Base oil recovery from waste lubricant oil by polar solvent extraction intensified by ultrasound
This paper proposes a greener approach to the intensification of base oil recovery for truck engines (32,500 km of use) using ethanol, propan-2-ol, 2-methylpropan-1-ol, and butan-1-ol as solvents for the extraction of base oil, combining mechanical stirring (220 rpm) and ultrasound (25 °C, 24 kHz, a...
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| Veröffentlicht in: | Environmental science and pollution research international 2021-12, Vol.28 (46), p.66000-66011 |
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| creator | Lins, Tomas S. Pisoler, Gleiciane Druzian, Gabriel T. Negris, Luana Decote, Paulo A. P. Vicente, Maristela A. Flores, Erico M. M. Santos, Maria F. P. |
| description | This paper proposes a greener approach to the intensification of base oil recovery for truck engines (32,500 km of use) using ethanol, propan-2-ol, 2-methylpropan-1-ol, and butan-1-ol as solvents for the extraction of base oil, combining mechanical stirring (220 rpm) and ultrasound (25 °C, 24 kHz, and 400 W). The results indicated that the recovery yields of the base oil, using the mechanical stirring and ultrasound (MS-US) system, for ethanol, propan-2-ol, 2-methylpropan-1-ol, and butan-1-ol were approximately 3.1, 25.6, 71.6, and 85.5%, respectively. By contrast, the recovery yields using only mechanical stirring were 8.8, 28.9, 58.9, and 76.1%, respectively. The system with pre-extraction could effectively remove Ca (85.3–93.0%), Mg (67.2–82.9%), Na (31.7–62.5%), and Zn (0.0–71.7%). Finally, the results showed a reduction of almost 100% for the concentrations of Al, Cr, Fe, and Mo in the pre-extraction system. The mechanical stirring (5 min) and ultrasound (5 min) system were able to intensify the extraction process using environmentally friendly solvents. |
| doi_str_mv | 10.1007/s11356-021-15582-y |
| format | Article |
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The system with pre-extraction could effectively remove Ca (85.3–93.0%), Mg (67.2–82.9%), Na (31.7–62.5%), and Zn (0.0–71.7%). Finally, the results showed a reduction of almost 100% for the concentrations of Al, Cr, Fe, and Mo in the pre-extraction system. The mechanical stirring (5 min) and ultrasound (5 min) system were able to intensify the extraction process using environmentally friendly solvents.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-021-15582-y</identifier><identifier>PMID: 34327639</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Automotive engines ; Chromium ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental science ; Ethanol ; Iron ; Isopropyl alcohol ; Lubricants ; Molybdenum ; Oil recovery ; Oil wastes ; oils ; Research Article ; Solvent extraction ; Solvents ; Stirring ; Truck engines ; Ultrasonic imaging ; ultrasonics ; Ultrasound ; Waste recovery ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Environmental science and pollution research international, 2021-12, Vol.28 (46), p.66000-66011</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>2021. 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P.</creatorcontrib><creatorcontrib>Vicente, Maristela A.</creatorcontrib><creatorcontrib>Flores, Erico M. M.</creatorcontrib><creatorcontrib>Santos, Maria F. P.</creatorcontrib><title>Base oil recovery from waste lubricant oil by polar solvent extraction intensified by ultrasound</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>This paper proposes a greener approach to the intensification of base oil recovery for truck engines (32,500 km of use) using ethanol, propan-2-ol, 2-methylpropan-1-ol, and butan-1-ol as solvents for the extraction of base oil, combining mechanical stirring (220 rpm) and ultrasound (25 °C, 24 kHz, and 400 W). The results indicated that the recovery yields of the base oil, using the mechanical stirring and ultrasound (MS-US) system, for ethanol, propan-2-ol, 2-methylpropan-1-ol, and butan-1-ol were approximately 3.1, 25.6, 71.6, and 85.5%, respectively. By contrast, the recovery yields using only mechanical stirring were 8.8, 28.9, 58.9, and 76.1%, respectively. The system with pre-extraction could effectively remove Ca (85.3–93.0%), Mg (67.2–82.9%), Na (31.7–62.5%), and Zn (0.0–71.7%). Finally, the results showed a reduction of almost 100% for the concentrations of Al, Cr, Fe, and Mo in the pre-extraction system. The mechanical stirring (5 min) and ultrasound (5 min) system were able to intensify the extraction process using environmentally friendly solvents.</description><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Automotive engines</subject><subject>Chromium</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Ethanol</subject><subject>Iron</subject><subject>Isopropyl alcohol</subject><subject>Lubricants</subject><subject>Molybdenum</subject><subject>Oil recovery</subject><subject>Oil wastes</subject><subject>oils</subject><subject>Research Article</subject><subject>Solvent extraction</subject><subject>Solvents</subject><subject>Stirring</subject><subject>Truck engines</subject><subject>Ultrasonic imaging</subject><subject>ultrasonics</subject><subject>Ultrasound</subject><subject>Waste recovery</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>BENPR</sourceid><recordid>eNqFkU1P3DAQhq2KqrvQ_gEOKBIXLmnHH7GdIyBakJB6ac-u7UxQVtl4sRMg_77eXT4kDu1pJM8z72j8EHJM4SsFUN8SpbySJTBa0qrSrJw_kCWVVJRK1PUBWUItREm5EAtymNIKgEHN1Cey4IIzJXm9JH8ubMIidH0R0YcHjHPRxrAuHm0asegnFztvh3FHuLnYhN7GIoX-AfMjPo3R-rELQ9ENIw6paztsttzU504K09B8Jh9b2yf88lyPyO_vV78ur8vbnz9uLs9vSy9Aj6XmQgJ3wJhTbStQK6ettq12LTRMWWcFs0o65nXlfcMlUg0cbE05Sq49PyJn-9xNDPcTptGsu-Sx7-2AYUqGSS4V1Qzg_2hVKcakVjyjp-_QVZjikA_JgZB_mcpqS7E95WNIKWJrNrFb2zgbCmaryuxVmazK7FSZOQ-dPEdPbo3N68iLmwzwPZBya7jD-Lb7H7F_Aa-In6s</recordid><startdate>20211201</startdate><enddate>20211201</enddate><creator>Lins, Tomas S.</creator><creator>Pisoler, Gleiciane</creator><creator>Druzian, Gabriel T.</creator><creator>Negris, Luana</creator><creator>Decote, Paulo A. 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P.</au><au>Vicente, Maristela A.</au><au>Flores, Erico M. M.</au><au>Santos, Maria F. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Base oil recovery from waste lubricant oil by polar solvent extraction intensified by ultrasound</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2021-12-01</date><risdate>2021</risdate><volume>28</volume><issue>46</issue><spage>66000</spage><epage>66011</epage><pages>66000-66011</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>This paper proposes a greener approach to the intensification of base oil recovery for truck engines (32,500 km of use) using ethanol, propan-2-ol, 2-methylpropan-1-ol, and butan-1-ol as solvents for the extraction of base oil, combining mechanical stirring (220 rpm) and ultrasound (25 °C, 24 kHz, and 400 W). The results indicated that the recovery yields of the base oil, using the mechanical stirring and ultrasound (MS-US) system, for ethanol, propan-2-ol, 2-methylpropan-1-ol, and butan-1-ol were approximately 3.1, 25.6, 71.6, and 85.5%, respectively. By contrast, the recovery yields using only mechanical stirring were 8.8, 28.9, 58.9, and 76.1%, respectively. The system with pre-extraction could effectively remove Ca (85.3–93.0%), Mg (67.2–82.9%), Na (31.7–62.5%), and Zn (0.0–71.7%). Finally, the results showed a reduction of almost 100% for the concentrations of Al, Cr, Fe, and Mo in the pre-extraction system. The mechanical stirring (5 min) and ultrasound (5 min) system were able to intensify the extraction process using environmentally friendly solvents.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>34327639</pmid><doi>10.1007/s11356-021-15582-y</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-6165-003X</orcidid></addata></record> |
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| subjects | Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Automotive engines Chromium Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Environmental science Ethanol Iron Isopropyl alcohol Lubricants Molybdenum Oil recovery Oil wastes oils Research Article Solvent extraction Solvents Stirring Truck engines Ultrasonic imaging ultrasonics Ultrasound Waste recovery Waste Water Technology Water Management Water Pollution Control |
| title | Base oil recovery from waste lubricant oil by polar solvent extraction intensified by ultrasound |
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