A bilayer coating as an oxygen-transfer cascade for the electrochemical ambient conversion of methane to oxygenates

Oxidation of methane at ambient conditions to useful oxygenates at a bilayer-coated electrode is demonstrated. The composition of the coating, a Mn porphyrin mediator layer on top of a N(OH) 2 /NiOOH one, allows a cascade of oxygen transfer events upon applying a potential. It is shown, using (spect...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (19), p.3154-3157
Hauptverfasser:	Kadosh, Yanir, Ben-Eliyahu, Yeshayahu, Bochlin, Yair, Ezuz, Lior, Iflah, Yacov, Halevy, Shuli, Kozuch, Sebastian, Korin, Eli, Bettelheim, Armand
Format:	Artikel
Sprache:	eng
Schlagworte:	Coated electrodes Density functional theory Electron transfer Energy conversion Methane Oxidation Oxygen transfer Porphyrins
Online-Zugang:	Volltext
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