Selective Oxidation of Alkylarenes to the Aromatic Ketones or Benzaldehydes with Water

Selective Oxidation of Alkylarenes to the Aromatic Ketones or Benzaldehydes with Water

Here a palladium-catalyzed oxidation method for converting alkylarenes into the aromatic ketones or benzaldehydes with water as the only oxygen donor is reported. This C–H bond oxidation functionalization does not require other oxidants and hydrogen acceptors, and H2 is the only byproduct. The oxyge...

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Veröffentlicht in:Organic letters 2022-02, Vol.24 (5), p.1152-1157
Hauptverfasser: Zhang, Jin, Du, Jihong, Zhang, Chenyang, Liu, Kun, Yu, Feifei, Yuan, Yongkun, Duan, Baogen, Liu, Renhua
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container_end_page 1157
container_issue 5
container_start_page 1152
container_title Organic letters
container_volume 24
creator Zhang, Jin
Du, Jihong
Zhang, Chenyang
Liu, Kun
Yu, Feifei
Yuan, Yongkun
Duan, Baogen
Liu, Renhua
description Here a palladium-catalyzed oxidation method for converting alkylarenes into the aromatic ketones or benzaldehydes with water as the only oxygen donor is reported. This C–H bond oxidation functionalization does not require other oxidants and hydrogen acceptors, and H2 is the only byproduct. The oxygen atom introduced into the products is confirmed to be from water by the MS analysis on the product of the 18O-labeled water reaction.
doi_str_mv 10.1021/acs.orglett.1c04154
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title Selective Oxidation of Alkylarenes to the Aromatic Ketones or Benzaldehydes with Water
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