Shake-up and shake-off structures in core level photoemission spectra from adsorbates
Previous studies of the satellites in adsorbate core level spectra are reviewed. New or recently published high resolution X-ray photoemission spectra are presented. The results represent systems which cover a range of different adsorption bond strengths, from physisorption (O 2/graphite) and weak c...
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| Veröffentlicht in: | Journal of electron spectroscopy and related phenomena 1993-03, Vol.62 (1), p.73-93 |
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| container_end_page | 93 |
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| container_title | Journal of electron spectroscopy and related phenomena |
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| creator | Tillborg, Helena Nilsson, Anders M»rtensson, Nils |
| description | Previous studies of the satellites in adsorbate core level spectra are reviewed. New or recently published high resolution X-ray photoemission spectra are presented. The results represent systems which cover a range of different adsorption bond strengths, from physisorption (O
2/graphite) and weak chemisorption (CO/Cu(100), N
2/Ni(100)) to strong chemisorption (CO/Ni(100)). The shake-up spectra reveal some new details, and are discussed in the light of previous models and interpretations. By extended shake-up/shake-off measurements, it is shown that the relative spectral weight of the main line in many cases is lower than previously suggested. The shake-up structures are discussed in terms of valence excitations in the substrate-adsorbate complex, and the role of the core hole is stressed. |
| doi_str_mv | 10.1016/0368-2048(93)80007-9 |
| format | Article |
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2/graphite) and weak chemisorption (CO/Cu(100), N
2/Ni(100)) to strong chemisorption (CO/Ni(100)). The shake-up spectra reveal some new details, and are discussed in the light of previous models and interpretations. By extended shake-up/shake-off measurements, it is shown that the relative spectral weight of the main line in many cases is lower than previously suggested. The shake-up structures are discussed in terms of valence excitations in the substrate-adsorbate complex, and the role of the core hole is stressed.</description><identifier>ISSN: 0368-2048</identifier><identifier>EISSN: 1873-2526</identifier><identifier>DOI: 10.1016/0368-2048(93)80007-9</identifier><identifier>CODEN: JESRAW</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Chemistry ; Exact sciences and technology ; General and physical chemistry ; Solid-gas interface ; Surface physical chemistry</subject><ispartof>Journal of electron spectroscopy and related phenomena, 1993-03, Vol.62 (1), p.73-93</ispartof><rights>1993</rights><rights>1993 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c364t-45ae2c70e0ea4fcf716095ebaa3657fe46097f0e3ad43d0f0d8c1420d35b05513</citedby><cites>FETCH-LOGICAL-c364t-45ae2c70e0ea4fcf716095ebaa3657fe46097f0e3ad43d0f0d8c1420d35b05513</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0368-2048(93)80007-9$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>313,314,780,784,792,3541,27913,27915,27916,45986</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4837864$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Tillborg, Helena</creatorcontrib><creatorcontrib>Nilsson, Anders</creatorcontrib><creatorcontrib>M»rtensson, Nils</creatorcontrib><title>Shake-up and shake-off structures in core level photoemission spectra from adsorbates</title><title>Journal of electron spectroscopy and related phenomena</title><description>Previous studies of the satellites in adsorbate core level spectra are reviewed. New or recently published high resolution X-ray photoemission spectra are presented. The results represent systems which cover a range of different adsorption bond strengths, from physisorption (O
2/graphite) and weak chemisorption (CO/Cu(100), N
2/Ni(100)) to strong chemisorption (CO/Ni(100)). The shake-up spectra reveal some new details, and are discussed in the light of previous models and interpretations. By extended shake-up/shake-off measurements, it is shown that the relative spectral weight of the main line in many cases is lower than previously suggested. The shake-up structures are discussed in terms of valence excitations in the substrate-adsorbate complex, and the role of the core hole is stressed.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Solid-gas interface</subject><subject>Surface physical chemistry</subject><issn>0368-2048</issn><issn>1873-2526</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LwzAYh4MoOKffwEMOInqoJk3atBdBhv9g4EF3Dln6hkW7puZtB357223s6Cn5wZNf3vch5JKzO854fs9EXiQpk8VNKW4LxphKyiMy4YUSSZql-TGZHJBTcob4NTKZSCdk8bEy35D0LTVNRXEbgnMUu9jbro-A1DfUhgi0hg3UtF2FLsDaI_rQUGzBdtFQF8OamgpDXJoO8JycOFMjXOzPKVk8P33OXpP5-8vb7HGeWJHLLpGZgdQqBgyMdNYpnrMyg6UxIs-UAzlE5RgIU0lRMceqwnKZskpkS5ZlXEzJ9a63jeGnB-z0MJiFujYNhB51mqecq1IOoNyBNgbECE630a9N_NWc6dGhHgXpUZAuhd46HC5TcrXvN2hN7aJprMfDW1kIVeRj-8MOg2HXjYeo0XpoLFQ-Dn50Ffz___wB-AKF5w</recordid><startdate>19930301</startdate><enddate>19930301</enddate><creator>Tillborg, Helena</creator><creator>Nilsson, Anders</creator><creator>M»rtensson, Nils</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19930301</creationdate><title>Shake-up and shake-off structures in core level photoemission spectra from adsorbates</title><author>Tillborg, Helena ; Nilsson, Anders ; M»rtensson, Nils</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-45ae2c70e0ea4fcf716095ebaa3657fe46097f0e3ad43d0f0d8c1420d35b05513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Solid-gas interface</topic><topic>Surface physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tillborg, Helena</creatorcontrib><creatorcontrib>Nilsson, Anders</creatorcontrib><creatorcontrib>M»rtensson, Nils</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of electron spectroscopy and related phenomena</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tillborg, Helena</au><au>Nilsson, Anders</au><au>M»rtensson, Nils</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Shake-up and shake-off structures in core level photoemission spectra from adsorbates</atitle><jtitle>Journal of electron spectroscopy and related phenomena</jtitle><date>1993-03-01</date><risdate>1993</risdate><volume>62</volume><issue>1</issue><spage>73</spage><epage>93</epage><pages>73-93</pages><issn>0368-2048</issn><eissn>1873-2526</eissn><coden>JESRAW</coden><abstract>Previous studies of the satellites in adsorbate core level spectra are reviewed. New or recently published high resolution X-ray photoemission spectra are presented. The results represent systems which cover a range of different adsorption bond strengths, from physisorption (O
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2/Ni(100)) to strong chemisorption (CO/Ni(100)). The shake-up spectra reveal some new details, and are discussed in the light of previous models and interpretations. By extended shake-up/shake-off measurements, it is shown that the relative spectral weight of the main line in many cases is lower than previously suggested. The shake-up structures are discussed in terms of valence excitations in the substrate-adsorbate complex, and the role of the core hole is stressed.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/0368-2048(93)80007-9</doi><tpages>21</tpages></addata></record> |
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| issn | 0368-2048 1873-2526 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Chemistry Exact sciences and technology General and physical chemistry Solid-gas interface Surface physical chemistry |
| title | Shake-up and shake-off structures in core level photoemission spectra from adsorbates |
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