdate><volume>61</volume><issue>12</issue><spage>5067</spage><epage>5075</epage><pages>5067-5075</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Detection of H2S in the biological system has attracted enormous attention in recent years. In this work, a new vinyl-functionalized metal–organic framework (MOF), [(Me2NH2)2] [Eu6(μ3-OH)8(BDC–CHCH2)6(H2O)6] (Eu-BDC–CHCH2, BDC–CHCH2 = 2-vinylterephthalic acid), was synthesized under solvothermal conditions. The vinyl groups in the ligands can not only modulate the “antenna effect” of the ligand on Eu3+ ions but also serve as an exposed reactive site to allow for the quantitative detection of H2S by Eu-BDC–CHCH2. The ratiometric fluorescent probe has the advantages of water stability, acid-base stability (pH = 2–11), fast response (&lt;2 min), high selectivity, and sensitivity (LOD = 38.4 μM). We also used Eu-BDC–CHCH2 to detect and analyze H2S in tap and lake waters, demonstrating the potential of the probe for biological and environmental applications. In addition, the MOF-based agarose hydrogel film allows for the visual detection of H2S via a smartphone by identifying the RGB values. The vinyl-functionalized MOF can thus be a powerful sensing platform for H2S.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.inorgchem.2c00019</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-5255-4852</orcidid><orcidid>https://orcid.org/0000-0002-0094-0591</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0020-1669
ispartof Inorganic chemistry, 2022-03, Vol.61 (12), p.5067-5075
issn 0020-1669
1520-510X
language eng
recordid cdi_proquest_miscellaneous_2639228117
source ACS Publications
title Water-Stable Eu6‑Cluster-Based fcu-MOF with Exposed Vinyl Groups for Ratiometric and Fluorescent Visual Sensing of Hydrogen Sulfide
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T01%3A01%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_acs_j&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Water-Stable%20Eu6%E2%80%91Cluster-Based%20fcu-MOF%20with%20Exposed%20Vinyl%20Groups%20for%20Ratiometric%20and%20Fluorescent%20Visual%20Sensing%20of%20Hydrogen%20Sulfide&rft.jtitle=Inorganic%20chemistry&rft.au=Han,%20Xue&rft.date=2022-03-28&rft.volume=61&rft.issue=12&rft.spage=5067&rft.epage=5075&rft.pages=5067-5075&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/acs.inorgchem.2c00019&rft_dat=%3Cproquest_acs_j%3E2639228117%3C/proquest_acs_j%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2639228117&rft_id=info:pmid/&rfr_iscdi=true