Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)­(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6– anions and H3BO3 molecules and features 9-ring channels along the c axis in a layered structure. This barium borate is a po...

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Veröffentlicht in:Inorganic chemistry 2022-03, Vol.61 (10), p.4246-4250
Hauptverfasser: Zhao, Wen-Zhuo, Zhang, Yi-Nan, Lan, You-Zhao, Cheng, Jian-Wen, Yang, Guo-Yu
Format: Artikel
Sprache:eng
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Zusammenfassung:A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)­(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6– anions and H3BO3 molecules and features 9-ring channels along the c axis in a layered structure. This barium borate is a possible deep-ultraviolet nonlinear-optical crystal for its moderate second-harmonic-generation signal and wide transparency window below 190 nm.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.2c00102