Approaching the isotropic spin-ladder regime: structure and magnetism of all-pyrazine-bridged copper()-based antiferromagnetic ladders

The crystal structure and magnetic properties of two all-pyrazine-bridged antiferromagnetic spin ladders are reported. The complexes, catena -(bis(3-X-4-pyridone)(μ-pyrazine)copper( ii )(-μ-pyrazine)diperchlorate ([Cu(pz) 1.5 (L) 2 ](ClO 4 ) 2 where L = 3-X-4-pyridone and X = Br ( 1 ) or Cl ( 2 )),...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2022-03, Vol.51 (12), p.4653-4667
Hauptverfasser:	Monroe, Jeffrey C, Carvajal, M. Angels, Landee, Christopher P, Deumal, Mercè, Turnbull, Mark M, Wikaira, Jan L, Dawe, Louise N
Format:	Artikel
Sprache:	eng
Schlagworte:	Antiferromagnetism Chemical bonds Copper Couplings Crystal structure Ladders Low temperature Magnetic permeability Magnetic properties Magnetization Mathematical analysis Railway bridges Scaffolds Topology
Online-Zugang:	Volltext
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