Rapid and sensitive electrochemical determination of tartrazine in commercial food samples using IL/AuTiO2/GO composite modified carbon paste electrode

•The developed sensor was efficient for the sensitive detection of tartrazine.•The IL/AuTiO2/GO/CPE exhibits excellent selectivity and high reproducibility.•The proposed sensor was used for the determination of tartrazine in food samples. A novel electrochemical sensor based on the modification of c...

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Veröffentlicht in:Food chemistry 2022-08, Vol.385, p.132616-132616, Article 132616
Hauptverfasser: State, Ramona Georgescu, van Staden, Jacobus (Koos) Frederick, State, Razvan Nicolae, Papa, Florica
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container_title Food chemistry
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creator State, Ramona Georgescu
van Staden, Jacobus (Koos) Frederick
State, Razvan Nicolae
Papa, Florica
description •The developed sensor was efficient for the sensitive detection of tartrazine.•The IL/AuTiO2/GO/CPE exhibits excellent selectivity and high reproducibility.•The proposed sensor was used for the determination of tartrazine in food samples. A novel electrochemical sensor based on the modification of carbon paste electrode with an ionic liquid (1-butyl-2,3-dimethylimidazolium tetrafluoroborate) and AuTiO2/GO composite (IL/AuTiO2/GO/CPE) was developed for rapid and sensitive determination of tartrazine by differential pulse voltammetry. Under the optimum experimental conditions, the peak current was linear to concentration of tartrazine in the ranges of 1–400 µmol L−1 and 400–1000 µmol L−1, with sensitivities of 0.008 µA µmol L−1 and 0.002 µA µmol L−1, respectively, and with a limit of detection of 0.33 µmol L−1 (S/N = 3). To demonstrate the performance of the method, the reproducibility was studied and the obtained values of RSD% were 2.72%. The method was applied to the sensitive determination of tartrazine in isotonic drink, mustard and yellow egg dye samples with recovery rates between 98.55% and 103.62%.
doi_str_mv 10.1016/j.foodchem.2022.132616
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A novel electrochemical sensor based on the modification of carbon paste electrode with an ionic liquid (1-butyl-2,3-dimethylimidazolium tetrafluoroborate) and AuTiO2/GO composite (IL/AuTiO2/GO/CPE) was developed for rapid and sensitive determination of tartrazine by differential pulse voltammetry. Under the optimum experimental conditions, the peak current was linear to concentration of tartrazine in the ranges of 1–400 µmol L−1 and 400–1000 µmol L−1, with sensitivities of 0.008 µA µmol L−1 and 0.002 µA µmol L−1, respectively, and with a limit of detection of 0.33 µmol L−1 (S/N = 3). To demonstrate the performance of the method, the reproducibility was studied and the obtained values of RSD% were 2.72%. The method was applied to the sensitive determination of tartrazine in isotonic drink, mustard and yellow egg dye samples with recovery rates between 98.55% and 103.62%.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.foodchem.2022.132616</doi><tpages>1</tpages></addata></record>
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source Elsevier ScienceDirect Journals Complete
subjects carbon electrodes
Composite
detection limit
eggs
Electrochemical sensor
electrochemistry
food chemistry
Food samples
Ionic liquid
ionic liquids
sensors (equipment)
Tartrazine
voltammetry
title Rapid and sensitive electrochemical determination of tartrazine in commercial food samples using IL/AuTiO2/GO composite modified carbon paste electrode
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