Three novel MOFs constructed from 1,3,5-tris(1-imidazolyl)benzene and dicarboxylate ligands with selective adsorption for C2H2/C2H4 and C2H6/CH4

The urothermal reactions of Co(ii)/Zn(ii) salts with the diverse carboxylic acid and 1,3,5,-tris(1-imidazolyl)benzene(tib) ligands afforded three novel MOFs, namely, [Co3(tib)2(abdc)2(ox)]2·6H2O (1), [Co3O(tib)(abdc)2(DMI)]·2DMI·2H2O (2) and [Zn3I2(tib)2(napdc)2]·2DMI·2H2O (3), (H2abdc = 5-amino-1,3...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2022-03, Vol.51 (12), p.4862-4868
Hauptverfasser:	Ming-Xing, Yang, Li-Juan, Chen, Gao, Jing, Gao, Yang, Guang-Tao Yu, Shen, Lin
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene Benzene Carbon Carboxylic acids Dicarboxylic acids Hydrocarbons Ligands Metal-organic frameworks Methane Naphthalene Selective adsorption Selectivity
Online-Zugang:	Volltext
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